Vinyl neodecanoate (trade name VeoVa 10) is a vinylic monomer that is virtually always used in combination with other monomers to create lattices or emulsion polymers.[3] The trade name is an acronym of Vinyl ester of Versatic Acid with the number 10 meaning 10 carbons in the molecule. It has a medium to low glass transition temperature of -3 °C. Chemically, it is a mixture of isomeric vinyl esters of neodecanoic acid.
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| Names | |
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| Preferred IUPAC name
Ethenyl 7,7-dimethyloctanoate | |
| Other names
Neodecanoic acid vinyl ester; VeoVa 10
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.051.715 |
| EC Number |
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PubChem CID
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| UNII | |
| UN number | 3082 |
CompTox Dashboard (EPA)
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| Properties | |
| C12H22O2 | |
| Molar mass | 198.306 g·mol−1 |
| Appearance | Colorless liquid[1] |
| Density | 0.882 g/mL[2] |
| Boiling point | 60–216 °C (140–421 °F; 333–489 K)[2] |
| Hazards | |
| GHS labelling: | |
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| Warning | |
| H410 | |
| P273, P391, P501 | |
| Flash point | 83 °C; 182 °F; 356 K[1] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Uses
editVinyl neodecanoate is mainly used as a modifying monomer in conjunction with other monomers and particularly the manufacture of vinyl acetate based polymer emulsions by the process of emulsion polymerization.[4] Vinyl neodecanoate-containing polymers are used in decorative emulsion paints, plasters and renders especially in Europe.[5] Vinyl neodecanoate, like most vinyl ester monomers, is very hydrophobic and the structure is highly branched with a tertiary substituted α-carbon. It is used as a hydrophobic co-monomer. This structure renders the polymers produced from it, very resistant to alkali degradation as there is no hydrogen (thus proton producing species) on the α-carbon.[6] They have good resistance to degradation from ultraviolet light.[7] The monomer has even been used to produce vibration dampening resins.[8] It is claimed to produce coatings with high liquid stain repellency.[9]
See also
editReferences
edit- ^ a b "Neodecanoic acid vinyl ester". caslab.com.
- ^ a b "Vinyl neodecanoate, mixture of isomers". Sigma-Aldrich.
- ^ "Technical Data Sheet - VeoVa™ 10 Monomer" (PDF). Retrieved 2023-12-24.
- ^ "VeoVa™ 10 - Hexion - datasheet". coatings.specialchem.com. Retrieved 2019-04-24.
- ^ "VeoVa 10 vinyl ester based binders for interior silk and exterior architectural paints". www.chemarc.com. Retrieved 2019-04-24.
- ^ "Vinyl Acetate-Versatic Acid Vinyl Ester Copolymer for Masonry Coatings". American Coatings Association. Retrieved 2021-12-10.
- ^ "Branched Vinyl Ester Monomers". www.pcimag.com. Retrieved 2019-04-02.
- ^ Taniuchi, Mamoru; Takatsuka, Kohro; Fujiwara, Haruo; Korida, Kazuhiko (1991-03-01). "Development of vibration-damping resins for room-temperature application". Metallurgical Transactions A. 22 (3): 629–631. Bibcode:1991MTA....22..629T. doi:10.1007/BF02670284. ISSN 1543-1940. S2CID 96556847.
- ^ Rohm and Haas (2015-04-16). "Coating composition with improved liquid stain repellency World Patent WO 2015/051514 A1" (PDF).