Iodoacetone is an organoiodine compound with the chemical formula C
3H
5IO[1][2] The substance is a colorless liquid[3] under normal conditions, soluble in ethanol.[4][5]
| |
| Names | |
|---|---|
| Preferred IUPAC name
1-Iodopropan-2-one | |
| Identifiers | |
3D model (JSmol)
|
|
| ChemSpider | |
| ECHA InfoCard | 100.019.238 |
| EC Number |
|
PubChem CID
|
|
CompTox Dashboard (EPA)
|
|
| |
| |
| Properties | |
| C3H5IO | |
| Molar mass | 183.976 g·mol−1 |
| Appearance | Yellow liquid |
| Density | 2.0±0.1 g/cm3 |
| Boiling point | 163.1 °C (325.6 °F; 436.2 K) |
| Vapor pressure | 2.1±0.3 mmHg |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Synthesis
editThe reaction of acetone and iodine produces iodoacetone. The reaction is typically acid catalysed and first order with respect to acetone and the acid catalyst:[3][6]
- C3H6O + I2 → HI + C3H5IO
See also
editReferences
edit- ^ "1-iodoacetone". chemsynthesis.com. Retrieved 1 June 2017.
- ^ Solly, R.K.; Golden, D.M.; Benson, S.W. (1970). "Thermochemical properties of iodoacetone. Intramolecular electrostatic interactions in polar molecules". J. Am. Chem. Soc. 92 (15): 4653–4656. doi:10.1021/ja00718a030.
- ^ a b Meyer, Earl (2010). "Rate and Activation Energy of the Iodination of Acetone" (PDF).
- ^ "Properties of substance: iodoacetone". chemister.ru. Retrieved 1 June 2017.
- ^ CRC Handbook of Chemistry and Physics (90 ed.). CRC Press. 2010. pp. 5–23.
- ^ "1-iodoacetone". webbook.nist.gov. Retrieved 1 June 2017.