Samarium(III) nitride is a binary inorganic compound of samarium and nitrogen with the chemical formula SmN.[1]
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| Other names
samarium mononitride, azanylidynesamarium
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3D model (JSmol)
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| ECHA InfoCard | 100.042.940 |
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| NSm | |
| Molar mass | 164.37 g·mol−1 |
| Density | 8.4 g/cm3 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preparation
editSamarium(III) nitrate can be prepared by directly reacting samarium and nitrogen at 800 °C:[2]
- 2 Sm + N2 → 2 SmN
Properties
editSamarium(III) nitride forms cubic crystals, space group Fm3m, unit cell parameters a = 0.50481 nm, Z = 4, and a structure like sodium chloride.[3][4][5]
References
edit- ^ "Samarium Nitride". American Elements. Retrieved 30 January 2024.
- ^ Eick, H. A.; Baenziger, N. C.; Eyring, L. (Dec 1956). "The Preparation, Crystal Structure and Some Properties of SmN, EuN and YbN 1". Journal of the American Chemical Society. 78 (23): 5987–5989. doi:10.1021/ja01604a006. ISSN 0002-7863.
- ^ Diagrammy sostojanija dvojnych metalličeskich sistem: spravočnik v trech tomach. 3,1. Moskva: Mašinostroenie. 2001. ISBN 978-5-217-02843-6.
- ^ Predel, B. (1997), "N-Sm (Nitrogen-Samarium)", Li-Mg – Nd-Zr, Landolt-Börnstein - Group IV Physical Chemistry, Berlin/Heidelberg: Springer-Verlag, p. 1, doi:10.1007/10522884_2133, ISBN 3-540-61433-8, retrieved 2024-01-31
- ^ Iandelli, A. (Nov 1956). "Über einige Verbindungen des Samariums vom NaCl-Typ". Zeitschrift für anorganische und allgemeine Chemie. 288 (1–2): 81–86. doi:10.1002/zaac.19562880111. ISSN 0044-2313.