Ytterbium(II) chloride

Ytterbium(II) chloride (YbCl2) is an inorganic chemical compound. It was first prepared in 1929 by W. K. Klemm and W. Schuth, by reduction of ytterbium(III) chloride, YbCl3, using hydrogen.

Ytterbium(II) chloride
Ytterbium(II) chloride
Names
Other names
ytterbium dichloride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.197 Edit this at Wikidata
EC Number
  • 237-632-3
  • InChI=1S/2ClH.Yb/h2*1H;/q;;+2/p-2 checkY
    Key: LINIOGPXIKIICR-UHFFFAOYSA-L checkY
  • InChI=1S/2ClH.Yb/h2*1H;/q;;+2/p-2
  • Key: LINIOGPXIKIICR-UHFFFAOYSA-L
  • [Yb+2].[Cl-].[Cl-]
Properties
YbCl2
Molar mass 243.95 g/mol
Appearance green crystals
Density 5.27 g/cm3, solid
Melting point 721 °C (1,330 °F; 994 K)
reacts[1]
Structure
Orthorhombic, oP24
Pbca, No. 61
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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2 YbCl3 + H2 → 2 YbCl2 + 2 HCl

Like other Yb(II) compounds and other low-valence rare earth compounds, it is a strong reducing agent. It is unstable in aqueous solution, reducing water to hydrogen gas.[2]

References

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  1. ^ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, pp. 4–94, ISBN 0-8493-0594-2
  2. ^ ytterbium - Britannica Online Encyclopedia