Lanthanum forms several alloys with nickel, including LaNi5, La2Ni7, LaNi2, LaNi3, La2Ni3, LaNi and La3Ni etc.[1]
| Identifiers | |
|---|---|
| Properties | |
| LaNi | |
| Molar mass | 197.60 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
LaNi5
edit| Names | |
|---|---|
| Other names
Lanthanum pentanickel
Pentanickel lanthanum | |
| Identifiers | |
| Properties | |
| LaNi5 | |
| Molar mass | 432.37 |
| Appearance | gold solid[2] |
| Density | 7.950 g/cm3[3] |
| reacts with water[3] | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
LaNi5 is an intermetallic compound with a CaCu5 structure. It belongs to the hexagonal crystal system.[4] It can be oxidized by air above 200 °C, and react with hydrochloric acid, sulfuric acid or nitric acid above 20 °C.[5] LaNi5 can be used as a catalyst for hydrogenation reactions.[6][7]
Other alloys
editIn addition to LaNi5, there are other alloys such as La2Ni7, LaNi2, LaNi3, La2Ni3, LaNi, and La3Ni, and nonstoichiometric alloys such as LaNi2.286 (tetragonal, space group I4̄2m).[8] The nickel atoms in LaxNiy can also be replaced by other atoms, such as LaNi2.5Co2.5.[9]
See also
editReferences
edit- ^ Picard, G. S.; Mottot, Y. E.; Tremillon, B. L. Study on electrowinning of solid lanthanum-nickel alloys in lithium chloride-potassium chloride eutectic melt. Proceedings - Electrochemical Society, 1984. 84-2. pp 585-602.
- ^ 13399 MSDS. Alfa Aesar. [2017-11-18]
- ^ a b Sigma-Aldrich Co., Lanthanum-nickel alloy. Retrieved on 2017-11-18.
- ^ Zhang, Yang-huan; Li, Peng-xin; Yang, Tai; Zhai, Ting-ting; Yuan, Ze-ming; Guo, Shi-hai (December 2014). "Effects of substituting La with M (M=Sm, Nd, Pr) on electrochemical hydrogen storage characteristics of A2B7-type electrode alloys". Transactions of Nonferrous Metals Society of China. 24 (12): 4012–4022. doi:10.1016/S1003-6326(14)63563-9.
- ^ Goncharuk, A. B.; Endrzheevskaya, S. N. Stability of lanthanum nickel (LaNi5) intermetallide in liquid and gaseous media{{Country data {{{1}}} | flag link/core | variant = | size = | name = | altlink = national rugby union team | altvar = rugby union}}. Poroshkovaya Metallurgiya (Kiev), 1980. 8: 77-79
- ^ Imamura, Hayao; Kato, Yuzo; Yamada, Kazuhiro; Tsuchiya, Susumu (January 1986). "Preparation and properties of raney catalysts from rare earth intermetallic compounds". Applied Catalysis. 27 (2): 243–256. doi:10.1016/S0166-9834(00)82921-8.
- ^ 吴富英, 安越, 宋林,等. 氟处理后的镧镍五对乙基咔唑的催化加氢性能[J]. 化学反应工程与工艺, 2015, 31(5):407-411.
- ^ A.V. Klimyenko, J. Seuntjens, L.L. Miller, B.J. Beaudry, R.A. Jacobson, K.A. Gschneidner (November 1988). "Structure of LaNi2.286 and the La-Ni system from LaNi1.75 to LaNi2.50". Journal of the Less Common Metals. 144 (1): 133–141. doi:10.1016/0022-5088(88)90357-8. ISSN 0022-5088. Archived from the original on 2019-08-31. Retrieved 2018-11-27.
{{cite journal}}: CS1 maint: multiple names: authors list (link) - ^ Sakai T, Miyamura H, Kuriyama N, et al. The influence of small amounts of added elements on various anode performance characteristics for LaNi2. 5Co2. 5-based alloys[J]. Journal of the Less common Metals, 1990, 159: 127-139.