Copper(II) perchlorate

Copper(II) perchlorate
	; Copper(II) perchlorate hexahydrate
Names
	IUPAC name Copper(II) perchlorate
	Other names Cupric perchlorate
Identifiers
CAS Number	10294-46-9 (hexahydrate) ;
3D model (JSmol)	Interactive image;
ChemSpider	26246;
ECHA InfoCard	100.033.978
EC Number	237-391-4;
PubChem CID	28211 (hexahydrate);
UNII	57JSH2LO1G ;
CompTox Dashboard (EPA)	DTXSID40890720 ;
	InChI InChI=1S/2ClHO4.Cu/c22-1(3,4)5;/h2(H,2,3,4,5);/q;;+2/p-2 Key: YRNNKGFMTBWUGL-UHFFFAOYSA-L;
	SMILES [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Cu+2];
Properties
Chemical formula	Cu(ClO4)2
Molar mass	262.447 g/mol (anhydrous) ; 370.539 g/mol (hexahydrate)
Appearance	Blue crystalline hygroscopic solid (hexahydrate)
Odor	odorless
Density	2.225 g/cm3 (hexahydrate)
Melting point	82 °C (180 °F; 355 K) (hexahydrate)
Boiling point	120 °C (248 °F; 393 K) (hexahydrate)
Solubility in water	146 g/(100 ml) (30°C)
Refractive index (nD)	1.505 (hexahydrate)
Hazards
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H272, H315, H319, H335
Precautionary statements	P210, P220, P221, P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P405, P501
	NIOSH (US health exposure limits):
PEL (Permissible)	TWA 1 mg/m3 (as Cu)
REL (Recommended)	TWA 1 mg/m3 (as Cu)
IDLH (Immediate danger)	TWA 100 mg/m3 (as Cu)
Safety data sheet (SDS)	External MSDS
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Copper(II) perchlorate is an inorganic compound with the chemical formula Cu(ClO₄)₂(H₂O)_x. The anhydrous solid is rarely encountered but several hydrates are known. Most important is the perchlorate salt of the aquo complex copper(II) perchlorate hexahydrate, [Cu(H₂O)₆]²⁺.^[3]

Infrared spectroscopic studies of anhydrous copper(II) perchlorate provided some of the first evidence for the binding of perchlorate anion to a metal ion.^[4] The structure of this compound was eventually deduced by X-ray crystallography. Copper resides in a distorted octahedral environment and the perchlorate ligands bridge between the Cu(II) centers.^[5]

Safety

Like other perchlorates, copper(II) perchlorate is a strong oxidant.

References

^ "Copper(Ii) Perchlorate Hexahydrate | 10294-46-9".
^ ^a ^b ^c NIOSH Pocket Guide to Chemical Hazards. "#0150". National Institute for Occupational Safety and Health (NIOSH).
^ Gallucci, J. C.; Gerkin, R. E. (1989). "Structure of copper(II) perchlorate hexahydrate". Acta Crystallogr. C. 45 (9): 1279–1284. doi:10.1107/S0108270189000818. PMID 2557867.
^ Hathaway, B. J.; Underhill, A. E. (1961). "592. The infrared spectra of some transition-metal perchlorates". Journal of the Chemical Society (Resumed): 3091. doi:10.1039/JR9610003091.
^ Pascal, Jean-Louis; Favier, Frédéric (1998). "Inorganic Perchlorato Complexes". Coordination Chemistry Reviews. 178–180: 865–902. doi:10.1016/S0010-8545(98)00102-7.

This inorganic compound–related article is a stub. You can help Wikipedia by expanding it.

[1] "Copper(Ii) Perchlorate Hexahydrate | 10294-46-9".

[PGCH-2] NIOSH Pocket Guide to Chemical Hazards. "#0150". National Institute for Occupational Safety and Health (NIOSH).

[3] Gallucci, J. C.; Gerkin, R. E. (1989). "Structure of copper(II) perchlorate hexahydrate". Acta Crystallogr. C. 45 (9): 1279–1284. doi:10.1107/S0108270189000818. PMID 2557867.

[4] Hathaway, B. J.; Underhill, A. E. (1961). "592. The infrared spectra of some transition-metal perchlorates". Journal of the Chemical Society (Resumed): 3091. doi:10.1039/JR9610003091.

[5] Pascal, Jean-Louis; Favier, Frédéric (1998). "Inorganic Perchlorato Complexes". Coordination Chemistry Reviews. 178–180: 865–902. doi:10.1016/S0010-8545(98)00102-7.

[3]

[1]

[2]

[4]

[5]

Names


Copper(II) perchlorate hexahydrate
IUPAC name Copper(II) perchlorate
Other names Cupric perchlorate
Identifiers
CAS Number	10294-46-9 (hexahydrate)^Y
3D model (JSmol)	Interactive image
ChemSpider	26246
ECHA InfoCard	100.033.978
EC Number	237-391-4
PubChem CID	28211 (hexahydrate)
UNII	57JSH2LO1G^Y
CompTox Dashboard (EPA)	DTXSID40890720
InChI InChI=1S/2ClHO4.Cu/c22-1(3,4)5;/h2(H,2,3,4,5);/q;;+2/p-2 Key: YRNNKGFMTBWUGL-UHFFFAOYSA-L
SMILES [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Cu+2]
Properties
Chemical formula	Cu(ClO₄)₂
Molar mass	262.447 g/mol (anhydrous) 370.539 g/mol (hexahydrate)
Appearance	Blue crystalline hygroscopic solid (hexahydrate)
Odor	odorless
Density	2.225 g/cm³ (hexahydrate)
Melting point	82 °C (180 °F; 355 K) (hexahydrate)
Boiling point	120 °C (248 °F; 393 K) (hexahydrate)
Solubility in water	146 g/(100 ml) (30°C)
Refractive index (n_D)	1.505 (hexahydrate)^[1]
Hazards
GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H272, H315, H319, H335
Precautionary statements	P210, P220, P221, P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P405, P501
NIOSH (US health exposure limits):
PEL (Permissible)	TWA 1 mg/m³ (as Cu)^[2]
REL (Recommended)	TWA 1 mg/m³ (as Cu)^[2]
IDLH (Immediate danger)	TWA 100 mg/m³ (as Cu)^[2]
Safety data sheet (SDS)	External MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Y verify (what is ^YN ?) Infobox references