Wikipedia

Atomic battery

For the generation of radioactive isotopes, see radionuclide generator.

An atomic battery, nuclear battery, radioisotope battery or radioisotope generator uses energy from the decay of a radioactive isotope to generate electricity. Like a nuclear reactor, it generates electricity from nuclear energy, but it differs by not using a chain reaction. Although commonly called batteries, atomic batteries are technically not electrochemical and cannot be charged or recharged. Although they are very costly, they have extremely long lives and high energy density, so they are typically used as power sources for equipment that must operate unattended for long periods, such as spacecraft, pacemakers, underwater systems, and automated scientific stations in remote parts of the world.[1][2][3]

Nuclear batteries began in 1913, when Henry Moseley first demonstrated a current generated by charged-particle radiation. In the 1950s and 1960s, this field of research got much attention for applications requiring long-life power sources for spacecraft. In 1954, RCA researched a small atomic battery for small radio receivers and hearing aids.[4] Since RCA's initial research and development in the early 1950s, many types and methods have been designed to extract electrical energy from nuclear sources. The scientific principles are well known, but modern nano-scale technology and new wide-bandgap semiconductors have allowed the making of new devices and interesting material properties not previously available.

Nuclear batteries can be classified by their means of energy conversion into two main groups: thermal converters and non-thermal converters. The thermal types convert some of the heat generated by the nuclear decay into electricity; an example is the radioisotope thermoelectric generator (RTG), often used in spacecraft. The non-thermal converters, such as betavoltaic cells, extract energy directly from the emitted radiation, before it is degraded into heat; they are easier to miniaturize and do not need a thermal gradient to operate, so they can be used in small machines.

Atomic batteries usually have an efficiency of 0.1–5%. High-efficiency betavoltaic devices can reach 6–8% efficiency.[5]

Thermal conversion

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Thermionic conversion

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A thermionic converter consists of a hot electrode, which thermionically emits electrons over a space-charge barrier to a cooler electrode, producing a useful power output. Caesium vapor is used to optimize the electrode work functions and provide an ion supply (by surface ionization) to neutralize the electron space charge.[6]

Thermoelectric conversion

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Main article: Radioisotope thermoelectric generator
 
Radioisotope-powered cardiac pacemaker being developed by the Atomic Energy Commission, circa 1967.

A radioisotope thermoelectric generator (RTG) uses thermocouples. Each thermocouple is formed from two wires of different metals (or other materials). A temperature gradient along the length of each wire produces a voltage gradient from one end of the wire to the other; but the different materials produce different voltages per degree of temperature difference. By connecting the wires at one end, heating that end but cooling the other end, a usable, but small (millivolts), voltage is generated between the unconnected wire ends. In practice, many are connected in series (or in parallel) to generate a larger voltage (or current) from the same heat source, as heat flows from the hot ends to the cold ends. Metal thermocouples have low thermal-to-electrical efficiency. However, the carrier density and charge can be adjusted in semiconductor materials such as bismuth telluride and silicon germanium to achieve much higher conversion efficiencies.[7]

Thermophotovoltaic conversion

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Thermophotovoltaic (TPV) cells work by the same principles as a photovoltaic cell, except that they convert infrared light (rather than visible light) emitted by a hot surface, into electricity. Thermophotovoltaic cells have an efficiency slightly higher than thermoelectric couples and can be overlaid on thermoelectric couples, potentially doubling efficiency. The University of Houston TPV Radioisotope Power Conversion Technology development effort is aiming at combining thermophotovoltaic cells concurrently with thermocouples to provide a 3- to 4-fold improvement in system efficiency over current thermoelectric radioisotope generators. [citation needed]

Stirling generators

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Main article: Stirling radioisotope generator

A Stirling radioisotope generator is a Stirling engine driven by the temperature difference produced by a radioisotope. A more efficient version, the advanced Stirling radioisotope generator, was under development by NASA, but was cancelled in 2013 due to large-scale cost overruns.[8]

Non-thermal conversion

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Non-thermal converters extract energy from emitted radiation before it is degraded into heat. Unlike thermoelectric and thermionic converters their output does not depend on the temperature difference. Non-thermal generators can be classified by the type of particle used and by the mechanism by which their energy is converted.

Electrostatic conversion

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Energy can be extracted from emitted charged particles when their charge builds up in a conductor, thus creating an electrostatic potential. Without a dissipation mode the voltage can increase up to the energy of the radiated particles, which may range from several kilovolts (for beta radiation) up to megavolts (alpha radiation). The built up electrostatic energy can be turned into usable electricity in one of the following ways.

Direct-charging generator

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A direct-charging generator consists of a capacitor charged by the current of charged particles from a radioactive layer deposited on one of the electrodes. Spacing can be either vacuum or dielectric. Negatively charged beta particles or positively charged alpha particles, positrons or fission fragments may be utilized. Although this form of nuclear-electric generator dates back to 1913, few applications have been found in the past for the extremely low currents and inconveniently high voltages provided by direct-charging generators. Oscillator/transformer systems are employed to reduce the voltages, then rectifiers are used to transform the AC power back to direct current.

English physicist H. G. J. Moseley constructed the first of these. Moseley's apparatus consisted of a glass globe silvered on the inside with a radium emitter mounted on the tip of a wire at the center. The charged particles from the radium created a flow of electricity as they moved quickly from the radium to the inside surface of the sphere. As late as 1945 the Moseley model guided other efforts to build experimental batteries generating electricity from the emissions of radioactive elements.

Electromechanical conversion

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Main article: Radioisotope piezoelectric generator

Electromechanical atomic batteries use the buildup of charge between two plates to pull one bendable plate towards the other, until the two plates touch, discharge, equalizing the electrostatic buildup, and spring back. The mechanical motion produced can be used to produce electricity through flexing of a piezoelectric material or through a linear generator. Milliwatts of power are produced in pulses depending on the charge rate, in some cases multiple times per second (35 Hz).[9]

Radiovoltaic conversion

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A radiovoltaic (RV) device converts the energy of ionizing radiation directly into electricity using a semiconductor junction, similar to the conversion of photons into electricity in a photovoltaic cell. Depending on the type of radiation targeted, these devices are called alphavoltaic (AV, αV), betavoltaic (BV, βV) and/or gammavoltaic (GV, γV). Betavoltaics have traditionally received the most attention since (low-energy) beta emitters cause the least amount of radiative damage, thus allowing a longer operating life and less shielding. Interest in alphavoltaic and (more recently) gammavoltaic devices is driven by their potential higher efficiency.

Alphavoltaic conversion

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Alphavoltaic devices use a semiconductor junction to produce electrical energy from energetic alpha particles.[10][11]

Betavoltaic conversion

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Main article: Betavoltaic device

Betavoltaic devices use a semiconductor junction to produce electrical energy from energetic beta particles (electrons). A commonly used source is the hydrogen isotope tritium, which is employed in City Labs' NanoTritium batteries.

Betavoltaic devices are particularly well-suited to low-power electrical applications where long life of the energy source is needed, such as implantable medical devices or military and space applications.[12]

The Chinese startup Betavolt claimed in January 2024 to have a miniature device in the pilot testing stage.[13] It is allegedly generating 100 microwatts of power and a voltage of 3V and has a lifetime of 50 years without any need for charging or maintenance.[13] Betavolt claims it to be the first such miniaturised device ever developed.[13] It gains its energy from the isotope nickel-63, held in a module the size of a very small coin.[14] As it is consumed, the nickel-63 decays into stable, non-radioactive isotopes of copper, which pose no environmental threat.[14] It contains a thin wafer of nickel-63 providing beta particle electrons sandwiched between two thin crystallographic diamond semiconductor layers.[15][16]

Gammavoltaic conversion

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Gammavoltaic devices use a semiconductor junction to produce electrical energy from energetic gamma particles (high-energy photons). They have only been considered in the 2010s[17][18][19][20] but were proposed as early as 1981.[21]

A gammavoltaic effect has been reported in perovskite solar cells.[17] Another patented design involves scattering of the gamma particle until its energy has decreased enough to be absorbed in a conventional photovoltaic cell.[18] Gammavoltaic designs using diamond and Schottky diodes are also being investigated.[19][20]

Radiophotovoltaic (optoelectric) conversion

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Main article: Optoelectric nuclear battery

In a radiophotovoltaic (RPV) device the energy conversion is indirect: the emitted particles are first converted into light using a radioluminescent material (a scintillator or phosphor), and the light is then converted into electricity using a photovoltaic cell. Depending on the type of particle targeted, the conversion type can be more precisely specified as alphaphotovoltaic (APV or α-PV),[22] betaphotovoltaic (BPV or β-PV)[23] or gammaphotovoltaic (GPV or γ-PV).[24]

Radiophotovoltaic conversion can be combined with radiovoltaic conversion to increase the conversion efficiency.[25]

Pacemakers

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Medtronic and Alcatel developed a plutonium-powered pacemaker, the Numec NU-5, powered by a 2.5 Ci slug of plutonium 238, first implanted in a human patient in 1970. The 139 Numec NU-5 nuclear pacemakers implanted in the 1970s are expected to never need replacing, an advantage over non-nuclear pacemakers, which require surgical replacement of their batteries every 5 to 10 years. The plutonium "batteries" are expected to produce enough power to drive the circuit for longer than the 88-year halflife of the plutonium-238.[26][27][28][29] The last of these units was implanted in 1988, as lithium-powered pacemakers, which had an expected lifespan of 10 or more years without the disadvantages of radiation concerns and regulatory hurdles, made these units obsolete.

Betavoltaic batteries are also being considered as long-lasting power sources for lead-free pacemakers.[30]

Radioisotopes used

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Atomic batteries use radioisotopes that produce low energy beta particles or sometimes alpha particles of varying energies. Low energy beta particles are needed to prevent the production of high energy penetrating Bremsstrahlung radiation that would require heavy shielding. Radioisotopes such as tritium, nickel-63, promethium-147, and technetium-99 have been tested. Plutonium-238, curium-242, curium-244 and strontium-90 have been used.[31] Besides the nuclear properties of the used isotope, there are also the issues of chemical properties and availability. A product deliberately produced via neutron irradiation or in a particle accelerator is more difficult to obtain than a fission product easily extracted from spent nuclear fuel.

Plutonium-238 must be deliberately produced via neutron irradiation of Neptunium-237 but it can be easily converted into a stable plutonium oxide ceramic. Strontium-90 is easily extracted from spent nuclear fuel but must be converted into the perovskite form strontium titanate to reduce its chemical mobility, cutting power density in half. Caesium-137, another high yield nuclear fission product, is rarely used in atomic batteries because it is difficult to convert into chemically inert substances. Another undesirable property of Cs-137 extracted from spent nuclear fuel is that it is contaminated with other isotopes of Caesium which reduce power density further.

Micro-batteries

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In the field of microelectromechanical systems (MEMS), nuclear engineers at the University of Wisconsin, Madison have explored the possibilities of producing minuscule batteries which exploit radioactive nuclei of substances such as polonium or curium to produce electric energy.[citation needed] As an example of an integrated, self-powered application, the researchers have created an oscillating cantilever beam that is capable of consistent, periodic oscillations over very long time periods without the need for refueling. Ongoing work demonstrate that this cantilever is capable of radio frequency transmission, allowing MEMS devices to communicate with one another wirelessly.

These micro-batteries are very light and deliver enough energy to function as power supply for use in MEMS devices and further for supply for nanodevices.[32]

The radiation energy released is transformed into electric energy, which is restricted to the area of the device that contains the processor and the micro-battery that supplies it with energy.[33]: 180–181 

See also

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References

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  1. ^ "A nuclear battery the size and thickness of a penny". Gizmag, 9 October 2009.
  2. ^ "Tiny 'nuclear batteries' unveiled". BBC News, Thursday, 8 October 2009.
  3. ^ "NanoTritium™ Battery Technology". City Labs. Retrieved 25 May 2023.
  4. ^ "Atomic Battery Converts Radioactivity Directly into Electricity". Popular Mechanics, April 1954, p. 87.
  5. ^ "Thermoelectric Generators". electronicbus.com. Archived from the original on 10 January 2016. Retrieved 23 February 2015.
  6. ^ Fitzpatrick, G. O. (19 May 1987). "Thermionic converter". Office of Scientific and Technical Information. OSTI 6377296.
  7. ^ McCoy, J.C (October 1995). An overview of the Radioisotope Thermoelectric Generator Transportation System Program. STAIF 96: space technology and applications international forum, Albuquerque, NM (United States), 7-11 Jan 1996. OSTI 168371.
  8. ^ The ASRG Cancellation in Context Future Planetary Exploration
  9. ^ Lal, Amit; Rajesh Duggirala; Hui Li (2005). "Pervasive Power:A Radioisotope-Powered Piezoelectric Generator" (PDF). IEEE Pervasive Computing. 4: 53–61. doi:10.1109/MPRV.2005.21. S2CID 18891519. Archived from the original (PDF) on 21 June 2007.
  10. ^ NASA Glenn Research Center, Alpha- and Beta-voltaics Archived 18 October 2011 at the Wayback Machine (accessed 4 October 2011)
  11. ^ Sheila G. Bailey, David M. Wilt, Ryne P. Raffaelle, and Stephanie L. Castro, Alpha-Voltaic Power Source Designs Investigated Archived 16 July 2010 at the Wayback Machine, Research and Technology 2005, NASA TM-2006-214016, (accessed 4 October 2011)
  12. ^ "Tritium Batteries as a Source of Nuclear Power". City Labs. Retrieved 25 May 2023.
  13. ^ a b c Anthony Cuthbertson (12 January 2024). "Nuclear battery produces power for 50 years without needing to charge". The Independent. Retrieved 14 January 2024.
  14. ^ a b Mark Tyson (13 January 2024). "Chinese-developed nuclear battery has a 50-year lifespan — Betavolt BV100 built with Nickel-63 isotope and diamond semiconductor material". Tom's Hardware. Retrieved 17 January 2024.
  15. ^ "Betavolt says its diamond nuclear battery can power devices for 50 years". David Szondy for New Atlas, 16 January 2024. Accessed 17 January 2024.
  16. ^ "贝塔伏特公司成功研制民用原子能电池" ('Betavolt successfully develops atomic energy battery for civilian use'), on Betavolt website (in Chinese). Accessed 17 January 2024.
  17. ^ a b Hiroshi Segawa; Ludmila Cojocaru; Satoshi Uchida (7 November 2016). "Gammavoltaic Property of Perovskite Solar Cell - Toward the Novel Nuclear Power Generation". Proceedings of International Conference Asia-Pacific Hybrid and Organic Photovoltaics. Retrieved 1 September 2020.
  18. ^ a b 20180350482, Ryan, Michael Doyle, "Gamma Voltaic Cell", issued 2018-12-06 
  19. ^ a b MacKenzie, Gordon (October 2017). "A Diamond Gammavoltaic Cell". UK Research and Innovation.
  20. ^ a b Mackenzie, Robbie (19 June 2020). "Diamond Gammavoltaic Cells for Biasless Gamma Dosimetry". South West Nuclear Hub. Retrieved 1 September 2020.
  21. ^ "Popular Science". January 1981.
  22. ^ Purbandari, Dessy; Ferdiansjah, Ferdiansjah; Sujitno, Tjipto (2019). "Optimization of the Alpha Energy Deposited in Radioluminescence Thin Film for Alphaphotovoltaic Application". Proceeding International Conference on Science and Engineering. 2: 41–44. doi:10.14421/icse.v2.52. S2CID 141390756.
  23. ^ Berman, Veronika; Litz, Marc Stuart; Russo, Johnny (2018). "Investigation of Electrical Power Degradation in Beta Photovoltaic (βPV) and Beta Voltaic (βV) Power Sources Using 63Ni and 147Pm". Defense Technical Information Center. S2CID 139545450.
  24. ^ LIAKOS, John K. (1 December 2011). "Gamma-Ray-Driven Photovoltaic Cells via a Scintillator Interface". Journal of Nuclear Science and Technology. 48 (12): 1428–1436. doi:10.1080/18811248.2011.9711836. ISSN 0022-3131. S2CID 98136174.
  25. ^ Guo, Xiao; Liu, Yunpeng; Xu, Zhiheng; Jin, Zhangang; Liu, Kai; Yuan, Zicheng; Gong, Pin; Tang, Xiaobin (1 June 2018). "Multi-level radioisotope batteries based on 60Co γ source and Radio-voltaic/Radio-photovoltaic dual effects". Sensors and Actuators A: Physical. 275: 119–128. doi:10.1016/j.sna.2018.04.010. ISSN 0924-4247. S2CID 117568424.
  26. ^ "MedTech Memoirs: The Plutonium-Powered Pacemaker".
  27. ^ "Nuclear pacemaker still energized after 34 years".
  28. ^ R L Shoup."Nuclear-Powered Cardiac Pacemakers".
  29. ^ Crystal Phend."Extra Battery Life Not Always a Plus for Nuclear-Powered Pacemaker".
  30. ^ "Pacemaker Batteries for Leadless Pacemakers". City Labs. Retrieved 25 May 2023.
  31. ^ Bindu, K.C.; Harmon, Frank; Starovoitova, Valeriia; Stoner, Jon; Wells, Douglas (2013). "Optimization of commercial scale photonuclear production of radioisotopes". AIP Conference Proceedings. 1525 (1): 407–411. Bibcode:2013AIPC.1525..407B. doi:10.1063/1.4802359.
  32. ^ Waldner, Jean-Baptiste (2007). Inventer l'Ordinateur du XXIème Siècle. London: Hermes Science. p. 172. ISBN 978-2-7462-1516-0.
  33. ^ Waldner, Jean-Baptiste (2008). Nanocomputers and Swarm Intelligence. London: ISTE John Wiley & Sons. ISBN 978-1-84704-002-2. radioactive nuclei releases electrons that shoot the negative pole of the battery
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