Jan Jozef van Deemter (31 March 1918 – 10 October 2004) was a Dutch physicist and engineer known for the Van Deemter equation in chromatography.[1][2][3]
Jan Jozef van Deemter | |
---|---|
Born | 31 March 1918 |
Died | 10 October 2004 | (aged 86)
Nationality | Dutch |
Alma mater | University of Groningen University of Amsterdam |
Known for | Van Deemter equation |
Scientific career | |
Institutions | Royal Dutch Shell |
Thesis | Theoretische en numerieke behandeling van ontwaterings- en infiltratie-stromings-problemen |
Doctoral advisor | Bartel Leendert van der Waerden |
He obtained his doctorate in physics from the University of Amsterdam in June of 1950. Starting in 1947 he began work for Royal Dutch Shell as a researcher and it was there that he developed and published his article in 1956.[4]
Van Deemter equation
editThe van Deemter equation relates the resolving power of a chromatographic column to the various flow and kinetic parameters which cause peak broadening through
Where HETP is the height equivalent theoretical plate, A is the eddy-diffusion parameter, B is the longitudinal diffusion coefficient of the eluting material in the longitudinal direction, C is the resistance to mass transfer coefficient of the analyte between mobile and stationary phase, and u is the linear velocity of the column flow.
References
edit- ^ 75 Years of Chromatography: A Historical Dialogue. Elsevier. 26 August 2011. pp. 461–. ISBN 978-0-08-085817-3.
- ^ van Deemter JJ, Zuiderweg FJ and Klinkenberg A (1956). "Longitudinal diffusion and resistance to mass transfer as causes of non ideality in chromatography". Chem. Eng. Sci. 5 (6): 271–289. Bibcode:1956ChEnS...5..271V. doi:10.1016/0009-2509(56)80003-1.
- ^ Ettre, Leslie S. (1979). "J.J. Van Deemter". 75 years of Chromatography a Historical Dialogue. Journal of Chromatography Library. Vol. 17. pp. 461–465. doi:10.1016/S0301-4770(08)60683-1. ISBN 9780444417541. ISSN 0301-4770.
- ^ "Dr. J J van Deemter is retiring" (in Dutch). 1978.