Lead picrate

Lead picrate
Names
	IUPAC name Lead(II) 2,4,6-trinitrophenolate
	Other names Lead dipicrate
Identifiers
CAS Number	25721-38-4; 6477-64-1;
3D model (JSmol)	Interactive image;
ECHA InfoCard	100.210.303
EC Number	229-335-2;
PubChem CID	3045289; 162344796;
CompTox Dashboard (EPA)	DTXSID80215079 ;
	InChI InChI=1S/2C6H3N3O7.Pb/c210-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16;/h21-2,10H;/q;;+2/p-2 Key: MHVVRZIRWITSIP-UHFFFAOYSA-L;
	SMILES C1=C(C=C(C(=C1[N+](=O)[O-])[O-])[N+](=O)[O-])[N+](=O)[O-].C1=C(C=C(C(=C1[N+](=O)[O-])[O-])[N+](=O)[O-])[N+](=O)[O-].[Pb+2];
Properties
Chemical formula	C12H4N6O14Pb
Molar mass	663.4 g·mol−1
Appearance	Orange powder
Solubility in water	7.06 g/L
Solubility	Soluble in ethanol, acetic acid; Very soluble in DMF, dichloromethane
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H201, H302, H332, H360, H373, H410
Precautionary statements	P260, P261, P264, P270, P271, P273, P280, P304+P340, P330, P391, P405, P501
Autoignition; temperature	270.75-327.15 °C (519.7-621.0 °F; 600.3-543.9 K)
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Lead picrate is an organic picrate salt.^[3] It is a sensitive and highly explosive compound that is typically found as a hydrate.^[2] Dry lead picrate is incredibly dangerous and cannot be handled without explosive decomposition occurring.

History

Lead picrate was first discovered in the early 1900s. It was investigated by numerous militaries during the First World War as a potential primary explosive, most notably Germany for using it in blasting caps.^[2]

Preparation

Numerous lead precursors can be used to create lead picrate. Two of the simplest examples of lead picrate synthesis are the addition of lead(II) oxide or lead carbonate with picric acid.^[2]

References

^ ^a ^b ^c Yang, Li; Pei, Qin; Zhang, Tonglai; Zhang, Jianguo; Cao, Yunling (2007). "Solubilities and enthalpies of solution of picric acid and picrates at 298.15K in DMF, EtOH and acetic acid". Thermochimica Acta. 463 (1–2): 13–14. doi:10.1016/j.tca.2007.04.013.
^ ^a ^b ^c ^d ^e Matsukakwa, Makoto; Matsunaga, Takehiro; Yoshida, Masatake; Fujiwara, Shuzo (2004). "Synthesis and properties of lead picrates". Science and Technology of Energetic Materials. 65 (1): 7–13.
^ Jai Prakash Agrawal (2015). High Energy Materials: Propellants, Explosives and Pyrotechnics. John Wiley & Sons.

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[Yang-1] Yang, Li; Pei, Qin; Zhang, Tonglai; Zhang, Jianguo; Cao, Yunling (2007). "Solubilities and enthalpies of solution of picric acid and picrates at 298.15K in DMF, EtOH and acetic acid". Thermochimica Acta. 463 (1–2): 13–14. doi:10.1016/j.tca.2007.04.013.

[Matsukakwa-2] Matsukakwa, Makoto; Matsunaga, Takehiro; Yoshida, Masatake; Fujiwara, Shuzo (2004). "Synthesis and properties of lead picrates". Science and Technology of Energetic Materials. 65 (1): 7–13.

[Agrawal-3] Jai Prakash Agrawal (2015). High Energy Materials: Propellants, Explosives and Pyrotechnics. John Wiley & Sons.

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