A Beckmann thermometer is a device used to measure small differences of temperature, but not absolute temperature values. It was invented by Ernst Otto Beckmann (1853 – 1923), a German chemist, for his measurements of colligative properties in 1905.[1] Today its use has largely been superseded by platinum PT100 resistance thermometers and thermocouples.
A Beckmann thermometer's length is usually 40 – 50 cm. The temperature scale typically covers about 5 °C and it is divided into hundredths of a degree. With a magnifier it is possible to estimate temperature changes to 0.001 °C. The peculiarity of Beckmann's thermometer design is a reservoir (R on diagram) at the upper end of the tube, by means of which the quantity of mercury in the bulb can be increased or diminished so that the instrument can be set to measure temperature differences at either high or low temperature values. In contrast, the range of a typical mercury-in-glass thermometer is fixed, being set by the calibration marks etched on the glass or the marks on the printed scale.
Calibration
editIn setting the thermometer, a sufficient amount of mercury must be left in the bulb and stem to give readings between the required temperatures. First, the thermometer is inverted and gently tapped so that the mercury in the reservoir lodges in the bend (B) at the end of the stem. Next, the bulb is heated until the mercury in the stem joins the mercury in the reservoir. The thermometer is then placed in a bath one or two degrees above the upper limit of temperatures to be measured.
The upper end of the tube is gently tapped with the finger, and the mercury suspended in the upper part of the reservoir will be jarred down, thus separating it from the thread at the bend (B). The thermometer will then be set for readings between the required temperatures.
See also
editReferences
edit- ^ Beckmann, Ernst (1905). "Modifikation des Thermometers für die bestimmung von Molekulargewichten und kleinen Temperaturdifferenzen" [Modification of the thermometer for the determination of molecular weights and small temperature differences]. Zeitschrift für physikalische Chemie. 51: 329–343. doi:10.1515/zpch-1905-5120. S2CID 102429187.
Further reading
edit- Jones, Harry C. (1915). The Elements of Physical Chemistry. New York: Macmillan. pp. 228–229. Retrieved 2008-02-09.
beckmann thermometer.
- Ferry, Ervin Sidney (1918). A Handbook of Physics Measurements. Boston: Stanhope Press. pp. 67–68. Retrieved 2008-02-09.
- - From which much of this article was taken
- Findlay, Alexander (1920). Practical Physical Chemistry. London: Longmans, Green and Company. pp. 130–132. Retrieved 2008-02-09.
beckmann thermometer.
- Sella, Andrea (December 2007). "Classic Kit: Beckmann thermometer". Chemistry World. Retrieved 2023-04-16.