2,6-Dichloroquinone-4-chloroimide (Gibbs reagent) is an organic compound used as an colorimetric indicator to detect phenolic compounds.[1] Upon reaction with phenol itself, 2,6-dichlorophenolindophenol is formed,[2] a chemical that is used as a redox indicator.
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Preferred IUPAC name
2,6-Dichloro-4-(chloroimino)cyclohexa-2,5-dien-1-one | |
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3D model (JSmol)
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ChEMBL | |
ChemSpider | |
ECHA InfoCard | 100.002.671 |
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PubChem CID
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UNII | |
CompTox Dashboard (EPA)
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Properties | |
C6H2Cl3NO | |
Molar mass | 210.44 g·mol−1 |
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GHS labelling: | |
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H242, H315, H319, H335 | |
P210, P220, P234, P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, P411, P420, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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References
edit- ^ Arip, Mohamad Nasir Mat; Heng, Lee Yook; Ahmad, Musa; Aishah Hasbullah, Siti (2013). "Reaction of 2,6-dichloroquinone-4-chloroimide (Gibbs reagent) with permethrin – an optical sensor for rapid detection of permethrin in treated wood". Chem Cent J. 7: 122. doi:10.1186/1752-153X-7-122. PMC 3726330. PMID 23867006.
- ^ Svobodová, D.; Křenek, P.; Fraenkl, M.; Gasparič, J. (1977). "Colour Reaction of Phenols with the Gibbs Reagent. The Reaction Mechanism and Decomposition and Stabilisation of the Reagent". Microchim. Acta. 67 (3–4): 251–264. doi:10.1007/BF01213035. S2CID 93587492.