Lithium molybdate

Lithium molybdate
Identifiers
CAS Number	13568-40-6 ;
3D model (JSmol)	Interactive image;
ChemSpider	3346702 ;
ECHA InfoCard	100.033.601
EC Number	236-977-7;
PubChem CID	6093689;
CompTox Dashboard (EPA)	DTXSID80894904 ;
	InChI InChI=1S/2Li.Mo.4O/q2+1;;;;2-1 Key: NMHMDUCCVHOJQI-UHFFFAOYSA-N ; InChI=1/2Li.Mo.4O/q2+1;;;;2-1/r2Li.MoO4/c;;2-1(3,4)5/q2*+1;-2 Key: NMHMDUCCVHOJQI-FFXFYZCHAF;
	SMILES [Li+].[Li+].[O-][Mo]([O-])(=O)=O;
Properties
Chemical formula	Li2MoO4
Molar mass	173.82 g/mol
Appearance	white odorless powder; hygroscopic or transparent crystal
Density	3.07 g/cm3 (pure crystal), 2.66 g/cm3 (hydrated crystal)
Melting point	705 °C (1,301 °F; 978 K)
Solubility in water	very soluble
Hazards
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H315, H319, H335
Precautionary statements	P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)	3 0 1
Related compounds
Other cations	sodium molybdate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Lithium molybdate (Li₂Mo O₄) is a chemical compound. It is mainly used as an inhibitor in some types of industrial air conditioning.

Uses

Lithium molybdate is used as corrosion inhibitor in LiBr (Lithium bromide) absorption chiller for industrial central air conditioning. It is manufactured and shipped as either a colorless, transparent fluid or a white crystal powder. In either state it not classified as a hazardous material.

Li₂MoO₄ crystals have been found applicable for cryogenic phonon-scintillation detectors, which are used to investigate some rare nuclear processes.^[2] The use of Li₂MoO₄ ceramics for antennas has been studied due to their low loss dielectric properties and the possibility to fabricate them by a room-temperature densification method instead of conventional sintering.^[3] Li₂MoO₄ (LMO) have also been used with hollow glass microspheres (HGMS) to make low permittivity composite which has been used to make lenses for lens antennas.^[4]

References

^ "Lithium molybdate". pubchem.ncbi.nlm.nih.gov.
^ Barinova, O. P.; Danevich, F. A.; Degoda, V. Ya.; Kirsanova, S. V.; Kudovbenko, V. M.; Pirro, S.; Tretyak, V. I. (2010-01-21). "First test of Li₂MoO₄ crystal as a cryogenic scintillating bolometer". Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment. 613 (1): 54–57. Bibcode:2010NIMPA.613...54B. doi:10.1016/j.nima.2009.11.059.
^ Kähäri, Hanna; Ramachandran, Prasadh; Juuti, Jari; Jantunen, Heli (2017). "Room-Temperature Densified Li2MoO4 Ceramic Patch Antenna and the Effect of Humidity". International Journal of Applied Ceramic Technology. 14: 50–55. doi:10.1111/ijac.12615. ISSN 1744-7402.
^ Kokkonen, Mikko; Nelo, Mikko; Chen, Jiangcheng; Myllymäki, Sami; Jantunen, Heli (2020). "Low Permittivity Environmentally Friendly Lenses for Ku Band". Progress in Electromagnetics Research Letters. 93: 1–7. doi:10.2528/pierl20060108. S2CID 221461236.

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[1] "Lithium molybdate". pubchem.ncbi.nlm.nih.gov.

[2] Barinova, O. P.; Danevich, F. A.; Degoda, V. Ya.; Kirsanova, S. V.; Kudovbenko, V. M.; Pirro, S.; Tretyak, V. I. (2010-01-21). "First test of Li₂MoO₄ crystal as a cryogenic scintillating bolometer". Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment. 613 (1): 54–57. Bibcode:2010NIMPA.613...54B. doi:10.1016/j.nima.2009.11.059.

[3] Kähäri, Hanna; Ramachandran, Prasadh; Juuti, Jari; Jantunen, Heli (2017). "Room-Temperature Densified Li2MoO4 Ceramic Patch Antenna and the Effect of Humidity". International Journal of Applied Ceramic Technology. 14: 50–55. doi:10.1111/ijac.12615. ISSN 1744-7402.

[4] Kokkonen, Mikko; Nelo, Mikko; Chen, Jiangcheng; Myllymäki, Sami; Jantunen, Heli (2020). "Low Permittivity Environmentally Friendly Lenses for Ku Band". Progress in Electromagnetics Research Letters. 93: 1–7. doi:10.2528/pierl20060108. S2CID 221461236.

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Identifiers
CAS Number	13568-40-6^Y
3D model (JSmol)	Interactive image
ChemSpider	3346702^Y
ECHA InfoCard	100.033.601
EC Number	236-977-7
PubChem CID	6093689
CompTox Dashboard (EPA)	DTXSID80894904
InChI InChI=1S/2Li.Mo.4O/q2+1;;;;2-1^Y Key: NMHMDUCCVHOJQI-UHFFFAOYSA-N^Y InChI=1/2Li.Mo.4O/q2+1;;;;2-1/r2Li.MoO4/c;;2-1(3,4)5/q2*+1;-2 Key: NMHMDUCCVHOJQI-FFXFYZCHAF
SMILES [Li+].[Li+].[O-][Mo]([O-])(=O)=O
Properties
Chemical formula	Li₂MoO₄
Molar mass	173.82 g/mol
Appearance	white odorless powder hygroscopic or transparent crystal
Density	3.07 g/cm³ (pure crystal), 2.66 g/cm³ (hydrated crystal)
Melting point	705 °C (1,301 °F; 978 K)
Solubility in water	very soluble
Hazards
GHS labelling:^[1]
Pictograms
Signal word	Warning
Hazard statements	H315, H319, H335
Precautionary statements	P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)	3 0 1
Related compounds
Other cations	sodium molybdate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is ^YN ?) Infobox references