In organic chemistry, the Ferrario–Ackermann reaction or simply the Ferrario reaction is a name reaction that allow for the generation of phenoxanthiine from diphenyl ether and sulfur in the presence of aluminum chloride catalyst.[1][2][3][4][5][6]
| Ferrario–Ackermann reaction | |
|---|---|
| Named after | M. E. Ferrario Fritz Ackermann |
| Reaction type | Ring forming reaction |
References
edit- ^ Ferrario, E. (January 1911). "Preparation of phenoxathiin from diphenyl ether and sulfur". Bulletin de la Société Chimique de France. 9 (4): 536–537.
- ^ Germany 234743, Fritz Ackermann, "Verfahren zur Darstellung von Phenoxthin und dessen Derivaten", published 20 May 1911
- ^ Deasy, Clara L. (1 April 1943). "The Chemistry of Phenoxathiin and its Derivatives". Chemical Reviews. 32 (2): 173–194. doi:10.1021/cr60102a001.
- ^ Suter, C. M.; Maxwell, Charles E. "Phenoxthin [Phenoxathiin]". Organic Syntheses. 18: 64. doi:10.15227/orgsyn.018.0064; Collected Volumes, vol. 2, p. 485.
- ^ Al-Araji, Suad M.; Mohamad, Ayad Ahmed (2 June 201). "Synthesis of New Pyrazoline - Phenoxathiin Derivatives". Baghdad Science Journal. 10 (2): 405–419. doi:10.21123/bsj.2013.10.2.405-419.
- ^ Suter, C. M.; Green, Frank O. (1 December 1937). "Phenoxthin. II. Extension of the Ferrario Reaction". Journal of the American Chemical Society. 59 (12): 2578–2580. doi:10.1021/ja01291a030.
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