Glycerine acetate is a mixture of esters produced from the esterification of glycerol (1) with acetic acid. This reaction produces five congeners:
- the two monoacetylglycerols / MAG / monoacetin (2 and 3)
- the two diacetylglycerols / DAG / diacetin / glyceryl diacetate (4 and 5)
- the one triacetalglycerol / TAG / triacetin (6)
R = H or CH3C(=O)
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Other names
glycerol acetate
glyceryl acetate 1,2,3-propanetriol acetate | |
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3D model (JSmol)
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ECHA InfoCard | 100.014.216 |
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Properties | |
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Molar mass | Variable |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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In addition, two of the congeners, 2 and 4, are chiral and can exist in either of two enantiomeric forms.
Uses
editDAG and TAG can be used as fuel additives for improving the cold and viscosity properties of biodiesel or the antiknocking properties of gasoline.[1]
Notes
edit- ^ J. A. Melero; R. vanGrieken; G. Morales; M. Paniagua (2007). "Acidic Mesoporous Silica for the Acetylation of Glycerol: Synthesis of Bioadditives to Petrol Fuel". Energy & Fuels. 21 (3): 1782–1791. doi:10.1021/ef060647q.