Borate nitrate

Borate nitrates are mixed anion compounds containing separate borate and nitrate anions.

List

	chem	mw	crystal system	space group	unit cell Å	volume	density	comment	references
	Na₃(NO₃)[B₆O₁₀]								^[1]
	K₃B₆O₁₀NO₃								^[2]
	K₃Na[B₆O₉(OH)₃]NO₃			Pnnm	a=13.208, b=9.107, c=12.325 Z=4				^[3]
	Co₃B₇O₁₃NO₃								^[4]
	[Co(H₂O)₆](NO₃)₂·[Co{B₃O₃(OH)₄}₂(H₂O)₄]·2H₂O								^[5]
	[Ni(H₂O)₆](NO₃)₂·[Ni{B₃O₃(OH)₄}₂(H₂O)₄]·2H₂O								^[5]
	Ni₃B₇O₁₃NO₃								^[4]
	K₇Ni[B₁₈O₂₄(OH)₉](NO₃)₆· (H₃BO₃)	1497.96	trigonal	R3	a=12.2229 c=54.784 Z=6	7088	2.11	green	^[6]
	Cu₃B₇O₁₃NO₃								^[4]
	Zn₃B₇O₁₃NO₃								^[4]
	[Zn(H₂O)₆](NO₃)₂·[Zn{B₃O₃(OH)₄}₂(H₂O)₄]·2H₂O		monoclinic	P2₁/c	a = 11.282, b = 6.5374, c = 17.668, β = 100.981°				^[5]
	Rb₃(NO₃)[B₆O₁₀]								^[2]
	Ag₁₂(B₉O₁₈)(NO₃)₃		hexagonal	P6₃/m	a = 11.2896 c = 11.6693				^[7]
	Cd₃B₇O₁₃NO₃								^[4]
	La[B₅O₈(OH)]NO₃
	La[B₅O₈(OH)]NO₃·2H₂O		monoclinic	P2₁/n	a=6.540, b=15.550, c=10.672, β=90.44° and Z=4				^[8]
cerium(III) aquahydroxidooctaoxidopentaborate nitrate dihydrate	Ce[B₅O₈(OH)(H₂O)]NO₃·2H₂O	455.24	monoclinic	P2₁/n	a=6.444 b=15.572 c=10.745 β=90.395 Z=4	1078.2	2.904	colourless	^[9]
	Pr[B₅O₈(OH)(H₂O)_x]NO₃·2H₂O		monoclinic	P2₁/n	a=6.419, b=15.518, c=10.684, with β=90.54° Z=4	1064.3			^[10]
	Pr₇(BO₃)₃(NO₃)N₃O		hexagonal	P6₃	a=10.6834 c=6.6752 Z=2		6.457	green; contains N(OBO₃)₃ clusters, oxide and nitride	^[11]
	Nd₇(BO₃)₃(NO₃)N₃O		hexagonal	P6₃	a=10.6446 c=6.6339 Z=2		6.664	purplish-blue;contains N(OBO₃)₃ clusters oxide, and nitride;SHG	^[11]
	Nd[B₅O₈(OH)(H₂O)_x]NO₃·2H₂O			P2₁/n	a = 6.4285, b = 15.5258, c = 10.7052, β = 90.39°	1068.44			^[12]
	Sm[B₅O₈(OH)(H₂O)_x]NO₃·2H₂O			P2₁/n	a = 6.4409, b = 15.4199, c = 10.5097, β = 90.33°	1043.79			^[12]
	Lu₂B₂O₅(NO₃)₂·2H₂O		triclinic	P1	a=7.8952, b=9.8862, c=14.6033, α=90.83, β=101.75, γ=110.02° Z=4				^[6]^[13]
	Pb₂(BO₃)(NO₃)	535.20	hexagonal	P6₃mc	a=5.0731 c=13.040 Z=2	290.64	6.116	colourless SHG 9×KDP	^[14]
	[Pb₃(B₃O₇)](NO₃)	828.01		Pnma	a=10.3481 b=7.8908 c=11.2123 Z=4	914.54	6.007	colourless	^[15]

References

^ Ortner, Teresa S.; Schildhammer, Daniel; Tribus, Martina; Joachim, Bastian; Huppertz, Hubert (2017-03-01). "Synthesis and characterization of the alkali borate-nitrates Na3–x Kx[B6O10]NO3 (x=0.5, 0.6, 0.7)". Zeitschrift für Naturforschung B. 72 (3): 215–223. doi:10.1515/znb-2016-0242. ISSN 1865-7117. S2CID 99165997.
^ ^a ^b Zhang, Qiqi; Zhang, Fangfang; Li, Fuming; Han, Shujuan; Yang, Zhihua; Pan, Shilie (2021-02-13). "M3B6O10NO3 (M = K, Rb): Two new alkali metal borate-nitrates with noncentrosymmetric structures". European Journal of Inorganic Chemistry. 2021 (13): 1297–1304. doi:10.1002/ejic.202001167. ISSN 1434-1948. S2CID 233784768.
^ Ortner, Teresa S.; Wurst, Klaus; Perfler, Lukas; Tribus, Martina; Huppertz, Hubert (January 2015). "Hydrothermal synthesis and characterization of the first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3". Journal of Solid State Chemistry. 221: 66–72. Bibcode:2015JSSCh.221...66O. doi:10.1016/j.jssc.2014.09.016.
^ ^a ^b ^c ^d ^e Bither, Tom A.; Young, Howard S. (1974-08-01). "Nitrato- and fluoroboracites M3B7O13NO3 and M3B7O13F". Journal of Solid State Chemistry. 10 (4): 302–311. Bibcode:1974JSSCh..10..302B. doi:10.1016/0022-4596(74)90039-5. ISSN 0022-4596.
^ ^a ^b ^c Liu, Ying; Deng, Jun-Xia; Pan, Chun-Yang (2020-05-04). "Synthesis and Structural Manipulation of a Polyanionic Zincoborate [Zn(H2O)6](NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O by the Molten Salt Method and its Potential Application as a Flame Retardant". Journal of Cluster Science. 32 (2): 469–477. doi:10.1007/s10876-020-01806-7. ISSN 1040-7278. S2CID 218495402.
^ ^a ^b Zoller, Michael; Wurst, Klaus; Huppertz, Hubert (2019-10-25). "Synthesis of the first nickel borate nitrate K7Ni[B18O24(OH)9](NO3)6· (H3BO3)". Zeitschrift für Naturforschung B. 74 (10): 757–764. doi:10.1515/znb-2019-0126. ISSN 1865-7117. S2CID 202872565. CC-BY can use images
^ Volkov, Sergey N.; Charkin, Dmitri O.; Marsiy, Ivan A.; Banaru, Daria A.; Povolotskiy, Alexey V.; Gosteva, Alevtina N.; Yu. Arsent’ev, Maxim; Krzhizhanovskaya, Maria G.; Ugolkov, Valery L.; Savchenko, Yevgeny E.; Kireev, Vadim E.; Aksenov, Sergey M.; Bubnova, Rimma S. (October 2024). "The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(–)". Journal of Crystal Growth. 644: 127837. doi:10.1016/j.jcrysgro.2024.127837.
^ Zhao, Biao-Chun; Sun, Wei; Ren, Wei-Jian; Huang, Ya-Xi; Li, Zucheng; Pan, Yuanming; Mi, Jin-Xiao (October 2013). "Hygroscopic La[B5O8(OH)]NO3·2H2O: Insight into the evolution of borate fundamental building blocks". Journal of Solid State Chemistry. 206: 91–98. Bibcode:2013JSSCh.206...91Z. doi:10.1016/j.jssc.2013.07.032.
^ Sun, Wei; Zhu, Teng-Teng; Zhao, Biao-Chun; Huang, Ya-Xi; Mi, Jin-Xiao (2012-05-15). "Redetermination of Ce[B 5 O 8 (OH)(H 2 O)]NO 3 ·2H 2 O". Acta Crystallographica Section E. 68 (5): i33–i34. doi:10.1107/S1600536812016169. ISSN 1600-5368. PMC 3344287. PMID 22590053.
^ Ortner, Teresa S.; Huppertz, Hubert (2017-09-26). "Hydrothermal synthesis and characterization of the praseodymium borate-nitrate Pr[B5O8(OH)(H2O)0.87]NO3·2H2O". Zeitschrift für Naturforschung B. 72 (9): 677–685. doi:10.1515/znb-2017-0121. ISSN 1865-7117. S2CID 103777780.
^ ^a ^b Katrych, Sergiy; Arakcheeva, Alla; Sienkiewicz, Andrzej; Forró, László; Ivšić, Trpimir (2020-12-15). "High-Pressure Synthesis of Rare-Earth Borate-Nitrate Crystals for Second Harmonic Generation". Inorganic Chemistry. 60 (1): 286–291. doi:10.1021/acs.inorgchem.0c02909. ISSN 0020-1669. PMID 33320648. S2CID 229283287.
^ ^a ^b Ortner, Teresa S.; Wurst, Klaus; Joachim, Bastian; Huppertz, Hubert (August 2016). "Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x ]NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]: Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x ]NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]". European Journal of Inorganic Chemistry. 2016 (22): 3659–3665. doi:10.1002/ejic.201600480.
^ Ortner, Teresa S.; Wurst, Klaus; Hejny, Clivia; Huppertz, Hubert (January 2016). "Hydrothermal synthesis and characterization of the lutetium borate–nitrate Lu2B2O5(NO3)2·2H2O". Journal of Solid State Chemistry. 233: 329–334. Bibcode:2016JSSCh.233..329O. doi:10.1016/j.jssc.2015.11.005.
^ Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2015-03-16). "A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π-Conjugated Planar Triangular Units". Angewandte Chemie. 127 (12): 3750–3753. Bibcode:2015AngCh.127.3750S. doi:10.1002/ange.201412344.
^ Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2013-08-05). "Pb 2 B 3 O 5.5 (OH) 2 and [Pb 3 (B 3 O 7 )](NO 3 ): Facile Syntheses of New Lead(II) Borates by Simply Changing the pH Values of the Reaction Systems". Inorganic Chemistry. 52 (15): 8979–8986. doi:10.1021/ic401175r. ISSN 0020-1669. PMID 23834222.

[1] Ortner, Teresa S.; Schildhammer, Daniel; Tribus, Martina; Joachim, Bastian; Huppertz, Hubert (2017-03-01). "Synthesis and characterization of the alkali borate-nitrates Na3–x Kx[B6O10]NO3 (x=0.5, 0.6, 0.7)". Zeitschrift für Naturforschung B. 72 (3): 215–223. doi:10.1515/znb-2016-0242. ISSN 1865-7117. S2CID 99165997.

[:5-2] Zhang, Qiqi; Zhang, Fangfang; Li, Fuming; Han, Shujuan; Yang, Zhihua; Pan, Shilie (2021-02-13). "M3B6O10NO3 (M = K, Rb): Two new alkali metal borate-nitrates with noncentrosymmetric structures". European Journal of Inorganic Chemistry. 2021 (13): 1297–1304. doi:10.1002/ejic.202001167. ISSN 1434-1948. S2CID 233784768.

[3] Ortner, Teresa S.; Wurst, Klaus; Perfler, Lukas; Tribus, Martina; Huppertz, Hubert (January 2015). "Hydrothermal synthesis and characterization of the first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3". Journal of Solid State Chemistry. 221: 66–72. Bibcode:2015JSSCh.221...66O. doi:10.1016/j.jssc.2014.09.016.

[:0-4] Bither, Tom A.; Young, Howard S. (1974-08-01). "Nitrato- and fluoroboracites M3B7O13NO3 and M3B7O13F". Journal of Solid State Chemistry. 10 (4): 302–311. Bibcode:1974JSSCh..10..302B. doi:10.1016/0022-4596(74)90039-5. ISSN 0022-4596.

[:3-5] Liu, Ying; Deng, Jun-Xia; Pan, Chun-Yang (2020-05-04). "Synthesis and Structural Manipulation of a Polyanionic Zincoborate [Zn(H2O)6](NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O by the Molten Salt Method and its Potential Application as a Flame Retardant". Journal of Cluster Science. 32 (2): 469–477. doi:10.1007/s10876-020-01806-7. ISSN 1040-7278. S2CID 218495402.

[:1-6] Zoller, Michael; Wurst, Klaus; Huppertz, Hubert (2019-10-25). "Synthesis of the first nickel borate nitrate K7Ni[B18O24(OH)9](NO3)6· (H3BO3)". Zeitschrift für Naturforschung B. 74 (10): 757–764. doi:10.1515/znb-2019-0126. ISSN 1865-7117. S2CID 202872565. CC-BY can use images

[7] Volkov, Sergey N.; Charkin, Dmitri O.; Marsiy, Ivan A.; Banaru, Daria A.; Povolotskiy, Alexey V.; Gosteva, Alevtina N.; Yu. Arsent’ev, Maxim; Krzhizhanovskaya, Maria G.; Ugolkov, Valery L.; Savchenko, Yevgeny E.; Kireev, Vadim E.; Aksenov, Sergey M.; Bubnova, Rimma S. (October 2024). "The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(–)". Journal of Crystal Growth. 644: 127837. doi:10.1016/j.jcrysgro.2024.127837.

[8] Zhao, Biao-Chun; Sun, Wei; Ren, Wei-Jian; Huang, Ya-Xi; Li, Zucheng; Pan, Yuanming; Mi, Jin-Xiao (October 2013). "Hygroscopic La[B5O8(OH)]NO3·2H2O: Insight into the evolution of borate fundamental building blocks". Journal of Solid State Chemistry. 206: 91–98. Bibcode:2013JSSCh.206...91Z. doi:10.1016/j.jssc.2013.07.032.

[9] Sun, Wei; Zhu, Teng-Teng; Zhao, Biao-Chun; Huang, Ya-Xi; Mi, Jin-Xiao (2012-05-15). "Redetermination of Ce[B 5 O 8 (OH)(H 2 O)]NO 3 ·2H 2 O". Acta Crystallographica Section E. 68 (5): i33–i34. doi:10.1107/S1600536812016169. ISSN 1600-5368. PMC 3344287. PMID 22590053.

[10] Ortner, Teresa S.; Huppertz, Hubert (2017-09-26). "Hydrothermal synthesis and characterization of the praseodymium borate-nitrate Pr[B5O8(OH)(H2O)0.87]NO3·2H2O". Zeitschrift für Naturforschung B. 72 (9): 677–685. doi:10.1515/znb-2017-0121. ISSN 1865-7117. S2CID 103777780.

[:4-11] Katrych, Sergiy; Arakcheeva, Alla; Sienkiewicz, Andrzej; Forró, László; Ivšić, Trpimir (2020-12-15). "High-Pressure Synthesis of Rare-Earth Borate-Nitrate Crystals for Second Harmonic Generation". Inorganic Chemistry. 60 (1): 286–291. doi:10.1021/acs.inorgchem.0c02909. ISSN 0020-1669. PMID 33320648. S2CID 229283287.

[:2-12] Ortner, Teresa S.; Wurst, Klaus; Joachim, Bastian; Huppertz, Hubert (August 2016). "Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x ]NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]: Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x ]NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]". European Journal of Inorganic Chemistry. 2016 (22): 3659–3665. doi:10.1002/ejic.201600480.

[13] Ortner, Teresa S.; Wurst, Klaus; Hejny, Clivia; Huppertz, Hubert (January 2016). "Hydrothermal synthesis and characterization of the lutetium borate–nitrate Lu2B2O5(NO3)2·2H2O". Journal of Solid State Chemistry. 233: 329–334. Bibcode:2016JSSCh.233..329O. doi:10.1016/j.jssc.2015.11.005.

[14] Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2015-03-16). "A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π-Conjugated Planar Triangular Units". Angewandte Chemie. 127 (12): 3750–3753. Bibcode:2015AngCh.127.3750S. doi:10.1002/ange.201412344.

[15] Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2013-08-05). "Pb 2 B 3 O 5.5 (OH) 2 and [Pb 3 (B 3 O 7 )](NO 3 ): Facile Syntheses of New Lead(II) Borates by Simply Changing the pH Values of the Reaction Systems". Inorganic Chemistry. 52 (15): 8979–8986. doi:10.1021/ic401175r. ISSN 0020-1669. PMID 23834222.

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