Schoenflies notation

The Schoenflies (or Schönflies) notation, named after the German mathematician Arthur Moritz Schoenflies, is a notation primarily used to specify point groups in three dimensions. Because a point group alone is completely adequate to describe the symmetry of a molecule, the notation is often sufficient and commonly used for spectroscopy. However, in crystallography, there is additional translational symmetry, and point groups are not enough to describe the full symmetry of crystals, so the full space group is usually used instead. The naming of full space groups usually follows another common convention, the Hermann–Mauguin notation, also known as the international notation.

Although Schoenflies notation without superscripts is a pure point group notation, optionally, superscripts can be added to further specify individual space groups. However, for space groups, the connection to the underlying symmetry elements is much more clear in Hermann–Mauguin notation, so the latter notation is usually preferred for space groups.

Symmetry elements

Symmetry elements are denoted by i for centers of inversion, C for proper rotation axes, σ for mirror planes, and S for improper rotation axes (rotation-reflection axes). C and S are usually followed by a subscript number (abstractly denoted n) denoting the order of rotation possible.

By convention, the axis of proper rotation of greatest order is defined as the principal axis. All other symmetry elements are described in relation to it. A vertical mirror plane (containing the principal axis) is denoted σ_v; a horizontal mirror plane (perpendicular to the principal axis) is denoted σ_h.

Point groups

In three dimensions, there are an infinite number of point groups, but all of them can be classified by several families.

C_n (for cyclic) has an n-fold rotation axis.
- C_nh is C_n with the addition of a mirror (reflection) plane perpendicular to the axis of rotation (horizontal plane).
- C_nv is C_n with the addition of n mirror planes containing the axis of rotation (vertical planes).
C_s denotes a group with only mirror plane (for Spiegel, German for mirror) and no other symmetry elements.
S_n (for Spiegel, German for mirror) contains only a n-fold rotation-reflection axis. The index, n, should be even because when it is odd an n-fold rotation-reflection axis is equivalent to a combination of an n-fold rotation axis and a perpendicular plane, hence S_n = C_nh for odd n.
C_ni has only a rotoinversion axis. This notation is rarely used because any rotoinversion axis can be expressed instead as rotation-reflection axis: For odd n, C_ni = S_2n and C_2ni = S_n = C_nh, and for even n, C_2ni = S_2n. Only the notation C_i (meaning C_1i) is commonly used, and some sources write C_3i, C_5i etc.
D_n (for dihedral, or two-sided) has an n-fold rotation axis plus n twofold axes perpendicular to that axis.
- D_nh has, in addition, a horizontal mirror plane and, as a consequence, also n vertical mirror planes each containing the n-fold axis and one of the twofold axes.
- D_nd has, in addition to the elements of D_n, n vertical mirror planes which pass between twofold axes (diagonal planes).
T (the chiral tetrahedral group) has the rotation axes of a tetrahedron (three 2-fold axes and four 3-fold axes).
- T_d includes diagonal mirror planes (each diagonal plane contains only one twofold axis and passes between two other twofold axes, as in D_2d). This addition of diagonal planes results in three improper rotation operations S₄.
- T_h includes three horizontal mirror planes. Each plane contains two twofold axes and is perpendicular to the third twofold axis, which results in inversion center i.
O (the chiral octahedral group) has the rotation axes of an octahedron or cube (three 4-fold axes, four 3-fold axes, and six diagonal 2-fold axes).
- O_h includes horizontal mirror planes and, as a consequence, vertical mirror planes. It contains also inversion center and improper rotation operations.
I (the chiral icosahedral group) indicates that the group has the rotation axes of an icosahedron or dodecahedron (six 5-fold axes, ten 3-fold axes, and 15 2-fold axes).
- I_h includes horizontal mirror planes and contains also inversion center and improper rotation operations.

All groups that do not contain more than one higher-order axis (order 3 or more) can be arranged as shown in a table below; symbols in red are rarely used.

	n = 1	2	3	4	5	6	7	8	...	∞
C_n	C₁	C₂	C₃	C₄	C₅	C₆	C₇	C₈	...	C_∞
C_nv	C_1v = C_1h	C_2v	C_3v	C_4v	C_5v	C_6v	C_7v	C_8v	...	C_∞v
C_nh	C_1h = C_s	C_2h	C_3h	C_4h	C_5h	C_6h	C_7h	C_8h	...	C_∞h
S_n	S₁ = C_s	S₂ = C_i	S₃ = C_3h	S₄	S₅ = C_5h	S₆	S₇ = C_7h	S₈	...	S_∞ = C_∞h
C_ni (redundant)	C_1i = C_i	C_2i = C_s	C_3i = S₆	C_4i = S₄	C_5i = S₁₀	C_6i = C_3h	C_7i = S₁₄	C_8i = S₈	...	C_∞i = C_∞h
D_n	D₁ = C₂	D₂	D₃	D₄	D₅	D₆	D₇	D₈	...	D_∞
D_nh	D_1h = C_2v	D_2h	D_3h	D_4h	D_5h	D_6h	D_7h	D_8h	...	D_∞h
D_nd	D_1d = C_2h	D_2d	D_3d	D_4d	D_5d	D_6d	D_7d	D_8d	...	D_∞d = D_∞h

In crystallography, due to the crystallographic restriction theorem, n is restricted to the values of 1, 2, 3, 4, or 6. The noncrystallographic groups are shown with grayed backgrounds. D_4d and D_6d are also forbidden because they contain improper rotations with n = 8 and 12 respectively. The 27 point groups in the table plus T, T_d, T_h, O and O_h constitute 32 crystallographic point groups.

Groups with n = ∞ are called limit groups or Curie groups. There are two more limit groups, not listed in the table: K (for Kugel, German for ball, sphere), the group of all rotations in 3-dimensional space; and K_h, the group of all rotations and reflections. In mathematics and theoretical physics they are known respectively as the special orthogonal group and the orthogonal group in three-dimensional space, with the symbols SO(3) and O(3).

Space groups

The space groups with given point group are numbered by 1, 2, 3, ... (in the same order as their international number) and this number is added as a superscript to the Schönflies symbol for the corresponding point group. For example, groups numbers 3 to 5 whose point group is C₂ have Schönflies symbols C¹
₂, C²
₂, C³
₂.

While in case of point groups, Schönflies symbol defines the symmetry elements of group unambiguously, the additional superscript for space group doesn't have any information about translational symmetry of space group (lattice centering, translational components of axes and planes), hence one needs to refer to special tables, containing information about correspondence between Schönflies and Hermann–Mauguin notation. Such table is given in List of space groups page.

References

Flurry, R. L., Symmetry Groups : Theory and Chemical Applications. Prentice-Hall, 1980. ISBN 978-0-13-880013-0 LCCN: 79-18729
Cotton, F. A., Chemical Applications of Group Theory, John Wiley & Sons: New York, 1990. ISBN 0-471-51094-7
Harris, D., Bertolucci, M., Symmetry and Spectroscopy. New York, Dover Publications, 1989.

External links

Symmetry @ Otterbein