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Amateur chemistry

(Redirected from Home chemistry)

Amateur chemistry or home chemistry is the pursuit of chemistry as a private hobby.[1] Amateur chemistry is usually done with whatever chemicals are available at disposal at the privacy of one's home. It should not be confused with clandestine chemistry, which involves the illicit production of controlled drugs.[a] Notable amateur chemists include Oliver Sacks and Sir Edward Elgar.[2][3]

History

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Origins

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Amateur chemistry shares its early history with that of chemistry in general. Pioneers of modern chemistry such as Robert Boyle and Antoine Lavoisier were gentlemen scientists who pursued their research independently from their source of income.[4][5] Only with the coming of the Industrial Revolution, and the rise of universities as research institutions, did any significant distinction between amateurs and professionals emerge. Nevertheless, amateur progress lasted well into the 19th century. For example, in 1886, Charles Martin Hall co-invented the Hall-Héroult process for extracting aluminium from its oxide whilst working in a woodshed behind his family home.[6] The history of amateur chemistry ties in well with that of chemistry in general. The history of chemistry represents a time span from ancient history to the present. By 1000 BC, civilizations used technologies that would eventually form the basis to the various branches of chemistry. These processes include extracting metals from ores, making pottery and glazes, fermenting beer and wine, extracting chemicals from plants for medicine and perfume, rendering fat into soap, making glass, and making alloys like bronze.

Chemistry as a hobby

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Throughout much of the 20th century, amateur chemistry was an unexceptional hobby, with high-quality chemistry sets readily available, and laboratory suppliers freely selling to hobbyists. For example, Linus Pauling had no difficulty in procuring potassium cyanide at the age of eleven.[2] Many academics, from researchers to university professors, and even Nobel prize laureates, have acknowledged that at least part of their interest in sciences could be traced back to chemistry sets and home labs when they were young. These include Dorothy Hodgkin,[7] Robert F. Curl,[8] George A. Olah,[9] Rudolph A. Marcus,[10] Louis J. Ignarro,[11] Richard Schrock,[12] Roger Y. Tsien,[13][14] William D. Phillips,[15] Steven Weinberg[16] Peter Licence,[17] etc. However, due to increasing concerns about terrorism, drugs, and safety, suppliers became increasingly reluctant to sell to amateurs, and chemistry sets were steadily toned down.[18][19] This trend has gradually continued, leaving hobbyists in many parts of the world without access to most reagents.[20]

Even as recently as 2023, amateur chemists on forums and YouTube channels have been credited by academic researchers for suggesting and discussing novel viable synthetic routes before full investigations by the latter.[21]

Usefulness as a learning and work training tool

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Home-based chemistry labs were explored as a way to remotely teach students during the COVID-19 pandemic, especially since many local and state-level governments across the world imposed lockdowns or other types of restrictions to contain the spread of the virus.[22][23][24]

Notable amateur chemists

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Restrictions

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Whilst the hobby is probably legal in most jurisdictions,[b] the relationship between amateur chemists and law enforcement agencies is often fraught. Hobbyists are often affected by laws intended to fight drugs and terrorism. Furthermore, many chemical supply houses refuse to sell to amateurs, with such policies sometimes being stated openly.[35][36] Even though the regulations discussed in this section may affect professional and academic laboratories (e.g. business and universities), private individuals, or both, amateur chemists are still affected by those addressed to the former ones, since they usually contain clues that explain the behaviour of these chemical suppliers. Medium-sized suppliers and multinationals have whole departments, sometimes named Compliance or Regulatory affairs, tasked with periodically checking and implementing new regulations regarding chemicals on their companies.

Canada

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In Canada, a wide range of basic laboratory reagents such as nitric acid and hydrogen peroxide are restricted as "explosives precursors".[37] Two of the main legal texts in Canada restricting the sale of certain chemicals are the Explosives Act,[38] and the Explosives Regulations, 2013 (SOR/2013-211).[39] Part 20 of the latter restricts the sale, acquisition, and storage of ten explosives precursors, namely, ammonium nitrate in solid form and with a nitrogen concentration >=28%, hydrogen peroxide >=30% conc., nitromethane, potassium chlorate, potassium perchlorate, solid sodium chlorate, nitric acid >= 75% conc., potassium nitrate, mixtures of potassium nitrate and sodium nitrate, and solid sodium nitrate. In 2021, the Canada Gazette published an amendment proposal to the Explosives Regulations, 2013 [1], which suggested measures including the classification of precursors into three tiers, and the addition of calcium ammonium nitrate, hexamethylenetetramine, aluminium powder, and acetone to the precursors list.

In late 2008, Lewis Casey, an 18-year-old college student from Saskatchewan, was arrested for owning a small chemistry lab in his family's garage. After the raid, the police initially claimed that it was a meth lab, but withdrew the drug charge a few days later.[40][41] The Crown withdrew criminal charges against him on Oct. 13.[42]

European Union

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In the EU, regulations regarding reagent restrictions can be classified in several different sets: dual-use goods, substances in the Schedules 1, 2 and 3 of the CWC, substances on the Common Military List, hazardous chemicals (as defined by Prior Informed Consent Regulation), chemicals subject to the anti-torture regulation, chemicals that cannot be exported to given countries due to sanctions and embargoes, explosives precursors and drug precursors.[43] Those regulations may contain provisions affecting one or more types of "agents" (e.g. manufacturers, resellers, distributors, etc.), end users, or both. Reagent manufacturers typically require customers to sign an end user declaration before accepting and processing the sale of a chemical listed on these schedules.

One of the cornerstones of EU legislation on hazardous chemicals is the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), which is defined in Regulation (EC) No. 1907/2006[44]

On the topic of explosives precursors, Regulation (EU) No. 98/2013[45] introduced rules to harmonize the sale, possession and use of several substances across all EU countries. It requires that each member state must define a National Contact Point to which economic operators must report suspicious transactions, thefts, and disappearances of significant quantities involving scheduled substances.

On 1 February 2021, Regulation (EU) 2019/1148[46] amended REACH and repealed Regulation (EC) No. 98/2013. The newer one is designed to ban the sale and possession of explosives precursors by members of the general public above given concentrations. Any individual can own these chemicals provided their concentration is below or equal to a given limit (e.g. for sulfuric acid up to 15% conc. in weight). Said upper limit allowed can be increased (e.g. for sulfuric acid, up to 40% conc.) by requesting a license to the national authority. Professional users are not affected by these thresholds. However, professional users and members of the general public must also report significant disappearances and thefts of restricted explosives precursors within 24 hours of detection to the national contact point.

List of scheduled explosives precursors on the EU
Category Substance Upper limit w/o license Upper limit w/ license
Restricted Nitric acid 3% w/w 10% w/w
Hydrogen peroxide 12% w/w 35% w/w
Sulfuric acid 15% w/w 40% w/w
Nitromethane 16% w/w 100% w/w
Ammonium nitrate 16% w/w of nitrogen in relation to ammonium nitrate (4) No licensing permitted
Potassium chlorate 40% w/w No licensing permitted
Potassium perchlorate 40% w/w No licensing permitted
Sodium chlorate 40% w/w No licensing permitted
Sodium perchlorate 40% w/w No licensing permitted
Reportable Hexamine Does not apply Does not apply
Acetone
Potassium nitrate
Sodium nitrate
Calcium nitrate
Calcium ammonium nitrate
Magnesium, powders
Magnesium nitrate hexahydrate
Aluminium, powders

Drug precursors: Regulation (EC) No 273/2004[47] Regulation (EC) No 111/2005[48] Commission Delegated Regulation (EU) 2015/1011 of 24 April 2015[49]

Regulation (EC) No 273/2004 was amended by Regulation (EU) No 1258/2013,[50] which introduced the term "user", and split reagents on category 2 into categories 2A and 2B

List of scheduled drug precursors on the EU
Category Substance Threshold
Category 1
Subcategory 2A 0,1 kg
100 l
Subcategory 2B 1 kg
1 kg
0,5 kg
100 kg
Category 3

Regarding waste management, it might be considered acceptable to dispose of some acidic or basic solutions by neutralizing and flushing them down the drain, provided that they don't contain other hazardous substances and the reaction products aren't hazardous either.[51] However, other types of wastes must be disposed by handling them to an authorised waste management entity in an appropriate container, usually HDPE jerry cans. Such entities require each container received to be appropriately labeled with several details, which may include GHS hazard pictograms, the EWC (European Waste Catalogue) code, also called LoW (List of Waste) code, that identifies the type of waste. These codes were defined by the Commission Decision 2000/532/EC,[52] later amended by Commission Decision 2014/955/EU.[53] Laboratories typically classify[54][55] their wastes into those containing halogenated solvents (such as chloroform and dichloromethane, EWC 14 06 02), non-halogenated solvents (like hexane and toluene, EWC 14 06 03 or 20 01 13), non-halogenated mineral oils (e.g. from rotary vane vacuum pumps, EWC 13 02 05, or 13 02 08), contaminated materials (including pipette tips, gloves, filter paper, EWC 15 02 02), contaminated glass (e.g. broken glassware, EWC 15 01 10), discarded reagents (EWC 16 05 06)

Several chemicals, especially solvents, are subject to taxes for certain uses. One such example is ethanol, due to its potential use in alcoholic drinks. Both Council Directive 92/81/EEC,[56] and Council Directive 2003/96/EC,[57] which repealed the former, impose taxes on several hydrocarbons that can be used as fuels. These hydrocarbons include hexane, heptane, isooctane (CN 2901 10 for most saturated acyclic hydrocarbons), petroleum ether (CN 2710 12 25), cyclohexane (CN 2902 11), benzene (CN 2902 20), toluene (CN 2902 30) and xylenes (o-Xylene: CN 2902 41, m-Xylene: CN 2902 42, p-Xylene: CN 2902 43, and a mix of these isomers: CN 2902 44), among others.

Germany

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Regulations regarding hazardous chemicals in this country include the Explosives Act (Sprengstoffgesetz), and the Hazardous Substances Ordinance (Gefahrstoffverordnung, abbreviated as GefStoffV), which is part of the Chemicals Act (Chemikaliengesetz, abbreviated as ChemG). Another one is the Chemicals Prohibition Ordinance (Chemikalien-Verbotsverordnung, abbreviated as ChemVerbotsV). Additionally, Regulation (EU) 2019/1148 was transposed into German law in the Precursor Act (Ausgangsstoffgesetz, Precursor Act, abbreviated as AusgStG).

German amateur chemists have been raided by the police, despite not being in the possession of illegal chemicals.[58][59]

Ireland

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Regarding explosives precursors, Regulation (EU) 98/2013, was transposed in the Statutory Instrument No 611/2014.[60]

Italy

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In Italy, regulations regarding explosives precursors have been approved as the Ministry of the Interior's Circolare 557/PAS/U/004997/XV.H.MASS(53)5,[61] titled Identificazione e tracciabilità degli esplosivi per uso civile: - Indicazioni operative e gestione delle scorte. Regulation (EU) 2019/1148 was implemented through the Legge 23 dicembre 2021, n. 238, whose article 13 modifies the Decreto Legislativo 14 settembre 2009, n. 133, adding a whole chapter to the latter (Chapter II, after article 17).

Portugal

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On the topic of explosives precursors, Regulation (EU) 98/2013, was transposed into the Portuguese legal system as the Decree Law 56/2016, of 29th of August.[62] This Decree Law was, in turn, repealed by Decree Law 62/2021, of 26th of July,[63] which transposes Regulation (EU) 2019/1148.

Spain

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Since the 1940s, chemistry sets for kids have been available on the Spanish market, some of these including "Quimicefa", manufactured by the Valencian company Celulosa Fabril SA (CEFA), and later on by CEFA Toys SA; "Cheminova", by Jugetes Mediterráneo SA, from Aldaia, Valencia, later acquired by MB-Hasbro; "La magia de la ciencia: Química" by the Madrilenian company Grupo Anaya SA; and "Quimex", by Quimex, Granollers, Catalonia.[64] On January 3, 1994, Eduardo Rey Díaz, a 13-year-old boy from Getxo, Basque Country, was at a friend's house doing an experiment using materials from a chemistry set. After approaching the open end of a graduated cylinder containing a flammable substance to an open flame, a deflagration occurred, which left him with severe burns in his hands and face. The manufacturer was sued and later fined.[65][66][67] Less than a year and a half later, in December 22, 1995, an 11-year-old boy and his 8-year-old sister from Galicia, suffered third and second-degree burns in 70 and 60% of their bodies. After watching them while they performed an experiment using another set from the same company, their mother ordered them to put the game away and left the room, but they kept playing. As a result of incorrectly handling the set, a deflagration occurred, and the company was sued and charged again.[68][69] By the 2010s, many of them were no longer available. Despite these incidents, the positive impact of chemistry sets on kickstarting the curiosity of children, some of whom would later become professional scientists and engineers, has been acknowledged.[70]

According to the Resolution of 20 November 2013 of the Spanish State Secretariat for Security, the National Contact Point for this country is the Intelligence Center for Counter-Terrorism and Organized Crime (CITCO). Before the transposition of Regulation (EU) 2019/1148 into Spanish Law 25/2022, of 1st of November,[71] explosives precursors were addressed[72] by Law 8/2017, of 8 November, on explosives precursors,[73] which the former repealed and replaced. On the other hand, drug precursors[74] are addressed by the Law 4/2009, of 15 June, on drug precursors control, and the Royal Decree 129/2017, of 24 February, by which the Drug Precursors Control Regulation is approved. Every year, operators of drug precursors are required to fill a questionnaire, titled "Annual questionnaire for the declaration of operations with scheduled chemicals" ("Cuestionario anual de declaración de operaciones con sustancias químicas catalogadas" in Spanish), stating in-depth details regarding purchases, sales, and operations involving substances listed in the Categories 1, 2 and 3 of the Regulation (EC) No 273/2004 during that year. The first ones (purchases and sales) must include information on the quantities, full contact details and address, and NIF or DNI number of the suppliers or buyers.[75][76][77]

Additionally, the storage of chemicals, including reagents, flammable solvents, and gas cylinders, is regulated by Royal Decree 656/2017, of 23 June.[78] Industrial establishments also need to take into account Royal Decree 2267/2004, of 3 December, by which the fire safety regulations for industrial establishments are approved.

In general, the topic of hazardous waste management is discussed on Law 22/2011, of 28 July, on wastes and contaminated soils,[79] which was repealed and replaced by Law 7/2022, of 8 April.[80] The transport of wastes is regulated as well, by the Royal Decree 553/2020, of 2 June.[81] Business that meet the definition of 'waste producers' or 'waste management facilities' need to obtain an Environmental Identification Number (Número de identificación medioambiental, NIMA). Said numbers are issued by the government of the autonomous community where the business is located.

Several EU regulations regarding special taxes have been transposed to Spanish regulations in Law 38/1992, of 28 December, of Special Taxes.[82] It was later extended by the Royal Decree 1165/1995, of 7 July, by which the Regulation on Special Taxes is approved.[83] According to article 79 of the latter, even though ethanol is subject to a special tax due to its potential use in spirits, its use in scientific research can be exempted. This exemption requires obtaining an Activity and Establishment Code (Código de Actividad y del Establecimiento, CAE), which allows to request a refund from the Tax Agency (Agencia Tributaria) by submitting a filled form model 572. Said code is composed of 13 characters, the first two being "ES", then three zeros, two characters identifying the local management office, two more characters for the activity, a sequential inscription number made up of three characters, and finally a control letter.[84] A refund can also be requested for the special tax on hydrocarbons as long as they aren't used as fuels, according to article 109 the same Royal Decree (1165/1995, of 7 July).[83]

Norway

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In September 2018, a 29-year-old physician and amateur chemist and his girlfriend were arrested at their home on in Nord-Jæren, two days after inquiring a local pharmacy about the availability of 35% hydrogen peroxide.[85] He explained[86] that he had an accident while camping, suffering a wound that he stitched himself. Being a physician and seeing the effect of flame-sterilizing on his surgical instruments, he was looking for a milder alternative that could also be used to disinfect wounds. However, his enquiry triggered the submission of an alert to KRIPOS, which sent a few police officers to the house. These officers would, in turn, find the chemicals from his lab, and arrest him.

One law in this country that regulates flammable chemicals, gas cylinders, and explosive substances is the Fire and Explosion Protection Act (Brann- og eksplosjonsvernloven).

United Kingdom

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In the UK it is a criminal offence for members of the general public to purchase, and for business to sell, certain types of poisons or explosives precursors to those of the former group without a valid EPP license.[87] Purchasing substances on this list is restricted since 26 May 2015, and its possession is also restricted since 3 March 2016.[88] Since July 1st 2018, the acquisition of sulphuric acid in concentrations above 15% in weight by members of the general public also requires an EPP licence, which has impacted lead-acid battery sellers.[89][90]

On 26 February 2022, three men, aged between 20 and 25, were arrested in Wigan on suspicions they had violated Section 4 of the Explosives Act. A search warrant had found several chemicals on their flat. Soon after, the eldest was released on bail, and the other two were also released under investigation. Two years later, in May 2024, the investigation concluded that they had just been doing amateur chemistry, and none of the three were charged.[91][92][93]

Some regulations regarding restricted chemicals in this country include the Poison Act 1972, which was amended by the Deregulation Act 2015, and the Control of Poisons and Explosives Precursors Regulations 2015.[94][88] On 1 October 2023, a new set of amendments to the Poisons Act 1972, known as the "Control of Poisons and Explosives Precursors Regulations 2023", came into force. According to these amendments, hexamine, hydrochloric acid in concentrations 10% w/w and higher, and ammonium nitrate with a nitrogen content of 16% or higher, and phosphoric acid in 30% w/w concentration or higher are now considered "regulated explosives precursors" instead of either "reportable explosives precursors" or "reportable poisons". The sulfides of aluminium, calcium, magnesium, sodium and zinc, as well as arsenic and its compounds are now considered "regulated poisons" rather than just "reportable poisons". Finally, sulfur, all metal phosphides, all metal sulfides, all metal polysulfides and sodium hypochlorite solutions above 6% available chlorine have been added to the "reportable poisons" list.[95]

Directly related to the above is the Offensive Weapons Act 2019, which forbids the sale of corrosive chemicals to minors, as well as their shipment to residential addresses or lockers.[96]

United States

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In the United States, the Drug Enforcement Administration maintains lists regarding the classification of illicit drugs, which contain chemicals that are used to manufacture the controlled substances/illicit drugs. The lists are designated within The Controlled Substances Act, 21 U.S.C. § 802, paragraphs 34 (list I) and 35 (list II). Additionally, some regions have stringent regulations concerning the ownership of chemicals and equipment. For example, Texas once required the registration of even the most basic laboratory glassware.[97] However, this requirement was repealed on June 6, 2019.[98]

Several states define hazardous waste management laws, one example being the California Hazardous Waste Control Law (Cal. Health and Safety Code § 25100 -§ 25259 ).[99][100] Passed in 2017, California Assembly Bill (AB) 245 raised the maximum administrative and civil penalties for violations of said law from $25,000 per day of noncompliance to $70,000 per day.[101][102]

United Nuclear, an amateur science supplier based in New Mexico was raided in June 2003 at the behest of the U.S. Consumer Product Safety Commission,[1] and subsequently fined $7,500 for "Selling Illegal Fireworks Components".[103]

In 2008, the home laboratory of Victor Deeb, a retired chemist, was raided and dismantled[104][105][106][107][108]

Almost a year later, Jack Robison,[109][110] then a 19-year-old chemistry student at the Holyoke Community College, received a visit from members of the Massachusetts State Police, the Bureau of Alcohol, Tobacco, Firearms and Explosives, and the FBI. They asked him questions regarding several videos on small-scale experiments he had posted two years earlier on YouTube involving energetic materials, including PETN, potassium nitrate, and RDX, and wanted to check his mother's house basement. He was initially charged with three counts of malicious explosion and one count of possessing explosives with the intent to harm people or property, facing up to 60 years in prison, but was found not guilty after trial.

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Amateur chemistry has been depicted multiple times in mass media, through different formats. The protagonists or other characters of animated television series like Dexter's Laboratory, Tracey McBean and The Simpsons (e.g. on the Haw-Haw Land episode) are sometimes displayed performing chemistry experiments in their own laboratories.

On the other hand, there are several meme-YouTube channels focused in chemical experiments. Most of them are run by amateurs, mostly by professional communicators and organizations, though there are a small sample of professional chemists.

See also

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Notes

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  • a. ^ The terms "amateur chemistry" and "clandestine chemistry" are not rigidly defined, and may depend upon context. For clarity, this article defines "amateur chemistry" to be the practice of chemistry as a hobby, and not as the means to an illegal end. While clandestine chemistry is often amateur chemistry, not all amateur chemistry is clandestine chemistry.
  • b. ^ The legal status of amateur chemistry per se is somewhat ambiguous. Whilst there appears to be no legislation explicitly banning the activity, there is also little evidence to confirm its legality.

References

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  1. ^ a b c Silberman, Steve (June 2006), "Don't Try This at Home", Wired, Wired Magazine, retrieved 2008-07-18
  2. ^ a b c Sacks, Oliver (2001), Uncle Tungsten: Memories of a Chemical Boyhood, Vintage Books, ISBN 0-375-40448-1
  3. ^ a b Weintraub, Stanley (2002), "Shaws's Musician: Edward Elgar" (PDF), Annual of Bernard Shaw Studies, 22: 1–18, doi:10.1353/shaw.2002.0017, S2CID 161277419, retrieved 2008-07-21
  4. ^ Rosenfeld, Louis (1999), Four Centuries of Clinical Chemistry, Taylor and Francis, ISBN 90-5699-645-2
  5. ^ University of Wisconsin - General Chemistry - The Law of Conservation of Mass, archived from the original on 2008-06-24, retrieved 2008-07-19
  6. ^ Emsley, John (2001), Nature's Building Blocks: An A-Z Guide to the Elements, Oxford University Press, pp. 451–53, ISBN 0-19-850341-5
  7. ^ "Dorothy Hodgkin FRS - Scientists with disabilities | Royal Society". royalsociety.org. Retrieved 1 August 2021.
  8. ^ Shampo, Marc A.; Kyle, Robert A.; Steensma, David P. (August 2010). "Robert F. Curl Jr—Nobel Laureate in Chemistry". Mayo Clinic Proceedings. 85 (8): e58. doi:10.4065/mcp.2010.0448. PMC 2912751. PMID 20704028.
  9. ^ Jacolby, Mitch (14 March 2005). "A LOVE AFFAIR WITH CHEMISTRY: Nobel Laureate George A. Olah has spent nearly six decades in the service of chemistry". Chemical & Engineering News Archive. 83 (11): 37–40. doi:10.1021/cen-v083n011.p037. Retrieved 1 August 2021.
  10. ^ "Laureate - Rudolph A. Marcus". Lindau Nobel Mediatheque. Retrieved 1 August 2021.
  11. ^ "Laureate - Louis J. Ignarro". Lindau Nobel Mediatheque. Retrieved 1 August 2021.
  12. ^ Nightingale, Sarah (24 July 2018). "Nobel laureate to join UC Riverside faculty". University of California. Retrieved 1 August 2021.
  13. ^ "Roger Y. Tsien – Biographical". NobelPrize.org. Nobel Prize Outreach AB. Retrieved 31 January 2023.
  14. ^ Rink, Timothy J.; Tsien, Louis Y.; Tsien, Richard W. (October 2016). "Roger Yonchien Tsien (1952–2016)". Nature. 538 (7624): 172. Bibcode:2016Natur.538..172R. doi:10.1038/538172a. PMC 5960232. PMID 27734865.
  15. ^ "The Nobel Prize in Physics 1997". NobelPrize.org. Retrieved 1 August 2021.
  16. ^ D’Agostino, Susan (27 July 2021). "Steven Weinberg, Nobel laureate in physics and Bulletin board member, dies at 88". Bulletin of the Atomic Scientists. Retrieved 1 August 2021.
  17. ^ Haran, Brady (2011). Childhood Chemistry - Viewer Questions (YouTube). Archived from the original on 2021-12-21. Retrieved 2021-08-01.
  18. ^ Fuscaldo, Donna (2007-12-11), The Grinch Who Stole the Chemistry Set, Fox Business, archived from the original on 2007-12-14, retrieved 2008-07-19
  19. ^ Zielinski, Sarah (10 October 2012). "The Rise and Fall and Rise of the Chemistry Set". Smithsonian Magazine. Retrieved 1 August 2021.
  20. ^ Houlton, Sarah. "Hobby chemists". Chemistry World. The Royal Society of Chemistry. Retrieved 22 December 2020.
  21. ^ Klimek, Angelique; Yount, Joseph; Wozniak, Dominique; Zeller, Mattias; Piercey, Davin G. (9 October 2023). "A Laboratory Preparation of High-Purity Calcium Cyanamide". Inorganic Chemistry. 62 (40): 16280–16282. doi:10.1021/acs.inorgchem.3c02235. PMID 37737133.
  22. ^ Andrews, Jessica L.; de Los Rios, Juan Pablo; Rayaluru, Mythreyi; Lee, Seungwon; Mai, Lilly; Schusser, Anna; Mak, Chi H. (14 July 2020). "Experimenting with At-Home General Chemistry Laboratories During the COVID-19 Pandemic". Journal of Chemical Education. 97 (7): 1887–1894. Bibcode:2020JChEd..97.1887A. doi:10.1021/acs.jchemed.0c00483. PMC 7336719. PMID 37556272.
  23. ^ Gilden, Melissa (11 May 2020). "STEM-ucation in the time of the coronavirus". Chemical & Engineering News. 98 (18): 40. doi:10.1021/cen-09818-newscripts. ISSN 0009-2347. S2CID 219442623. Retrieved 15 November 2021.
  24. ^ Al-Soufi, Wajih; Carrazana-Garcia, Jorge; Novo, Mercedes (8 September 2020). "When the Kitchen Turns into a Physical Chemistry Lab". Journal of Chemical Education. 97 (9): 3090–3096. Bibcode:2020JChEd..97.3090A. doi:10.1021/acs.jchemed.0c00745. S2CID 225421160. Retrieved 13 October 2022.
  25. ^ Goertzel (1995), Linus Pauling: A Life in Science and Politics, Basic Books, ISBN 0-465-00672-8
  26. ^ "Biographical Overview". Linus Pauling - Profiles in Science. 12 March 2019. Retrieved 1 August 2021.
  27. ^ Theodore Gray's website, retrieved 2008-07-18
  28. ^ Winners of the Ig Nobel Prize, retrieved 2008-07-18
  29. ^ Theodore Gray's website: 2002 Ig Nobel Prize in Chemistry, retrieved 2008-07-18
  30. ^ Popular Science: Gray Matter column, retrieved 2008-07-18
  31. ^ Hickam, Homer (1998), Rocket Boys: A Memoir, Delacorte Press, ISBN 0-385-33320-X
  32. ^ Sir Edward William Elgar; Amateur Chemist-Composer (PDF), archived from the original (PDF) on 2008-10-03, retrieved 2008-08-10
  33. ^ Andreasson, Karin (7 March 2014). "The first ever selfie, taken in 1839 - a picture from the past". The Guardian. Retrieved 7 September 2024.
  34. ^ Brin, Joseph G. (1 September 2017). "I'm Still Here: Saving The Work Of Robert Cornelius". Hidden City Philadelphia. Retrieved 7 September 2024.
  35. ^ Timstar Laboratory Suppliers Ltd: Ordering information, archived from the original on 2008-05-09, retrieved 2008-07-18
  36. ^ Stratlab Web Shop - Laboratory Supplies - Chemicals and reagents, archived from the original on 2012-02-16, retrieved 2008-08-10{{citation}}: CS1 maint: bot: original URL status unknown (link)
  37. ^ Natural Resources Canada: New Regulations Tighten Controls on Restricted Chemicals, Marketwire, 2008-05-19, retrieved 2008-08-08
  38. ^ Explosives Act, R.S.C. 1985, c. E-17
  39. ^ Explosives Regulations, SOR/2013-211
  40. ^ Newitz, Annalee (27 December 2008). "Teen with Home Chemistry Lab Arrested for Meth, Bombs". Gizmodo. Retrieved 5 October 2021.
  41. ^ Coolican, Lori (26 December 2008). "Student held on explosives charge released: Teen mistakenly arrested for meth production allowed home for holidays". The StarPhoenix. Saskatoon. Retrieved 28 December 2008.
  42. ^ "Criminal case against student chemist implodes". CBC/Radio-Canada. 25 October 2009. Retrieved 7 October 2021.
  43. ^ Arnés-Novau, Xavier; Sevini, Filippo (2021). Export control handbook for chemicals (2021 edition) (2021 ed.). Luxembourg: Publications Office of the European Union. ISBN 978-92-76-36153-4. Retrieved 9 November 2021.
  44. ^ Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC
  45. ^ Regulation (EU) No 98/2013 of the European Parliament and of the Council of 15 January 2013 on the marketing and use of explosives precursors
  46. ^ Regulation (EU) 2019/1148 of the European Parliament and of the Council of 20 June 2019 on the marketing and use of explosives precursors, amending Regulation (EC) No 1907/2006 and repealing Regulation (EU) No 98/2013
  47. ^ Regulation (EC) No 273/2004 of the European Parliament and of the Council of 11 February 2004 on drug precursors
  48. ^ Council Regulation (EC) No 111/2005 of 22 December 2004 laying down rules for the monitoring of trade between the Union and third countries in drug precursors
  49. ^ Commission Delegated Regulation (EU) 2015/1011 of 24 April 2015 supplementing Regulation (EC) No 273/2004 of the European Parliament and of the Council on drug precursors and Council Regulation (EC) No 111/2005 laying down rules for the monitoring of trade between the Union and third countries in drug precursors, and repealing Commission Regulation (EC) No 1277/2005
  50. ^ Regulation (EU) No 1258/2013 of the European Parliament and of the Council of 20 November 2013 amending Regulation (EC) No 273/2004 on drug precursors Text with EEA relevance
  51. ^ "Entsorgung von Kleinmengen ins Abwasser" [Disposal of small quantities into waste water] (in German). Frieie Universität Berlin. 9 January 2014. Archived from the original on 29 May 2022. Retrieved 28 November 2021.
  52. ^ Commission Decision of 3 May 2000 replacing Decision 94/3/EC establishing a list of wastes pursuant to Article 1(a) of Council Directive 75/442/EEC on waste and Council Decision 94/904/EC establishing a list of hazardous waste pursuant to Article 1(4) of Council Directive 91/689/EEC on hazardous waste (notified under document number C(2000) 1147)
  53. ^ 2014/955/EU: Commission Decision of 18 December 2014 amending Decision 2000/532/EC on the list of waste pursuant to Directive 2008/98/EC of the European Parliament and of the Council
  54. ^ Chemical waste disposal. United Kingdom: Lab Life Tutorials. 2018-10-21 – via YouTube.
  55. ^ Universität Konstanz (14 June 2023). "Disposal of hazardous liquids | Hazardous waste | waste management | Occupational Safety & Occupational Medicine - Health Protection & Environmental Protection | University of Konstanz". www.uni-konstanz.de. Konstanz, Germany. Retrieved 17 June 2023.
  56. ^ Council Directive 92/81/EEC of 19 October 1992 on the harmonization of the structures of excise duties on mineral oils
  57. ^ Council Directive 2003/96/EC of 27 October 2003 restructuring the Community framework for the taxation of energy products and electricity
  58. ^ Winsemann, Bettina (2008-08-02), Von Chemikalien, Aquarianern, Sprengstoffen und Drogen (in German), Telepolis, retrieved 2008-08-08
  59. ^ Winsemann, Bettina (2008-12-21), Terrorfahndung in Kinderzimmern] (in German), Telepolis, retrieved 2008-08-08
  60. ^ European Union (Marketing and Use of Explosives Precursors) Regulations 2014 (Statutory Instrument 611 of 2014). 23 December 2014.
  61. ^ "Identificazione e tracciabilità degli esplosivi per uso civile: - Indicazioni operative e gestione delle scorte" (PDF) (in Italian). Ministero dell'Interno, Dipartimento della pubblica sicurezza. 1 April 2015. Retrieved 11 June 2023.
  62. ^ Decreto-Lei n.º 56/2016, de 29 de agosto [Decree Law 56/2016, of 29th of August.] (Decree Law 165/2016, Série I) (in Portuguese). 29 August 2016. p. 2996-3000.
  63. ^ Decreto-Lei n.º 62/2021, de 26 de julho [Decree Law 62/2021, of 26th of July.] (Decree Law 143/2021, Série I) (in Portuguese). 26 July 2021. p. 3-12.
  64. ^ Villarreal, Antonio (28 December 2012). "Una historia en tres actos del juguete científico en España". Agencia SINC (in Spanish). Spain. Retrieved 24 January 2024.
  65. ^ Pérez González, Carmen (1997). "La Aplicación por parte del juez nacional de las directivas comunitarias no transpuestas en el ordenamiento jurídico español: algunos ejemplos" [The application by the national judge of Community directives not transposed into Spanish law: some examples]. Estudios Sobre Consumo (in Spanish) (43). Ministerio de Sanidad y Consumo: 47–62. hdl:10234/106714. ISSN 0212-9469. Retrieved 24 January 2024.
  66. ^ Guenaga Bidaurrazaga, Aitor (6 June 1996). "Condenado el fabricante de 'Quimicefa' por daños a un niño". El País (in Spanish). Retrieved 24 January 2024.
  67. ^ Guenaga Bidaurrazaga, Aitor (26 March 1996). "El lote del juego 'Quimicefa' hasta 1990 tiene "sustancias peligrosas"". El País (in Spanish). Retrieved 24 January 2024.
  68. ^ Sanjuán Pérez, Antonio (2002). Esto rompe: casos de productos en apuros y gestión de crisis (in Spanish) (1 ed.). A Coruña, Spain: Netibiblo. pp. 33–36. ISBN 978-84-9745-019-5. Retrieved 24 January 2024.
  69. ^ Guenaga Bidaurrazaga, Aitor (6 February 1998). "Segunda condena contra el fabricante del juego Quimicefa". El País (in Spanish). Retrieved 24 January 2024.
  70. ^ Silva Suárez, Manuel (2019). "Presentación: Trazas y reflejos, perspectivas en la historia de la técnica" [Introduction: Traces and reflections, perspectives on the history of technology] (PDF). Técnica e ingeniería en España IX. Trazas y reflejos culturales externos (1898-1973) [Technology and engineering in Spain IX. Traces and external cultural reflections (1898-1973)] (in Spanish). Zaragoza, Spain: Institución "Fernando el Católico". pp. 15–16. ISBN 978-84-7820-814-2. Retrieved 28 January 2024.
  71. ^ Ley 25/2022, de 1 de diciembre, sobre precursores de explosivos [Law 25/2022, of 1st of November, on explosives precursors.] (BOE-A-2022-20184) (in Spanish). February 12, 2022. p. 165096.
  72. ^ "Servicios al Ciudadano - Precursores de Explosivos". Ministerio del Interior (in European Spanish). Archived from the original on 23 May 2022. Retrieved 7 October 2021.
  73. ^ Ley 8/2017, de 8 de noviembre, sobre precursores de explosivos [Law 8/2017, of 8th of November, on explosives precursors.] (BOE-A-2017-12901) (in Spanish). November 9, 2017. p. 107702.
  74. ^ "Servicios al Ciudadano - Precursores de Drogas". Ministerio del Interior (in European Spanish). Archived from the original on 18 May 2022. Retrieved 7 October 2021.
  75. ^ Ministerio del Interior. Secretaría de estado de seguridad. Área de precursores. Registro general de operadores de sustancias químicas catalogadas. (2008). "Cuestionario anual de declaración de operaciones con sustancias químicas catalogadas, incluidas en el Anexo I del Reglamento (CE) 273/2004, sobre medidas de control de sustancias químicas catalogadas susceptibles de desvío para la fabricación ilícita de drogas y en el Anexo I de la Ley 3/1996, de 10 de enero" (in Spanish). Valencia, Spain: Universitat de València. Retrieved 11 June 2023.
  76. ^ "Cuestionario anual de declaración de operaciones con sustancias químicas catalogadas, incluidas en las categorias 1, 2 y 3 del Reglamento de la CE. 273/2004" (PDF). Universidad Complutense de Madrid (in Spanish). Madrid, Spain. 14 March 2016. Retrieved 11 June 2023.
  77. ^ Pérez López, Jose Andrés; Alvariño Poza, Víctor (5 November 2019). "Jornada de control técnico de comercio de precursores de drogas. Marco Regulatorio de Precursores de Drogas. Ámbito nacional" (PDF) (in Spanish). Madrid, Spain: Centro de Inteligencia contra el Terrorismo y el Crimen Organizado (CITCO). Retrieved 11 June 2023.
  78. ^ Real Decreto 656/2017, de 23 de junio, por el que se aprueba el Reglamento de Almacenamiento de Productos Químicos y sus Instrucciones Técnicas Complementarias MIE APQ 0 a 10 [Royal Decree 656/2017, of 23 June, by which the Chemicals Storage Regulation and its Complementary Technical Instructions MIE APQ 0 to 10 are approved.] (BOE-A-2017-8755) (in Spanish). July 25, 2017. p. 65747.
  79. ^ Ley 22/2011, de 28 de julio, de residuos y suelos contaminados [Law 22/2011, of 28 July, on wastes and contaminated soils.] (BOE-A-2011-13046) (in Spanish). July 28, 2011. p. 85650.
  80. ^ Ley 7/2022, de 8 de abril, de residuos y suelos contaminados para una economía circular [Law 7/2022, of 8 Abril, on wastes and contaminated soils for a circular economy.] (BOE-A-2022-5809) (in Spanish). July 4, 2022. p. 48578.
  81. ^ Real Decreto 553/2020, de 2 de junio, por el que se regula el traslado de residuos en el interior del territorio del Estado [Royal Decree 553/2020, of 2 June, by which the transport of wastes within the territory of the State is regulated.] (BOE-A-2020-6422) (in Spanish). June 2, 2020. p. 42222.
  82. ^ Ley 38/1992, de 28 de diciembre, de Impuestos Especiales [Law 38/1992, of 28 December, of Special Taxes.] (BOE-A-1992-28741) (in Spanish). December 29, 1992. p. 44305.
  83. ^ a b Real Decreto 1165/1995, de 7 de julio, por el que se aprueba el Reglamento de los Impuestos Especiales [Royal Decree 1165/1995, of 7 July, by which the Regulation on Special Taxes is approved.] (BOE-A-1995-18266) (in Spanish). July 7, 1995. p. 23028.
  84. ^ Orden EHA/3482/2007, de 20 de noviembre, por la que se aprueban determinados modelos, se refunden y actualizan diversas normas de gestión en relación con los Impuestos Especiales de Fabricación y con el Impuesto sobre las Ventas Minoristas de Determinados Hidrocarburos y se modifica la Orden EHA/1308/2005, de 11 de mayo, por la que se aprueba el modelo 380 de declaración-liquidación del Impuesto sobre el Valor Añadido en operaciones asimiladas a las importaciones, se determinan el lugar, forma y plazo de presentación, así como las condiciones generales y el procedimiento para su presentación por medios telemáticos [Order EHA/3482/2007, of 20 November, by which specific models are approved, several management norms regarding the Special Manufacturing Taxes and the Tax on Retail Sales of Specific Hydrocarbons are revised and updated, and the Order EHA/1308/2005, of 11 May, by which the model 830 for the declaration-settlement of the Value Added Tax on operations assimilated to imports is approved, the place, way and period for its submission is determined, as well as the general conditions and the procedure for its submission through telematic means.] (BOE-A-2007-20637) (in Spanish). December 1, 2007. p. 49509.
  85. ^ Bruland, Tore (4 September 2018). "Samboere pågrepet og bombesiktet – lege forsøkte å kjøpe ulovlig stoff". Rogalands Avis (in Norwegian). Retrieved 11 March 2022.
  86. ^ "Sciencemadness Discussion Board - I went to prison for my chemistry hobby - Powered by XMB 1.9.11". www.sciencemadness.org. Retrieved 18 June 2022.
  87. ^ "Licensing for home users of poisons and explosive precursors". GOV.UK. 3 April 2018. Retrieved 27 December 2020.
  88. ^ a b "Supplying explosives precursors and poisons". GOV.UK. Retrieved 27 December 2020.
  89. ^ "Important UK Announcement: New regulations will change the way motorcycle batteries can be sold". Yuasa. 1 August 2018. Retrieved 27 December 2020.
  90. ^ "Important: New Regulations on the Sale of Motorbike Batteries". Leoch Battery UK. Retrieved 27 December 2020.
  91. ^ Graham, Charles (28 February 2022). "Wigan 'bomb factory' suspects released as inquiries continue". Wigan Today. National World Publishing Ltd. Retrieved 3 June 2024.
  92. ^ Graham, Charles (21 May 2024). "Case closed: Wigan 'bomb factory' probe dropped". Wigan Today. National World Publishing Ltd. Retrieved 3 June 2024.
  93. ^ Britton, Paul (21 May 2024). "Police drop 'suspicious chemicals' probe as 'amateur chemistry enthusiasm' found". Manchester Evening News. Manchester Evening News Media Ltd. Retrieved 3 June 2024.
  94. ^ "The Control of Poisons and Explosives Precursors Regulations 2015". Legislation.gov.uk. Retrieved 27 December 2020.
  95. ^ "The Control of Explosives Precursors and Poisons Regulations 2023". Legislation.gov.uk. Retrieved 19 December 2023.
  96. ^ "Part 1. Acids and corrosive substances | Business Companion". www.businesscompanion.info. Chartered Trading Standards Institute. Retrieved 21 December 2023.
  97. ^ Texas Administrative Code: Title 37, Public Safety And Corrections; Part 1, Texas Department Of Public Safety; Chapter 13, Controlled Substances; Subchapter E, Precursors And Apparatus, archived from the original on 2009-01-07, retrieved 2008-07-19
  98. ^ "Texas SB616 | 2019-2020 | 86th Legislature".
  99. ^ "Defining Hazardous Waste". Department of Toxic Substances Control. CA, USA. January 2022. Retrieved 20 May 2024.
  100. ^ "Hazardous Waste Management". SanDiegoCounty.gov. San Diego, CA, USA. Retrieved 20 May 2024.
  101. ^ "AB 245 - California Assembly (20172018) - Open States". Open States. Retrieved 20 May 2024.
  102. ^ "California Environmental Quality Act Notice of Exemption" (PDF). Department of Toxic Substances Control. Sacramento, CA, USA. Retrieved 20 May 2024.
  103. ^ "New Mexico Company Fined, Ordered To Stop Selling Illegal Fireworks Components" (PDF) (Press release). Consumer Product Safety Commission. 2007-07-20. Retrieved 2006-07-18.
  104. ^ Dayal, Priyanka (9 August 2008). "Chemist allowed to go home, sans his lab". Worcester Telegram & Gazette. Archived from the original on 19 December 2020. Retrieved 11 November 2020.
  105. ^ Austin, Jim (13 August 2008). "Don't Try This at Home". Science Careers Blog. Retrieved 11 November 2020.
  106. ^ Halford, Bethany (10 November 2008). "Underground Science: Chemistry hobbyists face a labyrinth of local and state regulations". Chemical & Engineering News Archive. 86 (45): 38–40. doi:10.1021/cen-v086n045.p038.
  107. ^ "Victor Deeb Obituary (2016) MetroWest Daily News". Legacy.com. Retrieved 28 September 2021.
  108. ^ Dayal, Priyanka (29 October 2008). "Marlboro chemist sues over seizure". Telegram. Worcester Telegram & Gazette Corp. Archived from the original on 28 September 2021. Retrieved 28 September 2021.
  109. ^ Sullivan, S. P. (10 June 2009). "Action/reaction: How Jack Robison's chemistry lab led to an indictment from the DA". MassLive. Advance Local Media LLC. Retrieved 5 October 2021.
  110. ^ Contrada, Fred (27 May 2009). "John Robison of Amherst found innocent of malicious explosion charges". MassLive. Advance Local Media LLC. Retrieved 26 October 2021.

Further reading

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