Lithium hexafluoroaluminate is an inorganic chemical compound with the chemical formula Li3AlF6.[2][3]
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IUPAC name
trilithium;trifluoroalumane;trifluoride
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Other names
trilithium hexafluoroaluminate[1]
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Identifiers | |
3D model (JSmol)
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PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
AlF6Li3 | |
Molar mass | 161.79 g·mol−1 |
Appearance | White powder |
Density | 2.637 g/cm3 |
Melting point | 790 |
Hazards | |
GHS labelling: | |
Danger | |
H332, H362, H372, H411 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis
editThe compound crystallizes from melts of lithium fluoride and aluminium fluoride:[4]
- 3LiF + AlF3 → Li3AlF6.
References
edit- ^ "trilithium hexafluoroaluminate". webbook.nist.gov. NIST. Retrieved 16 June 2024.
- ^ "Lithium Hexafluoroaluminate". American Elements. Retrieved 16 June 2024.
- ^ Furukawa, George T.; Saba, William G.; Ford, James C. (1970). "Heat Capacity and Thermodynamic Properties of β-Lithium Hexafluoroaluminate, Li3AlF6, from 15 to 380 K". Journal of Research of the National Bureau of Standards, Section A. 74A (5): 631–639. doi:10.6028/jres.074A.050. ISSN 0022-4332. PMC 6696577. PMID 32523213.
- ^ Ryss, Iosif Grigorʹevich (1960). The Chemistry of Fluorine and Its Inorganic Compounds. State Publishing House for Scientific, Technical and Chemical Literature. p. 599. Retrieved 16 June 2024.