Holmium(III) selenide is an inorganic compound with the chemical formula Ho2Se3.
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| Ho2Se3 | |
| Molar mass | 566.774 g·mol−1 |
| Appearance | brown[1] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preparation
editHolmium(III) selenide can be obtained from the reaction of holmium and selenium (in the presence of iodine):[2]
- 2 Ho + 3 Se → Ho2Se3
It can also be prepared by reacting holmium oxide and hydrogen selenide at high temperature.[3]
- Ho2O3 + 3 H2Se → Ho2Se3 + 3 H2O
Properties
editHolmium(III) selenide can form orthorhombic AgHoSe2 in the binary system of silver selenide.[4]
References
edit- ^ K.-J. Range, Ch. Eglmeier (August 1991). "Crystal data for rare earth sesquiselenides Ln2Se3 (Ln ≡ Ho, Er, Tm, Yb, Lu) and structure refinement of Er2Se3". Journal of the Less Common Metals. 171 (1): L27–L30. doi:10.1016/0022-5088(91)90254-2. Retrieved 2023-06-13.
- ^ M.A. Bespyatov, A.E. Musikhin, V.N. Naumov, L.N. Zelenina, T.P. Chusova, R.E. Nikolaev, N.G. Naumov (March 2018). "Low-temperature thermodynamic properties of holmium selenide (2:3)". The Journal of Chemical Thermodynamics. 118: 21–25. doi:10.1016/j.jct.2017.10.013. Retrieved 2023-06-13.
{{cite journal}}: CS1 maint: multiple names: authors list (link) - ^ Guittard, Micheline; Benacerraf, A.; Flahaut, J. Selenides L2Se3 and L2Se4 of rare earth elements. Ann. Chim. (Paris), 1964. 9 (1-2): 25-34. CAN61: 38017.
- ^ Julien-Pouzol, M.; Guittard, M. Crystallochemical study of the ternary silver-rare earth-sulfur or selenium compounds situated along the silver chalcogenide-lanthanide(III) chalcogenide binary systems. Annales de Chimie (Paris, France), 1973. 8 (2): 139-145. ISSN 0151-9107.