Marrite (mar'-ite) is a mineral with the chemical formula PbAgAsS3. It is the arsenic equivalent of freieslebenite (PbAgSbS3), but also displays close polyhedral characteristics with sicherite and diaphorite.[6] Marrite was first described in 1905,[7] and was named in honor of geologist John Edward Marr (1857–1933) of Cambridge, England.[5]
| Marrite | |
|---|---|
 The two arrows point to the marrite microcrystals (one or two at each arrow, dull), the rest is galena (bright) | |
| General | |
| Category | Sulfosalt mineral |
| Formula (repeating unit) | PbAgAsS3 |
| IMA symbol | Mrr[1] |
| Strunz classification | 2.JB.15 |
| Crystal system | Monoclinic |
| Crystal class | Prismatic (2/m) (same H-M symbol) |
| Space group | P21/a |
| Unit cell | a = 7.29 Å, b = 12.68 Å, c = 5.99 Å; β = 91.22°; V = 553.57 Å3; Z = 4 |
| Identification | |
| Formula mass | 486.19 g/mol |
| Color | Lead gray, steel gray |
| Crystal habit | Tabular or striated crystals |
| Twinning | Partly bent twin lamellae observable in polished section. |
| Cleavage | None |
| Fracture | Conchoidal |
| Tenacity | Brittle |
| Mohs scale hardness | 3 |
| Luster | Metallic |
| Streak | Black with brownish tint |
| Diaphaneity | Opaque |
| Specific gravity | 5.82 |
| Optical properties | Biaxial |
| Refractive index | Anistrophic |
| Pleochroism | White, with red internal reflections. |
| Other characteristics | Of hydrothermal origin along with other sulfosalts in dolomite. |
| References | [2][3][4][5] |
Crystal habit
editMarrite is part of the monoclinic crystal class, and 2⁄m point group.[4] The symmetry reveals that this mineral is composed of 3 axes of unequal lengths. Two of the axes are perpendicular at 90 degrees, while one axis intersects at an angle less than 90 degrees. Crystal habit includes striated, meaning it forms parallel lines along crystal faces; or tabular, meaning that structure dimensions are thin in 1 direction.[4]
Optical mineralogy
editUnder a microscope, marrite has a distinct anisotropic refractive index, meaning the velocity of light varies depending on the direction being traveled through the mineral. It is typical of anisotropic minerals to display colorful, optical properties when viewed under cross polarized light. This differs from its vague gray color when viewed in plane polarized light, which is the reason optical mineralogy is essential for correctly identifying similar minerals.[3] Marrite belongs to the biaxial optical class, which signifies that it has two optic axes. An optic axis is the direction of light that travels at 0 birefringence, causing the mineral to appear isotropic. When viewing the indicatrix of biaxial minerals, both optic axes are always perpendicular to one of the two circular sections.
Occurrence
editThe only known occurrence of Marrite is the type locality of the Lengenbach quarry in Binntal, Valais, Switzerland. It is primarily formed because of hydrothermal activity, which involves water and high temperatures. Marrite is predominantly found in dolomite along with a variety of other sulfosalts.[5]
References
edit- ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
- ^ Mineralienatlas
- ^ a b "Marrite Mineral Information and Data." http://www.mindat.org/min-2579.html. Retrieved 8 September 2010.
- ^ a b c Anthony, J.W., Bideaux, R.A., Bladh, K.W., and Nichols, M.C. (1990) Marrite. Handbook of Mineralogy. 313 p. Mineral Data Publication. Tucson, Arizona.
- ^ a b c "Marrite Mineral Data." http://webmineral.com/data/Marrite.shtml. Retrieved 8 September 2010.
- ^ Berlepsch, P., Makovicky E., and Armbruster, T. (2002) Structural relationships between sicherite, marrite, freieslebenite, and diaphorite: Analysis based on anionic nets and polyhedral characteristics(178th edition) 75-91 p. E. Schweizerbart'sche Verlagsbuchhandlung. Stuttgart, Germany.
- ^ Solly, RH (1905). "Some new minerals from the Binnenthal, Switzerland" (PDF). Mineralogical Magazine. 14: 72–82. doi:10.1180/minmag.1905.014.64.03.