Phosphide bromides or bromide phosphides are compounds containing anions composed of bromide (Br−) and phosphide (P3−) anions. Usually phosphorus is covalently connected into more complex structures. They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the phosphide chlorides, phosphide iodides, nitride bromides, arsenide bromides, and antimonide bromides.
List
edit| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|---|---|---|---|---|---|---|
| Ca2PBr | cubic | I43d | a=5.96 Z=2 | red brown | [1] | ||
| Ca2PBr | hexagonal | R3m | a=4.23 c=20.9 Z=3 | [1] | |||
| Cu12P20Br10 | triclinic | P | a = 9.886, b = 13.190, c = 14.763, α = 70.83°, β = 82.68°, γ = 80.13°, Z = 2 | 1786.1 | [2] | ||
| Cu13P15Br12 | [3] | ||||||
| Cu6PS5Br | cubic | P43m | a=9.732 Z=4 | 921.8 | 4.701 | red | [4] |
| (CuBr)2P8Se3 | orthorhombic | Pbcm | a=8.761 b=11.957 c=13.858 Z=4 | 1451.8 | [5] | ||
| Sr2PBr | cubic | I43d | a=9.31 Z=2 | brown violet | [1] | ||
| Sr2PBr | hexagonal | R3m | a=4.44 c=22.0 Z=3 | dark reddish brown | [1] | ||
| Sr2P7Br | cubic | P213 | a=9.789 Z=4 | 938.0 | 3.342 | red band gap 2.1 eV | [6] |
| Y2PBr2 | rhombohedral | a=3.9807 c=29.250 | [7] | ||||
| Ag6PS5Br | cubic | P43m | a=10.3765 Z=4 | 1117.26 | 5.460 | red | [4] |
| Cd5P2Br4 | orthorhombic | Pna21 | a=12.189, b=7.7080, c=13.664 | [8] | |||
| Sn24P19.3Br8 | [9] | ||||||
| Sn17Zn7P22Br8 | cubic | Pm3n | a=10.7449 | [10] | |||
| Sn24−xInxP19.2+0.2x x<16 | cubic | Pm3n | [11] | ||||
| Si30+xP16–xTe8–xBrx x = 1–6.4 | cubic | Pm3n | a=9.9720 - 10.0405 | [12] | |||
| Ba2PBr | hexagonal | R3m | a=4.67 c=23.3 Z=3 | [1] | |||
| Ba2P7Br | monoclinic | P21/m | a=6.294 b=6.835 c=11.850 β=95.819 Z=2 | 507.2 | 3.742 | orange | [13] |
| La2PBr2 | trigonal | P3m1 | a=4.311 c=11.000 Z=1 | 177.04 | 5.28 | [7] | |
| La3Zn4P6.6Br0.8 | orthorhombic | Cmcm | a=4.099 b=14.229 c=20.388 Z=4 | 1189.0 | 5.290 | black | [14] |
| Eu2PBr | R3m | a = 4.385, c = 21.90, Z = 3 | [15] | ||||
| W4(PBr)Br10 | monoclinic | C12/m1 | a=14.0933 b=10.3228 c=11.8169 β=93.906 Z=4 | 1715.16 | dark green | [16] | |
| Hg2P3Br | orthorhombic | Pbcn | a = 8.014, b = 8.902, c = 7.823, Z = 4 | [17] | |||
| Hg7P4Br6 | monoclinic | P21/c | a = 6.0452, b = 19.848, c = 7.5596 β = 104.214° Z=2 | 879.3 | 7.582 | brown | [18] |
| (Hg2P)2HgBr4 | monoclinic | P21 | a=7.776 b=12.226 c=7.930 β=121.34 Z=2 | 643.9 | 7.141 | discovered in 1907; bright yellow; air with light sensitive | [19] |
| [Hg7P4Br3](SnBr3) | cubic | P213 | a=12.490 Z=4 | [20] |
References
edit- ^ a b c d e Hadenfeldt, Claus; Kosiol, Wilfried (1975-06-01). "Darstellung und Eigenschaften von Phosphidbromiden des Calciums, Strontiums und Bariums / Preparation and Properties of Phosphide Bromides of Calcium, Strontium, and Barium". Zeitschrift für Naturforschung B. 30 (5–6): 378–384. doi:10.1515/znb-1975-5-616. ISSN 1865-7117. S2CID 94967271.
- ^ Freudenthaler, E.; Pfitzner, A. (1997-02-01). Freudenthaler, E.; Pfitzner, A. (eds.). "Crystal structure of Cu 12 P 20 Br 10 , a polyphosphide containing a new phosphorus polymer". Zeitschrift für Kristallographie - Crystalline Materials. 212 (2): 103–109. Bibcode:1997ZK....212..103F. doi:10.1524/zkri.1997.212.2.103. ISSN 2194-4946.
- ^ Freudenthaler, E (November 1997). "Copper(I) halide-phosphorus adducts: a new family of copper(I) ion conductors". Solid State Ionics. 101–103: 1053–1059. doi:10.1016/S0167-2738(97)00169-0.
- ^ a b Gao, Lihua; Wu, Xiaowen; Yang, Daqing; Tian, Xinyu; Xu, Jingjing; Zhang, Bingbing; Wu, Kui (2021). "M 6 PS 5 X (M = Ag, Cu; X = Cl, Br) chalcohalides exhibiting strong nonlinear optical responses and high laser damage resistances". Dalton Transactions. 50 (48): 17901–17905. doi:10.1039/D1DT03251H. ISSN 1477-9226. PMID 34851337. S2CID 244148134.
- ^ Nilges, S.; Nilges, T.; Haeuseler, H.; Pfitzner, A. (November 2004). "(CuBr)2P8Se3: preparation, structural, and vibrational spectroscopic characterization of an adduct of P8Se3 cages to Cu2Br2 rhombs". Journal of Molecular Structure. 706 (1–3): 89–94. Bibcode:2004JMoSt.706...89N. doi:10.1016/j.molstruc.2004.01.037.
- ^ Dolyniuk, Juli-Anna; Tran, Nhon; Lee, Kathleen; Kovnir, Kirill (July 2015). "Sr 2 P 7 X ( X = Cl, Br, and I): Synthesis, Crystal and Electronic Structures of Double Zintl Salts Containing Heptaphosphanortricyclane, P 7 3-: Double Zintl Salts with Heptaphosphanortricyclane, P 7 3-". Zeitschrift für anorganische und allgemeine Chemie. 641 (8–9): 1422–1427. doi:10.1002/zaac.201500140.
- ^ a b Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds". Zeitschrift für Naturforschung B. 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. S2CID 95077294.
- ^ M.M., Shatruk; L.N., Reshetova; A.V., Shevel'kov; B.A., Popovkin (2000). "Cd5P2Br4 - the first cadmium analogue of salts of Millon's base" [Cd5P2Br4 - the first cadmium analogue of salts of Millon's base]. Zhurnal Neorganicheskoj Khimii (in Russian). 45 (4). ISSN 0044-457X.
- ^ Stefanoski, S.; Reshetova, L. N.; Shevelkov, A. V.; Nolas, G. S. (July 2009). "Low-Temperature Transport Properties of Sn24P19.3Br8 and Sn17Zn7P22Br8". Journal of Electronic Materials. 38 (7): 985–989. Bibcode:2009JEMat..38..985S. doi:10.1007/s11664-008-0644-8. ISSN 0361-5235. S2CID 135898461.
- ^ Kovnir, Kirill A.; Shatruk, Mikhail M.; Reshetova, Lyudmila N.; Presniakov, Igor A.; Dikarev, Evgeny V.; Baitinger, Michael; Haarmann, Frank; Schnelle, Walter; Baenitz, Michael; Grin, Yuri; Shevelkov, Andrei V. (August 2005). "Novel compounds Sn20Zn4P22−vI8 (), Sn17Zn7P22I8, and Sn17Zn7P22Br8: Synthesis, properties, and special features of their clathrate-like crystal structures". Solid State Sciences. 7 (8): 957–968. doi:10.1016/j.solidstatesciences.2005.04.002.
- ^ Reshetova, L. N.; Shevelkov, A. V. (January 2012). "Synthesis and clathrate-type crystal structure of a solid solution in the Sn-In-P-Br system". Russian Chemical Bulletin. 61 (1): 28–32. doi:10.1007/s11172-012-0004-y. ISSN 1066-5285. S2CID 95316491.
- ^ Abramchuk, Nikolay S.; Carrillo-Cabrera, Wilder; Veremchuk, Igor; Oeschler, Niels; Olenev, Andrei V.; Prots, Yurii; Burkhardt, Ulrich; Dikarev, Evgeny V.; Grin, Juri; Shevelkov, Andrei V. (2012-11-05). "Homo- and Heterovalent Substitutions in the New Clathrates I Si 30 P 16 Te 8– x Se x and Si 30+ x P 16– x Te 8– x Br x : Synthesis, Crystal Structure, and Thermoelectric Properties". Inorganic Chemistry. 51 (21): 11396–11405. doi:10.1021/ic3010097. ISSN 0020-1669. PMID 23072375.
- ^ Dolyniuk, Juli-Anna; Kovnir, Kirill (2013-08-26). "Zintl Salts Ba2P7X (X = Cl, Br, and I): Synthesis, Crystal, and Electronic Structures". Crystals. 3 (3): 431–442. doi:10.3390/cryst3030431. ISSN 2073-4352.
- ^ Wang, Jian; Kaseman, Derrick; Lee, Kathleen; Sen, Sabyasachi; Kovnir, Kirill (2016-07-12). "Enclathration of X@La 4 Tetrahedra in Channels of Zn–P Frameworks in La 3 Zn 4 P 6 X (X = Cl, Br)". Chemistry of Materials. 28 (13): 4741–4750. doi:10.1021/acs.chemmater.6b01752. ISSN 0897-4756.
- ^ Hadenfeldt, C.; Held, W. (September 1986). "Darstellung, eigenschaften und kristallstruktur der Europium(ii)-phosphidhalogenide Eu2PCl, Eu2PBr und Eu2PI". Journal of the Less Common Metals (in German). 123 (1–2): 25–35. doi:10.1016/0022-5088(86)90111-6.
- ^ Ströbele, Markus; Eichele, Klaus; Meyer, Hans-Jürgen (2015-02-02). "Cluster Harvesting in the WBr 6 –P System". Inorganic Chemistry. 54 (3): 989–992. doi:10.1021/ic502333u. ISSN 0020-1669. PMID 25392957.
- ^ Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (1994-07-01). Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (eds.). "Helical [unk](P 1− ) chains in the structures of Hg 2 P 3 Br and Hg 2 P 3 Cl". Zeitschrift für Kristallographie - Crystalline Materials. 209 (7): 583–585. Bibcode:1994ZK....209..583S. doi:10.1524/zkri.1994.209.7.583. ISSN 2194-4946.
- ^ Shevelkov, A.V.; Dikarev, E.V.; Popovkin, B.A. (June 1993). "Syntheses and Crystal Structure of Hg7P4Br6". Journal of Solid State Chemistry. 104 (2): 177–180. Bibcode:1993JSSCh.104..177S. doi:10.1006/jssc.1993.1151.
- ^ Shevelkov, Andrei V.; Mustyakimov, Marat Yu.; Dikarev, Evgeny V.; Popovkin, Boris A. (1996). "(Hg2P)2HgBr4: a phosphorus analogue of the Millon's base salts". Journal of the Chemical Society, Dalton Transactions (1): 147–148. doi:10.1039/dt9960000147. ISSN 0300-9246.
- ^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry. 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.