Fluoride nitrates are mixed anion compounds that contain both fluoride ions and nitrate ions. Compounds are known for some amino acids and for some heavy elements. Some transition metal fluorido complexes that are nitrates are also known. There are also fluorido nitrato complex ions known in solution.
List
edit| name | formula | mw | crystal system | space group | unit cell Å | volume | density | comment | reference |
|---|---|---|---|---|---|---|---|---|---|
| L-Argininium | L-Arg2+•F−•NO3− | triclinic | P1 | a=5.0130 b=10.6161 c=11.0352 α=87.471 β=86.038 γ=78.157 Z=2 | [1] | ||||
| 2L-Arg2+•F−•3NO3−•HF | orthorhombic | P212121 | a=7.3960 b=12.8672 c=26.990 Z=4 | [1] | |||||
| L-histidine | L-His2+•F−•NO3− | [1] | |||||||
| [Cr(NH3)5F](NO3)2 | [2] | ||||||||
| hexakis(1H-imidazole)-cobalt(ii) fluoride nitrate tetrahydrate | [Co(Im)6][F·NO3•(H2O)4] | hexagonal | P63/m | a 8.972 c 21.077 Z=2 | 1469.3 | 1.402 | pink | [3] | |
| [Co(NH3)4(OH)F]NO3 | [4] | ||||||||
| [Co(NH3)5F](NO3)2 | [5] | ||||||||
| [Co(NH3)6]F(NO3)2 | [4] | ||||||||
| [Co(en)2F2]NO3 | [4] | ||||||||
| [As(ONO2)4]+[AsF6]− | pale yellow; hydroscopic | [6] | |||||||
| [Zr2F3OH(NO3)2(H2O)5]2+ | in solution | [7] | |||||||
| SnF2(ONO2)2 | [6] | ||||||||
| SnF3(ONO2) | stable < 40 °C; hydroscopic | [6] | |||||||
| SbF(ONO2)4 | [6] | ||||||||
| SbF3(ONO2)2 | [6] | ||||||||
| Xenon fluoride nitrate | FXeONO2 | monoclinic | a = 4.6663 b = 8.799 c = 9.415 β = 90.325° | 386.6 | 3.648 | ||||
| CsFHONO2 | [8] | ||||||||
| [HfF4NO3]− | in solution | [7] | |||||||
| [HfF3(NO3)2]− | in solution | [7] | |||||||
| Hg3O2(NO3)F | orthorhombic | Pnma | a=7.547 b=10.990 c=6.9906 | birefringence Δn = 0.23 @ 1064 nm | [9] | ||||
| Pb3F5NO3 | triclinic | P1 | a 7.3796 b 12.147 c 16.8549, α 100.46° β 90.076° γ 95.517° | layered; stable to 450 °C | [10][11] | ||||
| Pb(OF)Cu3(SeO3)2(NO3) | trigonal | R3m | a 6.6973 c 18.5548 Z=3 | 720.75 | 5.175 | yellow; stable to 400 °C | [12] | ||
| PbCdF(SeO3)(NO3) | orthorhombic | Pca21 | a=11.121 b=10.366 c=5.3950 | NLO 2.6×KDP; band gap 4.42 eV | [13] | ||||
| BaPb2F5NO3 | [14] | ||||||||
| Bi2OF3(NO3) | hexagonal | P63/m | band gap 3.5 eV | [15] | |||||
| Bi6O6F5(NO3) | trigonal | R3 | band gap 4.0 eV | [15] | |||||
| [(UO2)4F13][Sr3(H2O)8](NO3)·H2O | 1814.13 | triclinic | P1 | a = 10.793, b = 10.918, c = 13.231 α = 92.570°, β = 109.147°, γ = 92.778° Z = 2. | 1468.1 | 4.105 | yellow | [16] |
References
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- ^ Merabet, K. E.; Burriel, Ramón; Carlin, Richard L. (1988-12-01). "Magnetochemistry of chromium(III): Linear-chain – to – simple-cubic crossover magnetic interactions in several halopentammines". Physical Review B. 38 (16): 11589–11592. doi:10.1103/PhysRevB.38.11589. ISSN 0163-1829.
- ^ Jian, Fang Fang; Liu, E.; Ma, Jun Ying (2018). "Interesting fluorine anion water clusters [F − ·(H 2 O) n ] in metal complex crystals". CrystEngComm. 20 (27): 3849–3857. doi:10.1039/C8CE00532J. ISSN 1466-8033.
- ^ a b c Chan, S. C.; Poon, C. K. (1966). "Preparation, properties, and isomerisation of aquofluorobis(ethylenediamine)cobalt(III) cations". Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 146–150. doi:10.1039/j19660000146. ISSN 0022-4944.
- ^ Balt, S.; Pothoff, G. F. (April 1975). "A conductance study of some cobalt(III) complexes in liquid ammonia". Journal of Solution Chemistry. 4 (4): 359–367. doi:10.1007/BF00650393. ISSN 0095-9782. S2CID 97374902.
- ^ a b c d e Weidlein, Johann; Dehnicke, Kurt (September 1965). "Über die Fluoridnitrate der Elemente Arsen, Antimon und Zinn". Chemische Berichte. 98 (9): 3053–3059. doi:10.1002/cber.19650980939. ISSN 0009-2940.
- ^ a b c Bertoli, Alexandre C.; Miguita, Ana Gabriella C.; Mingote, Raquel M.; Augusti, Rodinei; Duarte, Hélio A. (2021-03-26). "Unveiling the Zirconium and Hafnium Speciation in Fluoride‐Nitric Acid Solutions by Paper Spray Ionization Mass Spectrometry Combined with DFT Calculations". European Journal of Inorganic Chemistry. 2021 (12): 1175–1185. doi:10.1002/ejic.202001140. ISSN 1434-1948. S2CID 233628149.
- ^ Al-Zamil, Nabila; Delf, Brian W.; Gillard, R.D. (January 1980). "The fluoro-nitrato-hydrogenate(I) anion, [F··H··ONO2]−". Journal of Inorganic and Nuclear Chemistry. 42 (8): 1117–1122. doi:10.1016/0022-1902(80)80420-9.
- ^ Lv, Yi-Lei; Huai, Lei; Wei, Yu-Long; Ma, Liang; Wei, Yue-Qi; Liu, Wenlong; Tang, Ru-Ling (2023). "Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy". Inorganic Chemistry Frontiers. 10 (16): 4845–4853. doi:10.1039/D3QI01146A. ISSN 2052-1553.
- ^ Rogow, David L.; Russell, Matthew P.; Wayman, Lora M.; Swanson, Claudia H.; Oliver, Allen G.; Oliver, Scott R. J. (2010-02-03). "Hydrothermal Synthesis and Characterization of Three Cationic Inorganic−Organic Hybrid Materials Based on Lead Fluoride". Crystal Growth & Design. 10 (2): 823–829. doi:10.1021/cg9011923. ISSN 1528-7483.
- ^ Tran, Dat T.; Zavalij, Peter Y.; Oliver, Scott R. J. (2002-04-01). "Pb 3 F 5 NO 3 , a Cationic Layered Material for Anion-Exchange". Journal of the American Chemical Society. 124 (15): 3966–3969. doi:10.1021/ja017333w. ISSN 0002-7863. PMID 11942835.
- ^ Zhang, Mengsi; Zhao, Zhiying; Zhang, Wanwan; Li, Jinyang; Huang, Xiaoying; He, Zhangzhen (2020). "Pb(OF)Cu 3 (SeO 3 ) 2 (NO 3 ): a selenite fluoride nitrate with a breathing kagomé lattice". Chemical Communications. 56 (80): 11965–11968. doi:10.1039/D0CC03684F. ISSN 1359-7345. PMID 33033813. S2CID 222235842.
- ^ Ma, Yun-Xiang; Hu, Chun-Li; Li, Bing-Xuan; Kong, Fang; Mao, Jiang-Gao (2018-09-17). "PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units". Inorganic Chemistry. 57 (18): 11839–11846. doi:10.1021/acs.inorgchem.8b02044. ISSN 0020-1669. PMID 30160946. S2CID 52136440.
- ^ CHARKIN, DMITRI O. (2019). "NEW STRUCTURAL ANALOGIES AMONG LAYERED NITRATES AND HALIDES: SYNTHESIS AND STRUCTURE OF A NEW SILLéN-DERIVED FLUORIDE NITRATE, BAPB2F5NO3".
- ^ a b Cho, Eun Jeong; Oh, Seung-Jin; Jo, Hongil; Lee, Junsu; You, Tae-Soo; Ok, Kang Min (2019-02-04). "Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties". Inorganic Chemistry. 58 (3): 2183–2190. doi:10.1021/acs.inorgchem.8b03343. ISSN 0020-1669.
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