Wikipedia

Borate phosphate

(Redirected from Phosphate borates)

Borate phosphates are mixed anion compounds containing separate borate and phosphate anions. They are distinct from the borophosphates where the borate is linked to a phosphate via a common oxygen atom. The borate phosphates have a higher ratio of cations to number of borates and phosphates, as compared to the borophosphates.[1]

Borate phosphate
Identifiers
3D model (JSmol)
ChemSpider
  • 1:1: InChI=1S/BO3.H3O4P/c2-1(3)4;1-5(2,3)4/h;(H3,1,2,3,4)/q-3;/p-3
    Key: IVHMVLWSSMPWPQ-UHFFFAOYSA-K
  • 1:1: B([O-])([O-])[O-].[O-]P(=O)([O-])[O-]
Properties
BO7P−6
Molar mass 153.78 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

There are also organic esters of both borate and phosphate, e.g. NADH-borate.[2]

Production

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In the high temperature method, ingredients are heated together at atmospheric pressure. Products are anhydrous, and production or borophosphates is likely.[3]

The boron flux method involves dissolving ingredients such as an ammonium phosphate and metal carbonate in an excess of molten boric acid.[3]

Use

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Borate phosphates are of research interest for their optical, electrooptical or magnetic properties.[3]

List

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chem mw crystal system space group unit cell Å volume density comment references
Be3(BO3)(PO4) hexagonal SHG [1][4]
α-Mg3[BPO7] orthorhombic Immm a=8·495, b=4·886, c=12·565 Z=4 [5]
Mg3[BPO7] monoclinic Cm [3]
Mg3[BPO7] hexagonal P6_2m [3]
Lüneburgite Mg3[B2(OH)6](PO4)2 · 6H2O triclinic 2.05 Biaxial (-) nα = 1.520 – 1.522 nβ = 1.540 – 1.541 nγ = 1.545 – 1.548

2V 52° to 60°

Max birefringence δ = 0.025 – 0.026

[6][7]
Ca3[BPO7] monoclinic a=8.602 b=4.891 c=12.806 β=102.30 [5]
Seamanite Mn2+3[B(OH)4](PO4)(OH)2 orthorhombic Pbnm a = 7.81 Å, b = 15.11 Å, c = 6.69 Å Z=4 789.48 3.08 Biaxial (+) nα = 1.640 nβ = 1.663 nγ = 1.665

2V 40°

Max birefringence δ = 0.025

[8][9]
Laptevite-(Ce) Ca6(Fe2+,Mn2+)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11 trigonal R3m a = 10.804, c = 27.726 Z=3 2802.6 4.61 Uniaxial (-) nω = 1.741 nε = 1.720

Max birefringence δ = 0.021

[10]
(CoPO4)4, B5O6(OH)4N(CH3)4(CH3NH3) 1036.10 orthorhombic I222 a=6.7601 b=7.5422 c=34.822 Z=2 1775.4 1.938 red [11]
Co3[BPO7] monoclinic Cm a=9.774, b=12.688, c=4.9057, β=119.749°; Z=4 528.2 purple [3]
α-Zn3[BPO7] 349.89 orthorhombic a=8.438 b=4.884 c=12.558 [5]
α-Zn3[BPO7] 349.89 monoclinic Cm a=9.725 b=12.720 c=4.874 β=119.80 Z=4 [3][12]
β-Zn3[BPO7] 349.89 hexagonal P-6 a=8.4624 c=13.0690 Z=6 810.51 4.301 colourless [3][13]
α-Sr3[BPO7] orthorhombic a=9.0561, b=9.7984, c=13.9531 [14]
Sr10[(PO4)5.5(BO4)0.5](BO2) P3_ a=9.7973, c=7.3056, Z=1 607.29 [15]
SrCo2(BO3)(PO4) 359.26 monoclinic P21/c a=6.485 b=9.270 c=10.066 β=111.14 Z=4 548.7 4.349 red [1][16]
Byzantievite Ba5(Ca,REE,Y)22(Ti,Nb)18(SiO4)4[(PO4, SiO4)]4(BO3)9O22[(OH),F]43(H2O)1.5 trigonal R3 a = 9.1202, c = 102.145 7,357.9 4.10 Uniaxial (-) nω = 1.940 nε = 1.860

Max birefringence δ = 0.080

16 different layers in structure

[17][18]
Rhabdoborite Mg12(V5+,Mo6+,W6+)1 · 5O6{[BO3]6-x[(P,As)O4]xF2-x} (x < 1) hexagonal P63 a = 10.6314, c = 4.5661 446.95 [19]
CsNa2Y2(BO3)(PO4)2 605.46 orthorhombic Cmcm a=6.9491 b=14.907 c=10.6201 Z=4 1100.2 3.655 colourless [20]
CsZn4(BO3)(PO4)2 679.30 orthorhombic Pbca a=14.49 b=10.02 c=16.45 Z=8 2388 3.779 colourless [21]
Ba3(BO3)(PO4) hexagonal P63mc a=5.4898, c=14.7551, Z=2 [1][22]
Ba3(BO3)(PO4) monoclinic P2/m a = 11.7947, b = 9.6135, c = 12.9548, β= 111.25° 1369.08 [23]
Ba11B26O44(PO4)2(OH)6 monoclinic P21/c a=6.891, b=13.629, c=25.851, β=90.04° [24]
Ba3(ZnB5O10)PO4 786.41 orthorhombic Pnm21 a = 10.399 b = 7.064 c = 8.204 Z=2 602.6 4.334 [25]
La7O6(BO3)(PO4)2 monoclinic a=7.019 b=17.915 c=12.653 β=97.52 1577.27 [1][26]
Pr7O6(BO3)(PO4)2 monoclinic P121/n1 a=6.8939 b=17.662 c=12.442 β=97.24 Z=4 1502.9 green [1][27]
Nd7O6(BO3)(PO4)2 monoclinic a=6.862 b=17.591 c=12.375 β=97.18 1482.12 [1][26]
Sm7O6(BO3)(PO4)2 monoclinic P121/n1 a=6.778 b=17.396 c=12.218 β=96.96 Z=4 1430.0 yellow [1][27]
CsNa2Sm2(BO3)(PO4)2 728.34 orthorhombic Cmcm a=7.0631 b=15.288 c=10.725 Z=4 1158.1 4.177 colourless [28]
CsNa2Ho2(BO3)(PO4)2 [29]
CsNa2Er2(BO3)(PO4)2 [29]
CsNa2Tm2(BO3)(PO4)2 [29]
Gd7O6(BO3)(PO4)2 monoclinic a=6.704 b=17.299 c=12.100 β=96.94 1393.11 [1][26]
Dy7O6(BO3)(PO4)2 monoclinic a=6.623 b=17.172 c=11.960 β=96.76 1350.84 [1][26]
K3Yb[OB(OH)2]2[HOPO3]2 R3_ a=5.6809, c=36.594 Z=3 1022.8 [1][30]
CsNa2Yb2(BO3)(PO4)2 [29]
K3Lu[OB(OH)2]2[HOPO3]2 R3_ a=5.6668, c=36.692 Z=3 1020.4 [1][30]
CsNa2Lu2(BO3)(PO4)2 777.58 orthorhombic Cmcm a = 6.8750 b = 14.6919 c = 10.5581 1066.44 4.843
Pb4O(BO3)(PO4) 998.54 monoclinic P21/c a=10.202 b=7.005 c=12.92 β=113.057 Z=4 849.6 7.807 colourless [31]
LiPb4(BO3)(PO4)2 1084.85 orthorhombic Pbca a=12.613 b=6.551 c=25.63 Z=8 2095 6.875 colourless [1]
Bi4O3(BO3)(PO4) 1037.70 orthorhombic Pbca a=5.536 b=14.10 c=22.62 Z=8 1766 7.807 colourless [31]
Th2[BO4][PO4] monoclinic P21/c a=8.4665, b=7.9552, c=8.2297, β= 103.746° Z = 4 [32]
Ba5[(UO2)(PO4)3(B5O9)]·nH2O interlocking nanotubes; absorbs water from air [33]
U2[BO4][PO4] 645.84 monoclinic P21/c a = 8.546, b = 7.753, c = 8.163 β = 102.52° Z=4 528.0 8.12 generated at 12.5 GPa + 1000 °C; emerald green [34]
[Sr8(PO4)2][(UO2)(PO4)2(B5O9)2] 1746.97 monoclinic P21/n a = 6.5014, b =22.4302, c =9.7964 β = 90.241° Z=2 1428.57 4.061 orange [35]

References

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  1. ^ a b c d e f g h i j k l m Huang, Shengshi; Yu, Hongwei; Han, Jian; Pan, Shilie; Jing, Qun; Wang, Ying; Dong, Lingyun; Wu, Hongping; Yang, Zhihua; Wang, Xian (August 2014). "The Effect of the Ratio of [M/(B+P)] on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb 4 (BO 3 )(PO 4 ) 2". European Journal of Inorganic Chemistry. 2014 (22): 3467–3473. doi:10.1002/ejic.201402389.
  2. ^ Kim, Danny H.; Marbois, Beth N.; Faull, Kym F.; Eckhert, Curtis D. (June 2003). "Esterification of borate with NAD+ and NADH as studied by electrospray ionization mass spectrometry and11B NMR spectroscopy". Journal of Mass Spectrometry. 38 (6): 632–640. Bibcode:2003JMSp...38..632K. doi:10.1002/jms.476. PMID 12827632.
  3. ^ a b c d e f g h Yilmaz, Aysen; Bu, Xianhui; Kizilyalli, Meral; Kniep, Rudiger; Stucky, Galen D. (February 2001). "Cobalt Borate Phosphate, Co3[BPO7], Synthesis and Characterization". Journal of Solid State Chemistry. 156 (2): 281–285. Bibcode:2001JSSCh.156..281Y. doi:10.1006/jssc.2000.8963.
  4. ^ He, Zhangzhen; Moriyama, Hiroshi (2003). "A Model of New VUV NLO Materials Based on Borate: A Novel Noncentrosymmetric Borophosphate Compound Be 3 BPO 7". MRS Proceedings. 788: L8.23. doi:10.1557/PROC-788-L8.23. ISSN 0272-9172.
  5. ^ a b c Gözel, G.; Baykal, A.; Kizilyalli, M.; Kniep, R. (December 1998). "Solid-State Synthesis, X-ray Powder Investigation and IR Study of α-Mg3[BPO7]". Journal of the European Ceramic Society. 18 (14): 2241–2246. doi:10.1016/S0955-2219(98)00152-6.
  6. ^ "Lüneburgite". www.mindat.org. Retrieved 2020-12-15.
  7. ^ Korybska-Sadło, Iwona; Sitarz, Maciej; Król, Magdalena; Gunia, Piotr (2016-10-20). "Vibrational spectroscopic characterization of the magnesium borate-phosphate mineral lüneburgite". Spectroscopy Letters. 49 (9): 606–612. Bibcode:2016SpecL..49..606K. doi:10.1080/00387010.2016.1236819. ISSN 0038-7010. S2CID 99999165.
  8. ^ "Seamanite". www.mindat.org. Retrieved 2020-12-15.
  9. ^ Ewald, Bastian; Huang, Ya-Xi; Kniep, Rüdiger (August 2007). "Structural Chemistry of Borophosphates, Metalloborophosphates, and Related Compounds". Zeitschrift für anorganische und allgemeine Chemie (in German). 633 (10): 1517–1540. doi:10.1002/zaac.200700232.
  10. ^ "Laptevite-(Ce)". www.mindat.org. Retrieved 2020-12-15.
  11. ^ Lin, Zhuojia; Wragg, David S.; Lightfoot, Philip; Morris, Russell E. (2009). "A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis". Dalton Transactions (27): 5287–9. doi:10.1039/b904450g. ISSN 1477-9226. PMID 19565080.
  12. ^ Bluhm, K.; Park, C. H. (1997-01-01). "Die Synthese und Kristallstruktur des Borat-Phosphats: α -Zn3(BO3)(PO4) / Synthesis and Crystal Structure of the Borate-Phosphate: α-Zn3(BO3)( PO4)". Zeitschrift für Naturforschung B. 52 (1): 102–106. doi:10.1515/znb-1997-0120. ISSN 1865-7117. S2CID 100783759.
  13. ^ Zhang, Erpan; Zhao, Sangen; Zhang, Jianxiu; Fu, Peizhen; Yao, Jiyong (2011-01-15). "The β-modification of trizinc borate phosphate, Zn 3 (BO 3 )(PO 4 )". Acta Crystallographica Section E. 67 (1): i3. Bibcode:2011AcCrE..67I...3Z. doi:10.1107/S1600536810051871. ISSN 1600-5368. PMC 3050272. PMID 21522511.
  14. ^ Tekin, Berna (August 2007). "Bazi Metal İçeren Boratli, Fosfatli ve Borfosfatli Bi̇leşi̇kleri̇n Sentezi̇ ve Yapisal Karakteri̇zasyonu" (PDF).
  15. ^ Chen, Shuang; Hoffmann, Stefan; Carrillo-Cabrera, Wilder; Akselrud, Lev G.; Prots, Yurii; Schwarz, Ulrich; Zhao, Jing-Tai; Kniep, Rüdiger (March 2010). "Sr10[(PO4)5.5(BO4)0.5](BO2): Growth and crystal structure of a strontium phosphate orthoborate metaborate closely related to the apatite-type crystal structure". Journal of Solid State Chemistry. 183 (3): 658–661. Bibcode:2010JSSCh.183..658C. doi:10.1016/j.jssc.2009.12.026.
  16. ^ Gou, Wenbin; He, Zhangzhen; Yang, Ming; Zhang, Weilong; Cheng, Wendan (2013-03-04). "Synthesis and Magnetic Properties of a New Borophosphate SrCo 2 BPO 7 with a Four-Column Ribbon Structure". Inorganic Chemistry. 52 (5): 2492–2496. doi:10.1021/ic3023979. ISSN 0020-1669. PMID 23406089.
  17. ^ "Byzantievite". www.mindat.org. Retrieved 2020-12-15.
  18. ^ Sokolova, E.; Hawthorne, F. C.; Pautov, L. A.; Agakhanov, A. A. (April 2010). "Byzantievite, Ba 5 (Ca, REE ,Y) 22 (Ti,Nb) 18 (SiO 4 ) 4 [(PO 4 ),(SiO 4 )] 4 (BO 3 ) 9 O 21 [(OH),F] 43 (H 2 O) 1.5 : the crystal structure and crystal chemistry of the only known mineral with the oxyanions (BO 3 ), (SiO 4 ) and (PO 4 )". Mineralogical Magazine. 74 (2): 285–308. Bibcode:2010MinM...74..285S. doi:10.1180/minmag.2010.074.2.285. ISSN 0026-461X. S2CID 95182192.
  19. ^ "Rhabdoborite-(V)". www.mindat.org. Retrieved 2020-12-15.
  20. ^ Zhao, Dan; Xue, Yali; Zhang, Ruijuan; Fan, Yanping; Liu, Baozhong; Li, Yanan; Zhang, Shirui (2020). "Design, synthesis, crystal structure and luminescent properties introduced by Eu 3+ of a new type of rare-earth borophosphate CsNa 2 REE 2 (BO 3 )(PO 4 ) 2 (REE = Y, Gd)". Dalton Transactions. 49 (29): 10104–10113. doi:10.1039/D0DT00389A. ISSN 1477-9226. PMID 32662492. S2CID 220519447.
  21. ^ Guo, Fengjiao; Hu, Cong; Wang, Ying; Han, Jian; Yang, Zhihua; Pan, Shilie (2018). "Insights of BO 3 –PO 4 replacement for the design and synthesis of a new borate–phosphate with unique 1∞[Zn 4 BO 11 ] chains and two new phosphates". Inorganic Chemistry Frontiers. 5 (2): 327–334. doi:10.1039/C7QI00548B. ISSN 2052-1553.
  22. ^ Ma, H.W.; Liang, J.K.; Wu, L.; Liu, G.Y.; Rao, G.H.; Chen, X.L. (October 2004). "Ab initio structure determination of new compound Ba3(BO3)(PO4)". Journal of Solid State Chemistry. 177 (10): 3454–3459. Bibcode:2004JSSCh.177.3454M. doi:10.1016/j.jssc.2003.12.027.
  23. ^ Gözel, Güller (1993). "Preparation and structural investigation of alkaline-earth metal borophosphates – Tez Arşivi". tezarsivi.com. Retrieved 2021-03-01.
  24. ^ Heyward, Carla; McMillen, Colin D.; Kolis, Joseph (July 2013). "Hydrothermal synthesis and structural analysis of new mixed oxyanion borates: Ba11B26O44(PO4)2(OH)6, Li9BaB15O27(CO3) and Ba3Si2B6O16". Journal of Solid State Chemistry. 203: 166–173. Bibcode:2013JSSCh.203..166H. doi:10.1016/j.jssc.2013.04.022.
  25. ^ Yu, Hongwei; Zhang, Weiguo; Young, Joshua; Rondinelli, James M.; Halasyamani, P. Shiv (December 2015). "Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba 3 (ZnB 5 O 10 )PO 4". Advanced Materials. 27 (45): 7380–7385. Bibcode:2015AdM....27.7380Y. doi:10.1002/adma.201503951. PMID 26459262. S2CID 35637169.
  26. ^ a b c d Shi, Ying; Liang, Jingkui; Zhang, Hao; Yang, Jinling; Zhuang, Weidong; Rao, Guanghui (February 1997). "X-Ray Powder Diffraction and Vibrational Spectra Studies of Rare Earth Borophosphates,Ln7O6(BO3)(PO4)2(Ln=La, Nd, Gd, and Dy)". Journal of Solid State Chemistry. 129 (1): 45–52. Bibcode:1997JSSCh.129...45S. doi:10.1006/jssc.1996.7227.
  27. ^ a b Ewald, B.; Prots, Yu.; Kniep, R. (April 2004). "Refinement of the crystal structures of praseodymium- and samariumoxoborate- bis(oxophosphate)-oxide, Ln7O6[BO3][PO4]2, (Ln = Pr, Sm)". Zeitschrift für Kristallographie – New Crystal Structures. 219 (1–4): 233–235. doi:10.1524/ncrs.2004.219.14.233. ISSN 2197-4578. S2CID 96530323.
  28. ^ Zhao, Dan; Shi, Lin-Ying; Zhang, Rui-Juan; Xue, Ya-Li (2020-12-01). "Synthesis, crystal structure and luminescence properties of a new samarium borate phosphate, CsNa 2 Sm 2 (BO 3 )(PO 4 ) 2". Acta Crystallographica Section C: Structural Chemistry. 76 (12): 1068–1075. doi:10.1107/S2053229620014576. ISSN 2053-2296. PMID 33273144. S2CID 227283126.
  29. ^ a b c d Zhao, Dan; Xue, Ya-Li; Fan, Yun-Chang; Zhang, Rui-Juan; Zhang, Shi-Rui (June 2021). "A new series of rare-earth borate-phosphate family CsNa2Ln2(BO3)(PO4)2 (Ln = Ho, Er, Tm, Yb): Tunnel structure, upconversion luminescence and optical thermometry properties". Journal of Alloys and Compounds. 866: 158801. doi:10.1016/j.jallcom.2021.158801. S2CID 233561777.
  30. ^ a b Zhou, Yan; Hoffmann, Stefan; Huang, Ya-Xi; Prots, Yurii; Schnelle, Walter; Menezes, Prashanth W.; Carrillo-Cabrera, Wilder; Sichelschmidt, Jörg; Mi, Jin-Xiao; Kniep, Rüdiger (June 2011). "K3Ln[OB(OH)2]2[HOPO3]2 (Ln=Yb, Lu): Layered rare-earth dihydrogen borate monohydrogen phosphates". Journal of Solid State Chemistry. 184 (6): 1517–1522. Bibcode:2011JSSCh.184.1517Z. doi:10.1016/j.jssc.2011.04.023.
  31. ^ a b Wang, Ying; Pan, Shilie; Huang, Shengshi; Dong, Lingyun; Zhang, Min; Han, Shujuan; Wang, Xian (2014). "Structural insights for the design of new borate–phosphates: synthesis, crystal structure and optical properties of Pb 4 O(BO 3 )(PO 4 ) and Bi 4 O 3 (BO 3 )(PO 4 )". Dalton Trans. 43 (34): 12886–12893. doi:10.1039/C4DT01199F. ISSN 1477-9226. PMID 25020047.
  32. ^ Lipp, C.; Burns, P. C. (2011-10-01). "Th2[BO4][PO4]: A RARE EXAMPLE OF AN ACTINIDE BORATE-PHOSPHATE". The Canadian Mineralogist. 49 (5): 1211–1220. Bibcode:2011CaMin..49.1211L. doi:10.3749/canmin.49.5.1211. ISSN 0008-4476.
  33. ^ Wu, Shijun; Wang, Shuao; Diwu, Juan; Depmeier, Wulf; Malcherek, Thomas; Alekseev, Evgeny V.; Albrecht-Schmitt, Thomas E. (2012). "Complex clover cross-sectioned nanotubules exist in the structure of the first uranium borate phosphate". Chemical Communications. 48 (29): 3479–81. doi:10.1039/c2cc17517g. ISSN 1359-7345. PMID 22267020.
  34. ^ Hinteregger, Ernst; Wurst, Klaus; Perfler, Lukas; Kraus, Florian; Huppertz, Hubert (2013-10-14). "High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U 2 [BO 4 ][PO 4 ]: High-Pressure Synthesis and Characterization of U 2 [BO 4 ][PO 4 ]". European Journal of Inorganic Chemistry. 2013 (30): 5247–5252. doi:10.1002/ejic.201300662. PMC 3939824. PMID 24611029.
  35. ^ Hao, Yucheng (2017). "New Insight into the Crystal Chemistry of Uranium and Thorium Borates, Borophosphates and Borate-phosphates". p. 109.
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