The Britton–Robinson buffer (BRB or PEM) is a "universal" pH buffer used for the pH range from 2 to 12. It has been used historically as an alternative to the McIlvaine buffer, which has a smaller pH range of effectiveness (from 2 to 8).[1]
Universal buffers consist of mixtures of acids of diminishing strength (increasing pKa), so that the change in pH is approximately proportional to the amount of alkali added. It consists of a mixture of 0.04 M boric acid, 0.04 M phosphoric acid and 0.04 M acetic acid that has been titrated to the desired pH with 0.2 M sodium hydroxide. Britton and Robinson also proposed a second formulation that gave an essentially linear pH response to added alkali from pH 2.5 to pH 9.2 (and buffers to pH 12). This mixture consists of 0.0286 M citric acid, 0.0286 M monopotassium phosphate, 0.0286 M boric acid, 0.0286 M veronal and 0.0286 M hydrochloric acid titrated with 0.2 M sodium hydroxide.
The buffer was invented in 1931 by the English chemist Hubert Thomas Stanley "Kevin" Britton (1892–1960) and the New Zealand chemist Robert Anthony Robinson (1904–1979).[2]
See also
editReferences
edit- ^ Mongay, Carlos; Cerdà, Víctor (January 1974). "A Britton-Robinson Buffer of Known Ionic Strength". Annali di Chimica. 64.
- ^ Britton, Hubert Thomas Stanley; Robinson, Robert Anthony (1931). "The use of the antimony–antimonous oxide electrode in the determination of the concentration of hydrogen ions and in potenliometric titrations. The Prideaux–Ward universal buffer mixture". Journal of the Chemical Society (Resumed). Royal Society of Chemistry: 747–748. doi:10.1039/JR9310001456.
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