Chloropentammineplatinum chloride is an inorganic compound with the formula [PtCl(NH3)5]Cl3. It is a chloride salt of the coordination complex [PtCl(NH3)5]+. It is a white, water soluble solid.
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| Other names
Pentammineplatinum(IV) chloride, Pentammineplatinum chloride, Chloropentammineplatinum(IV) chloride
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| Identifiers | |
3D model (JSmol)
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| Cl4H15N5Pt | |
| Molar mass | 422.04 g·mol−1 |
| Appearance | white solid |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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The compound is prepared by treating potassium hexachloroplatinate with aqueous ammonia:[1]
- K2PtCl6 + 5 NH3 → [PtCl(NH3)5]Cl3 + 2 KCl
Related platinum(IV) ammines
editThe title complex is one of several platinum ammine complexes.
- Hexaammineplatinum(IV) chloride
- Trichlorotriammineplatinum(IV) chloride[2]
- cis-Tetrachlorodiammineplatinum(IV)[3]
- trans-Tetrachlorodiammineplatinum(IV) (RN 16986-23-5)[3]
References
edit- ^ Curtis, Neville J.; Lawrance, Geoffrey A.; Sargeson, Alan M.; Johnson, Ronald C. (1986). "Pentaammineplatinum(IV) Complexes". Inorganic Syntheses. Vol. 24. pp. 277–279. doi:10.1002/9780470132555.ch74. ISBN 9780471834410.
- ^ Gildengershel, Kh. I. (1966). "Synthesis of Cleve's salts [Pt(NH3)3Cl]Cl and [Pt(NH3)3Cl3]Cl". Zhurnal Prikladnoi Khimii. 39: 223-5.
- ^ a b Kauffman, George B.; Slusarczuk, George; Kirschner, Stanley (1963). "cis ‐ and trans ‐Tetrachlorodiammineplatinum(IV)". Inorganic Syntheses. Vol. 7. pp. 236–238. doi:10.1002/9780470132388.ch62. ISBN 9780470131664.