Monolayer-protected cluster molecules

Monolayer protected clusters (MPCs) are one type of nanoparticles or clusters of atoms. A single MPC contains three main parts: metallic core, protective ligand layer and metal-ligand interface between, each defined by their distinctive chemical and structural environments.^[1] The main part of a MPC is a metallic core, which can consist of a single metal or it can be a mixture of metals. Bare metal particles tend to be reactive. They usually react with environment or with other particles making larger structures. Ligand layer is used to protect them, so that the particle size is preserved. Ligands are usually some organic molecules and they are bound to metallic core via some linking atoms such as sulfur or phosphorus forming thiol and phosphine ligands. However, there are alkynyl and carbene protected MPCs,^[2]^[3] where carbon is directly bound to metal atoms. Ligand layer can consist of a single type of ligands, like in the case of thiolate-protected gold clusters, or it can contain several different molecules. Even though the ligand layer is usually used to passivate a nanoparticle, it is not a passive part of the MPCs. For example, ligands can be functionalized to work in specific applications such as binding to surfaces or acting as a carrier for other molecules. Ligand layer also contributes to the total electronic structure of the particle, which furthermore affects the superatomic nature of the particle.^[1]

In order to fully understand how MPCs work, one has to solve their atomic structures. One of the most common ways is to use X-ray crystallography. There are a large amount of these structures found but they are scattered over different sources. This article is designed to be a list of known structures of MPCs focusing on experimentally determined ones. MPCs are divided to tables according to their cores. Within the tables they are sorted according to the amount of metal atoms from smallest to largest. If there several clusters with similar core sizes, earlier published is listed first. The last table contains some structures which are partially determined experimentally and partially predicted by theoretical calculations. Every table lists the chemical formula of the MPC, the full reference to the publication and a their shortened DOI code with a link to the publication. There are three main ways to access the structure information. The first one is to go to the webpage of the original publication and see if there is supplementary information file containing the data. The second approach is to use the listed DOI and search the structure from the Cambridge Structural Database (CSD)^[4] or Crystallography Open Database (COD).^[5] There one can easily download the structure, if authors have submitted their crystallographic data. Some crystal structures are published in Protein Data Bank (PDB),^[6] in which case corresponding accession code is listed after the DOI. The third option is for the situations, where two first ones don't work and the data is really needed. One can check who is the corresponding author of the publication and ask politely for the data.

Gold

Table of the crystal structures of gold MPCs.
Formula	References
[Au₃C₂₇N₂H₃₆]¹⁺	Robilotto, Thomas J.; Bacsa, John; Gray, Thomas G.; Sadighi, Joseph P. (2012). "Synthesis of a Trigold Monocation: An Isolobal Analogue of [H₃]⁺". Angewandte Chemie International Edition. 51 (48): 12077–12080. doi:10.1002/anie.201206712. PMID 23038641.
{[(^tBu)₃PAu]₄}²⁺	Zeller, Edgar; Beruda, Holger; Schmidbaur, Hubert (1993). "Tetrahedral gold cluster [Au4]2+: Crystal structure of {[(tert-Bu)3PAu]4}2+(BF4-)2.2CHCl3". Inorganic Chemistry. 32 (15): 3203–3204. doi:10.1021/ic00067a002.
[(Au(P(mesityl)₃)₄]²⁺	Yang, Yi; Sharp, Paul R. (1994). "New Gold Clusters [Au8L6](BF4)2 and [(AuL)4](BF4)2 (L = P(mesityl)3)". Journal of the American Chemical Society. 116 (15): 6983–6984. doi:10.1021/ja00094a082.
[Au₆(PPh₃)₆]²⁺	Briant, Clive E.; Hall, Kevin P.; Mingos, D. Michael P.; Wheeler, Allison C. (1986). "Synthesis and structural characterisation of hexakis(triphenyl phosphine)hexagold(2+) nitrate, [Au6(PPh3)6][NO3]2, and related clusters with edgesharing bitetrahedral geometries". Journal of the Chemical Society, Dalton Transactions (3): 687. doi:10.1039/DT9860000687.
[Au₆P(PhCH₃)₃]²⁺	Bellon, Pierluigi; Manassero, Mario; Sansoni, Mirella (1973). "An octahedral gold cluster: Crystal and molecular structure of hexakis[tris-(p-tolyl)phosphine]-octahedro-hexagold bis(tetraphenylborate)". Journal of the Chemical Society, Dalton Transactions (22): 2423. doi:10.1039/DT9730002423.
[Au₆(dppp)₄]²⁺	Van Der Velden, J. W. A.; Bour, J. J.; Steggerda, J. J.; Beurskens, P. T.; Roseboom, M.; Noordik, J. H. (1982). "Gold clusters. Tetrakis[1,3-bis(diphenylphosphino)propane]hexagold dinitrate: Preparation, x-ray analysis, and gold-197 Moessbauer and phosphorus-31{proton} NMR spectra". Inorganic Chemistry. 21 (12): 4321–4324. doi:10.1021/ic00142a041.
[(ImⁱPr₂·Au)₆(μ₆-C)]²⁺	Salorinne, Kirsi; Man, Renee W. Y.; Lummis, Paul A.; Hazer, Maryam Sabooni Asre; Malola, Sami; Yim, Jacky C.-H.; Veinot, Alex J.; Zhou, Wenxia; Häkkinen, Hannu; Nambo, Masakazu; Crudden, Cathleen M. (2020). "Synthesis and properties of an Au₆ cluster supported by a mixed N-heterocyclic carbene–thiolate ligand". Chemical Communications. 56 (45): 6102–6105. doi:10.1039/D0CC01482F. PMID 32355943.
[Au₇(PPh₃)₇]¹⁺	Van Der Velden, J. W. A.; Beurskens, P. T.; Bour, J. J.; Bosman, W. P.; Noordik, J. H.; Kolenbrander, M.; Buskes, J. A. K. M. (1984). "Intermediates in the formation of gold clusters. Preparation and x-ray analysis of [Au7(PPh3)7]+ and synthesis and characterization of [Au8(PPh3)6I]PF6". Inorganic Chemistry. 23 (2): 146–151. doi:10.1021/ic00170a007.
[Au₇(dppp)₄]³⁺	Shichibu, Yukatsu; Zhang, Mingzhe; Kamei, Yutaro; Konishi, Katsuaki (2014). "[Au₇]³⁺: A Missing Link in the Four-Electron Gold Cluster Family". Journal of the American Chemical Society. 136 (37): 12892–12895. doi:10.1021/ja508005x. PMID 25184446.
[Au₈(PPh₃)₈]²⁺	Manassero, Mario; Naldini, Luciana; Sansoni, Mirella (1979). "A new class of gold cluster compounds. Synthesis and X-ray structure of the octakis(triphenylphosphinegold) dializarinsulphonate, [Au8(PPh3)8](aliz)2". Journal of the Chemical Society, Chemical Communications (9): 385. doi:10.1039/C39790000385.
[Au₈(PPh₃)₇]²⁺	Van Der Velden, Jan W. A.; Bour, Jan J.; Bosman, Wil P.; Noordik, Jan H. (1981). "Synthesis and X-ray crystal structure determination of the cationic gold cluster compound [Au8(PPh3)7](NO3)2". Journal of the Chemical Society, Chemical Communications (23): 1218. doi:10.1039/C39810001218.
[Au₈(PPh₃)₇(SnCl₃)]⁺	Demidowicz, Zenon; Johnston, Roy L.; Machell, Jonathan C.; Mingos, D. Michael P.; Williams, Ian D. (1988). "Synthesis and structural characterisation of a novel high-nuclearity gold–tin cluster compound, [Au₈(PPH₃)₇(SNCL₃)]₂[SNCL₆]". J. Chem. Soc., Dalton Trans. (7): 1751–1756. doi:10.1039/DT9880001751.
[Au₈L₆]¹⁺	Yang, Yi; Sharp, Paul R. (1994). "New Gold Clusters [Au8L6](BF4)2 and [(AuL)4](BF4)2 (L = P(mesityl)3)". Journal of the American Chemical Society. 116 (15): 6983–6984. doi:10.1021/ja00094a082.
[Au₈(dppp)₄]²⁺	Kamei, Yutaro; Shichibu, Yukatsu; Konishi, Katsuaki (2011). "Generation of Small Gold Clusters with Unique Geometries through Cluster-to-Cluster Transformations: Octanuclear Clusters with Edge-sharing Gold Tetrahedron Motifs". Angewandte Chemie International Edition. 50 (32): 7442–7445. doi:10.1002/anie.201102901. PMID 21688379.
[Au₈(dppp)₄Cl₂]²⁺	Kamei, Yutaro; Shichibu, Yukatsu; Konishi, Katsuaki (2011). "Generation of Small Gold Clusters with Unique Geometries through Cluster-to-Cluster Transformations: Octanuclear Clusters with Edge-sharing Gold Tetrahedron Motifs". Angewandte Chemie International Edition. 50 (32): 7442–7445. doi:10.1002/anie.201102901. PMID 21688379.
[Au₈(dppp)₄(CCPh)₂]²⁺	Kobayashi, Naoki; Kamei, Yutaro; Shichibu, Yukatsu; Konishi, Katsuaki (2013). "Protonation-Induced Chromism of Pyridylethynyl-Appended [core+ exo ]-Type Au₈ Clusters. Resonance-Coupled Electronic Perturbation through π-Conjugated Group". Journal of the American Chemical Society. 135 (43): 16078–16081. doi:10.1021/ja4099092. PMID 24127776.
[Au₈(dppm)₄S₂]²⁺	Zhang, Shan-Shan; Feng, Lei; Senanayake, Ravithree D.; Aikens, Christine M.; Wang, Xing-Po; Zhao, Quan-Qin; Tung, Chen-Ho; Sun, Di (2018). "Diphosphine-protected ultrasmall gold nanoclusters: Opened icosahedral Au₁₃and heart-shaped Au₈clusters". Chemical Science. 9 (5): 1251–1258. doi:10.1039/C7SC03566G. PMC 5885941. PMID 29675171.
[Au₈(dppp)₄(C₄Ph)₂]²⁺	Iwasaki, Mitsuhiro; Shichibu, Yukatsu; Konishi, Katsuaki (2019). "Unusual Attractive Au–π Interactions in Small Diacetylene-Modified Gold Clusters". Angewandte Chemie International Edition. 58 (8): 2443–2447. doi:10.1002/anie.201814359. PMID 30614159.
[Au₈(dppp)₄(C₂(CH₂)₂CH₃)₂]²⁺	Iwasaki, Mitsuhiro; Shichibu, Yukatsu; Konishi, Katsuaki (2019). "Unusual Attractive Au–π Interactions in Small Diacetylene-Modified Gold Clusters". Angewandte Chemie International Edition. 58 (8): 2443–2447. doi:10.1002/anie.201814359. PMID 30614159.
Au₈(DPPF)₄	Li, Shuo Hao; Liu, Xu; Hu, Weigang; Chen, Mingyang; Zhu, Yan (2020). "An Au₈ Cluster Fortified by Four Ferrocenes". The Journal of Physical Chemistry A. 124 (29): 6061–6067. Bibcode:2020JPCA..124.6061L. doi:10.1021/acs.jpca.0c03366. PMID 32639744.
[Au₉{P(p-C₆H₄Me)₃}₈]³⁺	Bellon, P. L.; Cariati, F.; Manassero, M.; Naldini, L.; Sansoni, M. (1971). "Novel gold clusters. Preparation, properties, and X-ray structure determination of salts of octakis(triarylphosphine)enneagold, [Au9L8]X3". Journal of the Chemical Society D: Chemical Communications (22): 1423. doi:10.1039/C29710001423.
[Au₉{P(p-C₆H₄OMe)₃}₈]³⁺	Hall, Kevin P.; Theoblad, Brain R. C.; Gilmour, David I.; Mingos, D. Michael P.; Welch, Alan J. (1982). "Synthesis and structural characterization of [Au9{P(p-C6H4OMe)3}8](BF4)3; a cluster with a centred crown of gold atoms". Journal of the Chemical Society, Chemical Communications (10): 528. doi:10.1039/C39820000528.
[Au₉{P(p-C₆H₄OMe)₃}₈]³⁺	Briant, Clive E.; Hall, Kevin P.; Mingos, D. Michael P. (1984). "Structural characterisation of two crystalline modifications of [Au9{P(C6H4OMe-p)3}8](NO3)3: The first example of skeletal isomerism in metal cluster chemistry". Journal of the Chemical Society, Chemical Communications (5): 290. doi:10.1039/C39840000290.
[Au₉(PPh₃)₈]³⁺	Schulz-Dobrick, Martin; Jansen, Martin (2006). "Supramolecular Intercluster Compounds Consisting of Gold Clusters and Keggin Anions". European Journal of Inorganic Chemistry. 2006 (22): 4498–4502. doi:10.1002/ejic.200600790.
[Au₉(PPh₃)₈]³⁺	Schulz-Dobrick, Martin; Jansen, Martin (2007). "Structure-Directing Effects in the Supramolecular Intercluster Compound [Au₉(PPH₃)₈]₂[V₁₀O₂₈H₃]₂: Long-Range versus Short-Range Bonding Interactions". Inorganic Chemistry. 46 (11): 4380–4382. doi:10.1021/ic700434x. PMID 17477525.
[Au₉(PPh₃)₈]³⁺	Wen, Fei; Englert, Ulli; Gutrath, Benjamin; Simon, Ulrich (2008). "Crystal Structure, Electrochemical and Optical Properties of [Au₉(PPH₃)₈](NO₃)₃". European Journal of Inorganic Chemistry. 2008: 106–111. doi:10.1002/ejic.200700534.
[Au₁₀Cl₃(PCy₂Ph)₆]⁺	Briant, Clive E.; Hall, Kevin P.; Wheeler, Alison C.; Mingos, D. Michael P. (1984). "Structural characterisation of [Au10Cl3(PCy2Ph)6](NO3)(Cy = cyclohexyl) and the development of a structural principle for high nuclearity gold clusters". Journal of the Chemical Society, Chemical Communications (4): 248. doi:10.1039/C39840000248.
[Au₁₀(μ-cis-dppee)₄(μ₃-S)₄]²⁺	Yao, Liao-Yuan; Yam, Vivian Wing-Wah (2015). "Photoinduced Isomerization-Driven Structural Transformation Between Decanuclear and Octadecanuclear Gold(I) Sulfido Clusters". Journal of the American Chemical Society. 137 (10): 3506–3509. doi:10.1021/jacs.5b01676. PMID 25741572.
[Au₁₀(bisNHC)₄Br₂]²⁺	Man, Renee W. Y.; Yi, Hong; Malola, Sami; Takano, Shinjiro; Tsukuda, Tatsuya; Häkkinen, Hannu; Nambo, Masakazu; Crudden, Cathleen M. (2022). "Synthesis and Characterization of Enantiopure Chiral Bis NHC-Stabilized Edge-Shared Au₁₀ Nanocluster with Unique Prolate Shape". Journal of the American Chemical Society. 144 (5): 2056–2061. doi:10.1021/jacs.1c11857. PMID 35100506.
[Au₁₀(^MesCH2Bimy)₆Br₃]⁺	Lummis, Paul A.; Osten, Kimberly M.; Levchenko, Tetyana I.; Sabooni Asre Hazer, Maryam; Malola, Sami; Owens-Baird, Bryan; Veinot, Alex J.; Albright, Emily L.; Schatte, Gabriele; Takano, Shinjiro; Kovnir, Kirill; Stamplecoskie, Kevin G.; Tsukuda, Tatsuya; Häkkinen, Hannu; Nambo, Masakazu; Crudden, Cathleen M. (2022). "NHC-Stabilized Au₁₀ Nanoclusters and Their Conversion to Au₂₅ Nanoclusters". Jacs Au. 2 (4): 875–885. doi:10.1021/jacsau.2c00004. PMC 9088291. PMID 35557749.
Au₁₁(S-4-NC₅-H₄)₃(PPh₃)₇	Nunokawa, Keiko; Onaka, Satoru; Ito, Mitsuhiro; Horibe, Makoto; Yonezawa, Tetsu; Nishihara, Hiroshi; Ozeki, Tomoji; Chiba, Hirokazu; Watase, Seiji; Nakamoto, Masami (2006). "Synthesis, single crystal X-ray analysis, and TEM for a single-sized Au11 cluster stabilized by SR ligands: The interface between molecules and particles". Journal of Organometallic Chemistry. 691 (4): 638–642. doi:10.1016/j.jorganchem.2005.09.043.
[Au₁₁(Ph₂P(CH₂)₂PPh₂)₆]³⁺	Shichibu, Yukatsu; Kamei, Yutaro; Konishi, Katsuaki (2012). "Unique [core+two] structure and optical property of a dodeca-ligated undecagold cluster: Critical contribution of the exo gold atoms to the electronic structure". Chemical Communications. 48 (61): 7559–7561. doi:10.1039/C2CC30251A. hdl:2115/52107. PMID 22430877.
Au₁₁(PPh₃)₇Cl₃	McKenzie, Lallie C.; Zaikova, Tatiana O.; Hutchison, James E. (2014). "Structurally Similar Triphenylphosphine-Stabilized Undecagolds, Au₁₁(PPH₃)₇Cl₃ and [Au₁₁(PPH₃)₈Cl₂]Cl, Exhibit Distinct Ligand Exchange Pathways with Glutathione". Journal of the American Chemical Society. 136 (38): 13426–13435. doi:10.1021/ja5075689. PMC 4183609. PMID 25171178.
[Au₁₁(PPh₃)₈Cl₂]⁺	McKenzie, Lallie C.; Zaikova, Tatiana O.; Hutchison, James E. (2014). "Structurally Similar Triphenylphosphine-Stabilized Undecagolds, Au₁₁(PPH₃)₇Cl₃ and [Au₁₁(PPH₃)₈Cl₂]Cl, Exhibit Distinct Ligand Exchange Pathways with Glutathione". Journal of the American Chemical Society. 136 (38): 13426–13435. doi:10.1021/ja5075689. PMC 4183609. PMID 25171178.
[Au₁₁(PPh₃)₇(NHC^i-Pr)Cl₂]⁺	Narouz, Mina R.; Osten, Kimberly M.; Unsworth, Phillip J.; Man, Renee W. Y.; Salorinne, Kirsi; Takano, Shinjiro; Tomihara, Ryohei; Kaappa, Sami; Malola, Sami; Dinh, Cao-Thang; Padmos, J. Daniel; Ayoo, Kennedy; Garrett, Patrick J.; Nambo, Masakazu; Horton, J. Hugh; Sargent, Edward H.; Häkkinen, Hannu; Tsukuda, Tatsuya; Crudden, Cathleen M. (2019). "N-heterocyclic carbene-functionalized magic-number gold nanoclusters". Nature Chemistry. 11 (5): 419–425. Bibcode:2019NatCh..11..419N. doi:10.1038/s41557-019-0246-5. PMID 30988416.
[Au₁₂(PPh₂)₂S₄(L2)₄]²⁺	Yu, Wen; Wang, Yingxia; Fuhr, Olaf; Fenske, Dieter; Dehnen, Stefanie (2018). "[Au₁₂(PPH₂)₂S₄(L2)₄]²⁺ (L2 = 3,4-bis(diphenylphosphino)-2,5-bis(trimethylsilyloxy)furan): An Au₁₂ unit protected by modified maleic anhydride phosphine ligands". Dalton Transactions. 47 (4): 1032–1035. doi:10.1039/C7DT04263A. PMID 29292447.
[Au₁₃(PMe₂Ph)₁₀Cl₂]³⁺	Briant, Clive E.; Theobald, Brian R. C.; White, James W.; Bell, Linda K.; Mingos, D. Michael P.; Welch, Alan J. (1981). "Synthesis and X-ray structural characterization of the centred icosahedral gold cluster compound [Aul3(PMe2Ph)10Cl2](PF6)3; the realization of a theoretical prediction". Journal of the Chemical Society, Chemical Communications (5): 201. doi:10.1039/C39810000201.
[Au₁₃(dppe)₅Cl₂]³⁺	Shichibu, Yukatsu; Konishi, Katsuaki (2010). "HCL-Induced Nuclearity Convergence in Diphosphine-Protected Ultrasmall Gold Clusters: A Novel Synthetic Route to "Magic-Number" Au₁₃ Clusters". Small. 6 (11): 1216–1220. doi:10.1002/smll.200902398. PMID 20486140.
[Au₁₃(dppe)₅(CCPh)₂]³⁺	Sugiuchi, Mizuho; Shichibu, Yukatsu; Nakanishi, Takayuki; Hasegawa, Yasuchika; Konishi, Katsuaki (2015). "Cluster–π electronic interaction in a superatomic Au₁₃ cluster bearing σ-bonded acetylide ligands". Chemical Communications. 51 (70): 13519–13522. doi:10.1039/C5CC04312C. hdl:2115/62372. PMID 26215256.
[Au₁₃(dppm)₆]⁵⁺	Zhang, Shan-Shan; Feng, Lei; Senanayake, Ravithree D.; Aikens, Christine M.; Wang, Xing-Po; Zhao, Quan-Qin; Tung, Chen-Ho; Sun, Di (2018). "Diphosphine-protected ultrasmall gold nanoclusters: Opened icosahedral Au₁₃and heart-shaped Au₈clusters". Chemical Science. 9 (5): 1251–1258. doi:10.1039/C7SC03566G. PMC 5885941. PMID 29675171.
[Au₁₃(NHC^Bn)₉Cl₃]²⁺	Narouz, Mina R.; Takano, Shinjiro; Lummis, Paul A.; Levchenko, Tetyana I.; Nazemi, Ali; Kaappa, Sami; Malola, Sami; Yousefalizadeh, Goonay; Calhoun, Larry A.; Stamplecoskie, Kevin G.; Häkkinen, Hannu; Tsukuda, Tatsuya; Crudden, Cathleen M. (2019). "Robust, Highly Luminescent Au₁₃ Superatoms Protected by N-Heterocyclic Carbenes". Journal of the American Chemical Society. 141 (38): 14997–15002. doi:10.1021/jacs.9b07854. PMID 31497943.
[Au₁₃(NHC-1)₆Br₆]^-	Shen, Hui; Xiang, Sijin; Xu, Zhen; Liu, Chen; Li, Xihua; Sun, Cunfa; Lin, Shuichao; Teo, Boon K.; Zheng, Nanfeng (2020). "Superatomic Au13 clusters ligated by different N-heterocyclic carbenes and their ligand-dependent catalysis, photoluminescence, and proton sensitivity". Nano Research. 13 (7): 1908–1911. doi:10.1007/s12274-020-2685-0.
[Au₁₃(NHC-2)₅Br₂]³⁺	Shen, Hui; Xiang, Sijin; Xu, Zhen; Liu, Chen; Li, Xihua; Sun, Cunfa; Lin, Shuichao; Teo, Boon K.; Zheng, Nanfeng (2020). "Superatomic Au13 clusters ligated by different N-heterocyclic carbenes and their ligand-dependent catalysis, photoluminescence, and proton sensitivity". Nano Research. 13 (7): 1908–1911. doi:10.1007/s12274-020-2685-0.
[Au₁₃(NHC-3)₉Cl₃]²⁺	Shen, Hui; Xiang, Sijin; Xu, Zhen; Liu, Chen; Li, Xihua; Sun, Cunfa; Lin, Shuichao; Teo, Boon K.; Zheng, Nanfeng (2020). "Superatomic Au13 clusters ligated by different N-heterocyclic carbenes and their ligand-dependent catalysis, photoluminescence, and proton sensitivity". Nano Research. 13 (7): 1908–1911. doi:10.1007/s12274-020-2685-0.
[Au₁₃(NHC-4)₈(ArC≡C)₄]⁺	Shen, Hui; Wu, Qingyuan; Malola, Sami; Han, Ying-Zi; Xu, Zhen; Qin, Ruixuan; Tang, Xiongkai; Chen, Yang-Bo; Teo, Boon K.; Häkkinen, Hannu; Zheng, Nanfeng (2022). "N-Heterocyclic Carbene-Stabilized Gold Nanoclusters with Organometallic Motifs for Promoting Catalysis". Journal of the American Chemical Society. 144 (24): 10844–10853. doi:10.1021/jacs.2c02669. PMID 35671335.
Au₁₄(PPh₃)₈(NO₃)₄	Gutrath, Benjamin S.; Oppel, Iris M.; Presly, Oliver; Beljakov, Igor; Meded, Velimir; Wenzel, Wolfgang; Simon, Ulrich (2013). "[Au₁₄(PPH₃)₈(NO₃)₄]: An Example of a New Class of Au(NO₃)-Ligated Superatom Complexes". Angewandte Chemie International Edition. 52 (12): 3529–3532. doi:10.1002/anie.201208681. PMID 23420716.
[Au₁₆(NHC-1)₅(PA)₃Br₂]³⁺	Shen, Hui; Wu, Qingyuan; Malola, Sami; Han, Ying-Zi; Xu, Zhen; Qin, Ruixuan; Tang, Xiongkai; Chen, Yang-Bo; Teo, Boon K.; Häkkinen, Hannu; Zheng, Nanfeng (2022). "N-Heterocyclic Carbene-Stabilized Gold Nanoclusters with Organometallic Motifs for Promoting Catalysis". Journal of the American Chemical Society. 144 (24): 10844–10853. doi:10.1021/jacs.2c02669. PMID 35671335.
[Au₁₆(NHC-1)₅(PA)₂(4-MePhC≡C)Br₂]³⁺	Shen, Hui; Wu, Qingyuan; Malola, Sami; Han, Ying-Zi; Xu, Zhen; Qin, Ruixuan; Tang, Xiongkai; Chen, Yang-Bo; Teo, Boon K.; Häkkinen, Hannu; Zheng, Nanfeng (2022). "N-Heterocyclic Carbene-Stabilized Gold Nanoclusters with Organometallic Motifs for Promoting Catalysis". Journal of the American Chemical Society. 144 (24): 10844–10853. doi:10.1021/jacs.2c02669. PMID 35671335.
[Au₁₇(NHC-1)₄(PA)₄Br₄]⁺	Shen, Hui; Wu, Qingyuan; Malola, Sami; Han, Ying-Zi; Xu, Zhen; Qin, Ruixuan; Tang, Xiongkai; Chen, Yang-Bo; Teo, Boon K.; Häkkinen, Hannu; Zheng, Nanfeng (2022). "N-Heterocyclic Carbene-Stabilized Gold Nanoclusters with Organometallic Motifs for Promoting Catalysis". Journal of the American Chemical Society. 144 (24): 10844–10853. doi:10.1021/jacs.2c02669. PMID 35671335.
[Au₁₈(μ-trans-dppee)₆(μ₃-S)₈]²⁺	Yao, Liao-Yuan; Yam, Vivian Wing-Wah (2015). "Photoinduced Isomerization-Driven Structural Transformation Between Decanuclear and Octadecanuclear Gold(I) Sulfido Clusters". Journal of the American Chemical Society. 137 (10): 3506–3509. doi:10.1021/jacs.5b01676. PMID 25741572.
Au₁₈(SC₆H₁₁)₁₄	Das, Anindita; Liu, Chong; Byun, Hee Young; Nobusada, Katsuyuki; Zhao, Shuo; Rosi, Nathaniel; Jin, Rongchao (2015). "Structure Determination of [Au₁₈(SR)₁₄]". Angewandte Chemie International Edition. 54 (10): 3140–3144. doi:10.1002/anie.201410161. PMID 25619892.
Au₁₈(SC₆H₁₁)₁₄	Chen, Shuang; Wang, Shuxin; Zhong, Juan; Song, Yongbo; Zhang, Jun; Sheng, Hongting; Pei, Yong; Zhu, Manzhou (2015). "The Structure and Optical Properties of the [Au₁₈(SR)₁₄] Nanocluster". Angewandte Chemie International Edition. 54 (10): 3145–3149. doi:10.1002/anie.201410295. PMID 25620108.
[Au₁₈S₈(dppe)₆]²⁺	Keter, Frankline K.; Guzei, Ilia A.; Nell, Margo; Zyl, Werner E. van; Darkwa, James (2014). "Phosphinogold(I) Dithiocarbamate Complexes: Effect of the Nature of Phosphine Ligand on Anticancer Properties". Inorganic Chemistry. 53 (4): 2058–2067. doi:10.1021/ic4025926. PMC 3993921. PMID 24476103.
[Au₁₈(dppm)₆Cl₄]⁴⁺	Zhang, Shan-Shan; Senanayake, Ravithree D.; Zhao, Quan-Qin; Su, Hai-Feng; Aikens, Christine M.; Wang, Xing-Po; Tung, Chen-Ho; Sun, Di; Zheng, Lan-Sun (2019). "[Au₁₈(DPPM)₆Cl₄]⁴⁺: A phosphine-protected gold nanocluster with rich charge states". Dalton Transactions. 48 (11): 3635–3640. doi:10.1039/C9DT00042A. PMID 30747941.
[Au₁₉(CCPh)₉(Hdppa)₃]²⁺	Wan, Xian-Kai; Tang, Qing; Yuan, Shang-Fu; Jiang, De-en; Wang, Quan-Ming (2015). "Au₁₉ Nanocluster Featuring a V-Shaped Alkynyl–Gold Motif". Journal of the American Chemical Society. 137 (2): 652–655. doi:10.1021/ja512133a. PMID 25545109.
[Au₂₀(PPhpy₂)₁₀Cl₄]²⁺	Wan, Xian-Kai; Lin, Zhi-Wei; Wang, Quan-Ming (2012). "Au₂₀ Nanocluster Protected by Hemilabile Phosphines". Journal of the American Chemical Society. 134 (36): 14750–14752. doi:10.1021/ja307256b. PMID 22931402.
Au₂₀(TBBT)₁₆	Zeng, Chenjie; Liu, Chong; Chen, Yuxiang; Rosi, Nathaniel L.; Jin, Rongchao (2014). "Gold–Thiolate Ring as a Protecting Motif in the Au₂₀(SR)₁₆ Nanocluster and Implications". Journal of the American Chemical Society. 136 (34): 11922–11925. doi:10.1021/ja506802n. PMID 25126666.
[Au₂₀(PP₃)₄]⁴⁺	Chen, Jing; Zhang, Qian-Fan; Williard, Paul G.; Wang, Lai-Sheng (2014). "Synthesis and Structure Determination of a New Au₂₀ Nanocluster Protected by Tripodal Tetraphosphine Ligands". Inorganic Chemistry. 53 (8): 3932–3934. doi:10.1021/ic500562r. PMID 24684605.
Au₂₁(S-tBu)₁₅	Yang, Sha; Chai, Jinsong; Song, Yongbo; Fan, Jiqiang; Chen, Tao; Wang, Shuxin; Yu, Haizhu; Li, Xiaowu; Zhu, Manzhou (2017). "In Situ Two-Phase Ligand Exchange: A New Method for the Synthesis of Alloy Nanoclusters with Precise Atomic Structures". Journal of the American Chemical Society. 139 (16): 5668–5671. doi:10.1021/jacs.7b00668. PMID 28383901.
Au₂₁(S-Adm)₁₅	Chen, Shuang; Xiong, Lin; Wang, Shuxin; Ma, Zhongyun; Jin, Shan; Sheng, Hongting; Pei, Yong; Zhu, Manzhou (2016). "Total Structure Determination of Au₂₁(S-Adm)₁₅ and Geometrical/Electronic Structure Evolution of Thiolated Gold Nanoclusters". Journal of the American Chemical Society. 138 (34): 10754–10757. doi:10.1021/jacs.6b06004. PMID 27552520.
Au₂₂(L⁸)₆	Chen, Jing; Zhang, Qian-Fan; Bonaccorso, Timary A.; Williard, Paul G.; Wang, Lai-Sheng (2014). "Controlling Gold Nanoclusters by Diphospine Ligands". Journal of the American Chemical Society. 136 (1): 92–95. doi:10.1021/ja411061e. PMID 24351099.
Au₂₂(SAdm)₁₆	Li, Yingwei; Cowan, Michael J.; Zhou, Meng; Luo, Tian-Yi; Song, Yongbo; Wang, He; Rosi, Nathaniel L.; Mpourmpakis, Giannis; Jin, Rongchao (2020). "Atom-by-Atom Evolution of the Same Ligand-Protected Au₂₁, Au₂₂, Au₂₂Cd₁, and Au₂₄ Nanocluster Series". Journal of the American Chemical Society. 142 (48): 20426–20433. doi:10.1021/jacs.0c09110. PMID 33170677.
[Au₂₃(SC₆H₁₁)₁₆]^-	Das, Anindita; Li, Tao; Nobusada, Katsuyuki; Zeng, Chenjie; Rosi, Nathaniel L.; Jin, Rongchao (2013). "Nonsuperatomic [Au₂₃(SC₆H₁₁)₁₆]⁻ Nanocluster Featuring Bipyramidal Au₁₅ Kernel and Trimeric Au₃(SR)₄ Motif". Journal of the American Chemical Society. 135 (49): 18264–18267. doi:10.1021/ja409177s. PMID 24274138.
[Au₂₃(CCPh)₉(PPh₃)₆]²⁺	Wan, Xian-Kai; Yuan, Shang-Fu; Tang, Qing; Jiang, De-en; Wang, Quan-Ming (2015). "Alkynyl-Protected Au₂₃ Nanocluster: A 12-Electron System". Angewandte Chemie International Edition. 54 (20): 5977–5980. doi:10.1002/anie.201500590. PMID 25808199.
Au₂₃(CCBu)₁₅	Guan, Zong-Jie; Hu, Feng; Li, Jiao-Jiao; Wen, Zhao-Rui; Lin, Yu-Mei; Wang, Quan-Ming (2020). "Isomerization in Alkynyl-Protected Gold Nanoclusters". Journal of the American Chemical Society. 142 (6): 2995–3001. doi:10.1021/jacs.9b11836. PMID 31958012.
[Au₂₃(NHC^ptol)₆(C≡CPh)₉]²⁺	Hirano, Koto; Takano, Shinjiro; Tsukuda, Tatsuya (2021). "Ligand Effects on the Structures of [Au₂₃L₆(C≡CPH)₉]²⁺ (L = N-Heterocyclic Carbene vs Phosphine) with Au₁₇ Superatomic Cores". The Journal of Physical Chemistry C. 125 (18): 9930–9936. doi:10.1021/acs.jpcc.1c02197.
[Au₂₄(CCPh)₁₄(PPh₃)₄]²⁺	Wan, Xian-Kai; Xu, Wen Wu; Yuan, Shang-Fu; Gao, Yi; Zeng, Xiao-Cheng; Wang, Quan-Ming (2015). "A Near-Infrared-Emissive Alkynyl-Protected Au₂₄ Nanocluster". Angewandte Chemie International Edition. 54 (33): 9683–9686. doi:10.1002/anie.201503893. PMID 26119538.
Au₂₄(SAdm)₁₆	Crasto, David; Barcaro, Giovanni; Stener, Mauro; Sementa, Luca; Fortunelli, Alessandro; Dass, Amala (2014). "Au₂₄(SAdm)₁₆ Nanomolecules: X-ray Crystal Structure, Theoretical Analysis, Adaptability of Adamantane Ligands to Form Au₂₃(SAdm)₁₆ and Au₂₅(SAdm)₁₆, and Its Relation to Au₂₅(SR)₁₈". Journal of the American Chemical Society. 136 (42): 14933–14940. doi:10.1021/ja507738e. PMID 25308728.
Au₂₄(SCH₂Ph-tBu)₂₀	Das, Anindita; Li, Tao; Li, Gao; Nobusada, Katsuyuki; Zeng, Chenjie; Rosi, Nathaniel L.; Jin, Rongchao (2014). "Crystal structure and electronic properties of a thiolate-protected Au24 nanocluster". Nanoscale. 6 (12): 6458–6462. doi:10.1039/C4NR01350F. PMID 24817094.
[Au₂₄L₆Cl₄]²⁺	Sugiuchi, Mizuho; Shichibu, Yukatsu; Konishi, Katsuaki (2018). "An Inherently Chiral Au₂₄ Framework with Double-Helical Hexagold Strands". Angewandte Chemie International Edition. 57 (26): 7855–7859. doi:10.1002/anie.201804087. PMID 29719106.
[Au₂₄(PPh₃)₁₀(SC₂H₄Ph)₅Cl₂]⁺	Das, Anindita; Li, Tao; Nobusada, Katsuyuki; Zeng, Qiong; Rosi, Nathaniel L.; Jin, Rongchao (2012). "Total Structure and Optical Properties of a Phosphine/Thiolate-Protected Au₂₄ Nanocluster". Journal of the American Chemical Society. 134 (50): 20286–20289. doi:10.1021/ja3101566. PMID 23227995.
[Au₂₄(NHC)₁₄Cl₂H₃]³⁺	Kulkarni, Viveka K.; Khiarak, Behnam Nourmohammadi; Takano, Shinjiro; Malola, Sami; Albright, Emily L.; Levchenko, Tetyana I.; Aloisio, Mark D.; Dinh, Cao-Thang; Tsukuda, Tatsuya; Häkkinen, Hannu; Crudden, Cathleen M. (2022). "N-Heterocyclic Carbene-Stabilized Hydrido Au₂₄ Nanoclusters: Synthesis, Structure, and Electrocatalytic Reduction of CO₂". Journal of the American Chemical Society. 144 (20): 9000–9006. doi:10.1021/jacs.2c00789. PMID 35549258.
[Au₂₅(PPh₃)₁₀(SEt)₅Cl₂]²⁺	Shichibu, Yukatsu; Konishi, Katsuaki (2010). "HCL-Induced Nuclearity Convergence in Diphosphine-Protected Ultrasmall Gold Clusters: A Novel Synthetic Route to "Magic-Number" Au₁₃ Clusters". Small. 6 (11): 1216–1220. doi:10.1002/smll.200902398. PMID 20486140.
[Au₂₅(SC₂H₄Ph)₁₈]^1-	Zhu, Manzhou; Aikens, Christine M.; Hollander, Frederick J.; Schatz, George C.; Jin, Rongchao (2008). "Correlating the Crystal Structure of a Thiol-Protected Au₂₅ Cluster and Optical Properties". Journal of the American Chemical Society. 130 (18): 5883–5885. doi:10.1021/ja801173r. PMID 18407639.
[Au₂₅(SC₂H₄Ph)₁₈]^1-	Heaven, Michael W.; Dass, Amala; White, Peter S.; Holt, Kennedy M.; Murray, Royce W. (2008). "Crystal Structure of the Gold Nanoparticle [N(C₈H₁₇)₄][Au₂₅(SCH₂CH₂Ph)₁₈]". Journal of the American Chemical Society. 130 (12): 3754–3755. doi:10.1021/ja800561b. PMID 18321116.
[Au₂₅(SC₂H₄Ph)₁₈]^1-	Zhu, Manzhou; Eckenhoff, William T.; Pintauer, Tomislav; Jin, Rongchao (2008). "Conversion of Anionic [Au₂₅(SCH₂CH₂Ph)₁₈]⁻ Cluster to Charge Neutral Cluster via Air Oxidation". The Journal of Physical Chemistry C. 112 (37): 14221–14224. doi:10.1021/jp805786p.
Au₂₅(SC₂H₄Ph)₁₈	Zhu, Manzhou; Eckenhoff, William T.; Pintauer, Tomislav; Jin, Rongchao (2008). "Conversion of Anionic [Au₂₅(SCH₂CH₂Ph)₁₈]⁻ Cluster to Charge Neutral Cluster via Air Oxidation". The Journal of Physical Chemistry C. 112 (37): 14221–14224. doi:10.1021/jp805786p.
Au₂₅(SC₂H₄Ph)₁₈	Antonello, Sabrina; Dainese, Tiziano; Pan, Fangfang; Rissanen, Kari; Maran, Flavio (2017). "Electrocrystallization of Monolayer-Protected Gold Clusters: Opening the Door to Quality, Quantity, and New Structures". Journal of the American Chemical Society. 139 (11): 4168–4174. doi:10.1021/jacs.7b00568. hdl:11577/3230060. PMID 28281762.
[Au₂₅(S-nC₅H₁₁)₁₈]₄	Antonello, Sabrina; Dainese, Tiziano; Pan, Fangfang; Rissanen, Kari; Maran, Flavio (2017). "Electrocrystallization of Monolayer-Protected Gold Clusters: Opening the Door to Quality, Quantity, and New Structures". Journal of the American Chemical Society. 139 (11): 4168–4174. doi:10.1021/jacs.7b00568. hdl:11577/3230060. PMID 28281762.
Au₂₅(SC₂H₄Ph)₁₈	Tofanelli, Marcus A.; Salorinne, Kirsi; Ni, Thomas W.; Malola, Sami; Newell, Brian; Phillips, Billy; Häkkinen, Hannu; Ackerson, Christopher J. (2016). "Jahn–Teller effects in Au₂₅(SR)₁₈". Chemical Science. 7 (3): 1882–1890. doi:10.1039/C5SC02134K. PMC 5965251. PMID 29899911.
[Au₂₅(SC₂H₄Ph)₁₈]¹⁺	Tofanelli, Marcus A.; Salorinne, Kirsi; Ni, Thomas W.; Malola, Sami; Newell, Brian; Phillips, Billy; Häkkinen, Hannu; Ackerson, Christopher J. (2016). "Jahn–Teller effects in Au₂₅(SR)₁₈". Chemical Science. 7 (3): 1882–1890. doi:10.1039/C5SC02134K. PMC 5965251. PMID 29899911.
Au₂₅(SEt)₁₈	Dainese, Tiziano; Antonello, Sabrina; Gascón, José A.; Pan, Fangfang; Perera, Neranjan V.; Ruzzi, Marco; Venzo, Alfonso; Zoleo, Alfonso; Rissanen, Kari; Maran, Flavio (2014). "Au₂₅(SEt)₁₈, a Nearly Naked Thiolate-Protected Au₂₅ Cluster: Structural Analysis by Single Crystal X-ray Crystallography and Electron Nuclear Double Resonance". ACS Nano. 8 (4): 3904–3912. doi:10.1021/nn500805n. PMID 24628268.
Au₂₅(SPr)₁₈	Agrachev, Mikhail; Antonello, Sabrina; Dainese, Tiziano; Gascón, José A.; Pan, Fangfang; Rissanen, Kari; Ruzzi, Marco; Venzo, Alfonso; Zoleo, Alfonso; Maran, Flavio (2016). "A magnetic look into the protecting layer of Au₂₅ clusters". Chemical Science. 7 (12): 6910–6918. doi:10.1039/C6SC03691K. PMC 5450596. PMID 28567262.
[Au₂₅(SBu)₁₈]₂	De Nardi, Marco; Antonello, Sabrina; Jiang, De-en; Pan, Fangfang; Rissanen, Kari; Ruzzi, Marco; Venzo, Alfonso; Zoleo, Alfonso; Maran, Flavio (2014). "Gold Nanowired: A Linear (Au₂₅)_n Polymer from Au₂₅ Molecular Clusters". ACS Nano. 8 (8): 8505–8512. doi:10.1021/nn5031143. PMID 25088331.
[Au₂₅(PPh₃)₁₀(SePh)₅Cl₂]¹⁺	Song, Yongbo; Jin, Shan; Kang, Xi; Xiang, Ji; Deng, Huijuan; Yu, Haizhu; Zhu, Manzhou (2016). "How a Single Electron Affects the Properties of the "Non-Superatom" Au₂₅ Nanoclusters". Chemistry of Materials. 28 (8): 2609–2617. doi:10.1021/acs.chemmater.5b04655.
[Au₂₅(PPh₃)₁₀(SePh)₅Cl₂]²⁺	Song, Yongbo; Jin, Shan; Kang, Xi; Xiang, Ji; Deng, Huijuan; Yu, Haizhu; Zhu, Manzhou (2016). "How a Single Electron Affects the Properties of the "Non-Superatom" Au₂₅ Nanoclusters". Chemistry of Materials. 28 (8): 2609–2617. doi:10.1021/acs.chemmater.5b04655.
[Au₂₅(PPh₃)₁₀(SC₂H₅)₅Cl₂]²⁺	Shichibu, Yukatsu; Negishi, Yuichi; Watanabe, Takahito; Chaki, Nirmalya K.; Kawaguchi, Hiroyuki; Tsukuda, Tatsuya (2007). "Biicosahedral Gold Clusters [Au₂₅(PPH₃)₁₀(SC _n H₂ _n ₊₁)₅Cl₂]²⁺ ( n = 2−18): A Stepping Stone to Cluster-Assembled Materials". The Journal of Physical Chemistry C. 111 (22): 7845–7847. doi:10.1021/jp073101t.
[Au₂₅(ⁱPr₂-bimy)₁₀Br₇]²⁺	Shen, Hui; Deng, Guocheng; Kaappa, Sami; Tan, Tongde; Han, Ying-Zi; Malola, Sami; Lin, Shui-Chao; Teo, Boon K.; Häkkinen, Hannu; Zheng, Nanfeng (2019). "Highly Robust but Surface-Active: An N-Heterocyclic Carbene-Stabilized Au₂₅ Nanocluster". Angewandte Chemie International Edition. 58 (49): 17731–17735. doi:10.1002/anie.201908983. PMID 31517436.
[Au₂₅(^MesCH2Bimy)₁₀Br₇]²⁺	Lummis, Paul A.; Osten, Kimberly M.; Levchenko, Tetyana I.; Sabooni Asre Hazer, Maryam; Malola, Sami; Owens-Baird, Bryan; Veinot, Alex J.; Albright, Emily L.; Schatte, Gabriele; Takano, Shinjiro; Kovnir, Kirill; Stamplecoskie, Kevin G.; Tsukuda, Tatsuya; Häkkinen, Hannu; Nambo, Masakazu; Crudden, Cathleen M. (2022). "NHC-Stabilized Au₁₀ Nanoclusters and Their Conversion to Au₂₅ Nanoclusters". Jacs Au. 2 (4): 875–885. doi:10.1021/jacsau.2c00004. PMC 9088291. PMID 35557749.
[Au₂₅(^MesCH2Bimy)₁₀Br₈]⁺	Lummis, Paul A.; Osten, Kimberly M.; Levchenko, Tetyana I.; Sabooni Asre Hazer, Maryam; Malola, Sami; Owens-Baird, Bryan; Veinot, Alex J.; Albright, Emily L.; Schatte, Gabriele; Takano, Shinjiro; Kovnir, Kirill; Stamplecoskie, Kevin G.; Tsukuda, Tatsuya; Häkkinen, Hannu; Nambo, Masakazu; Crudden, Cathleen M. (2022). "NHC-Stabilized Au₁₀ Nanoclusters and Their Conversion to Au₂₅ Nanoclusters". Jacs Au. 2 (4): 875–885. doi:10.1021/jacsau.2c00004. PMC 9088291. PMID 35557749.
Au₂₈(TBBT)₂₀	Zeng, Chenjie; Li, Tao; Das, Anindita; Rosi, Nathaniel L.; Jin, Rongchao (2013). "Chiral Structure of Thiolate-Protected 28-Gold-Atom Nanocluster Determined by X-ray Crystallography". Journal of the American Chemical Society. 135 (27): 10011–10013. doi:10.1021/ja404058q. PMID 23815445.
Au₂₈(S-c-C₆H₁₁)₂₀	Chen, Yuxiang; Liu, Chong; Tang, Qing; Zeng, Chenjie; Higaki, Tatsuya; Das, Anindita; Jiang, De-en; Rosi, Nathaniel L.; Jin, Rongchao (2016). "Isomerism in Au₂₈(SR)₂₀ Nanocluster and Stable Structures". Journal of the American Chemical Society. 138 (5): 1482–1485. doi:10.1021/jacs.5b12094. PMID 26817394.
Au₂₈(S-c-C₆H₁₁)₂₀	Higaki, Tatsuya; Liu, Chong; Chen, Yuxiang; Zhao, Shuo; Zeng, Chenjie; Jin, Renxi; Wang, Shuxin; Rosi, Nathaniel L.; Jin, Rongchao (2017). "Oxidation-Induced Transformation of Eight-Electron Gold Nanoclusters: [Au₂₃(SR)₁₆]⁻ to [Au₂₈(SR)₂₀]⁰". The Journal of Physical Chemistry Letters. 8 (4): 866–870. doi:10.1021/acs.jpclett.6b03061. PMID 28145114.
Au₂₉(S-Adm)₁₉	Li, Yingwei; Zhou, Meng; Song, Yongbo; Higaki, Tatsuya; Wang, He; Jin, Rongchao (2021). "Double-helical assembly of heterodimeric nanoclusters into supercrystals". Nature. 594 (7863): 380–384. Bibcode:2021Natur.594..380L. doi:10.1038/s41586-021-03564-6. PMID 34135522.
Au₃₀S(S-^tBu)₁₈	Crasto, David; Malola, Sami; Brosofsky, Grace; Dass, Amala; Häkkinen, Hannu (2014). "Single Crystal XRD Structure and Theoretical Analysis of the Chiral Au₃₀S(S- t -Bu)₁₈ Cluster". Journal of the American Chemical Society. 136 (13): 5000–5005. doi:10.1021/ja412141j. PMID 24605935.
Au₃₀S(S-^tBu)₁₈	Yang, Huayan; Wang, Yu; Edwards, Alison J.; Yan, Juanzhu; Zheng, Nanfeng (2014). "High-yield synthesis and crystal structure of a green Au₃₀cluster co-capped by thiolate and sulfide". Chem. Commun. 50 (92): 14325–14327. doi:10.1039/C4CC01773K. PMID 25285336.
Au₃₀(S-^tBu)₁₈	Dass, Amala; Jones, Tanya; Rambukwella, Milan; Crasto, David; Gagnon, Kevin J.; Sementa, Luca; De Vetta, Martina; Baseggio, Oscar; Aprà, Edoardo; Stener, Mauro; Fortunelli, Alessandro (2016). "Crystal Structure and Theoretical Analysis of Green Gold Au₃₀(S- t Bu)₁₈ Nanomolecules and Their Relation to Au₃₀S(S- t Bu)₁₈". The Journal of Physical Chemistry C. 120 (11): 6256–6261. doi:10.1021/acs.jpcc.6b00062. hdl:11368/2881618.
Au₃₀(S-Adm)₁₈	Higaki, Tatsuya; Liu, Chong; Zeng, Chenjie; Jin, Renxi; Chen, Yuxiang; Rosi, Nathaniel L.; Jin, Rongchao (2016). "Controlling the Atomic Structure of Au₃₀ Nanoclusters by a Ligand-Based Strategy". Angewandte Chemie International Edition. 55 (23): 6694–6697. doi:10.1002/anie.201601947. PMID 27099989.
Au₃₀(S-Adm)₁₈	Li, Yingwei; Zhou, Meng; Song, Yongbo; Higaki, Tatsuya; Wang, He; Jin, Rongchao (2021). "Double-helical assembly of heterodimeric nanoclusters into supercrystals". Nature. 594 (7863): 380–384. Bibcode:2021Natur.594..380L. doi:10.1038/s41586-021-03564-6. PMID 34135522.
Au₃₄(S-c-C₆H₁₁)₂₂	Dong, Hongwei; Liao, Lingwen; Zhuang, Shengli; Yao, Chuanhao; Chen, Jishi; Tian, Shubo; Zhu, Min; Liu, Xu; Li, Lingling; Wu, Zhikun (2017). "A novel double-helical-kernel evolution pattern of gold nanoclusters: Alternate single-stranded growth at both ends". Nanoscale. 9 (11): 3742–3746. doi:10.1039/C6NR09724C. PMID 28134388.
Au₃₄(SPh-2,4-(CH₃)₂)₂₂	Zhuang, Shengli; Liao, Lingwen; Yuan, Jinyun; Xia, Nan; Zhao, Yan; Wang, Chengming; Gan, Zibao; Yan, Nan; He, Lizhong; Li, Jin; Deng, Haiteng; Guan, Zhaoyong; Yang, Jinlong; Wu, Zhikun (2019). "FCC versus Non-FCC Structural Isomerism of Gold Nanoparticles with Kernel Atom Packing Dependent Photoluminescence". Angewandte Chemie International Edition. 58 (14): 4510–4514. doi:10.1002/anie.201813426. PMID 30719808.
Au₃₆(SC₅H₉)₂₄	Das, Anindita; Liu, Chong; Zeng, Chenjie; Li, Gao; Li, Tao; Rosi, Nathaniel L.; Jin, Rongchao (2014). "Cyclopentanethiolato-Protected Au₃₆(SC₅H₉)₂₄ Nanocluster: Crystal Structure and Implications for the Steric and Electronic Effects of Ligand". The Journal of Physical Chemistry A. 118 (37): 8264–8269. Bibcode:2014JPCA..118.8264D. doi:10.1021/jp501073a. PMID 24617814.
Au₃₆(SPh)₂₄	Nimmala, Praneeth Reddy; Knoppe, Stefan; Jupally, Vijay Reddy; Delcamp, Jared H.; Aikens, Christine M.; Dass, Amala (2014). "Au₃₆(SPH)₂₄ Nanomolecules: X-ray Crystal Structure, Optical Spectroscopy, Electrochemistry, and Theoretical Analysis". The Journal of Physical Chemistry B. 118 (49): 14157–14167. doi:10.1021/jp506508x. PMID 25315687.
Au₃₆(TBBT)₂₄	Zeng, Chenjie; Qian, Huifeng; Li, Tao; Li, Gao; Rosi, Nathaniel L.; Yoon, Bokwon; Barnett, Robert N.; Whetten, Robert L.; Landman, Uzi; Jin, Rongchao (2012). "Total Structure and Electronic Properties of the Gold Nanocrystal Au₃₆(SR)₂₄". Angewandte Chemie International Edition. 51 (52): 13114–13118. doi:10.1002/anie.201207098. PMID 23154932.
Au₃₆(SCH₂Ph-^tBu)₈Cl₂₀	Yang, Sha; Chai, Jinsong; Song, Yongbo; Kang, Xi; Sheng, Hongting; Chong, Hanbao; Zhu, Manzhou (2015). "A New Crystal Structure of Au₃₆ with a Au₁₄ Kernel Cocapped by Thiolate and Chloride". Journal of the American Chemical Society. 137 (32): 10033–10035. doi:10.1021/jacs.5b06235. PMID 26252023.
[Au₃₇(PPh₃)₁₀(SC₂H₄Ph)₁₀X₂]⁺	Jin, Renxi; Liu, Chong; Zhao, Shuo; Das, Anindita; Xing, Hongzhu; Gayathri, Chakicherla; Xing, Yan; Rosi, Nathaniel L.; Gil, Roberto R.; Jin, Rongchao (2015). "Tri-icosahedral Gold Nanocluster [Au₃₇(PPH₃)₁₀(SC₂H₄Ph)₁₀X₂]⁺: Linear Assembly of Icosahedral Building Blocks". ACS Nano. 9 (8): 8530–8536. doi:10.1021/acsnano.5b03524. PMID 26214221.
Au₃₈(SC₂H₄Ph)₂₄	Qian, Huifeng; Eckenhoff, William T.; Zhu, Yan; Pintauer, Tomislav; Jin, Rongchao (2010). "Total Structure Determination of Thiolate-Protected Au₃₈ Nanoparticles". Journal of the American Chemical Society. 132 (24): 8280–8281. doi:10.1021/ja103592z. PMID 20515047.
Au₃₈(SC₂H₄Ph)₂₄	Tian, Shubo; Li, Yi-Zhi; Li, Man-Bo; Yuan, Jinyun; Yang, Jinlong; Wu, Zhikun; Jin, Rongchao (2015). "Structural isomerism in gold nanoparticles revealed by X-ray crystallography". Nature Communications. 6: 8667. Bibcode:2015NatCo...6.8667T. doi:10.1038/ncomms9667. PMC 4667693. PMID 26482704.
Au₃₈S₂(S-Adm)₂₀	Liu, Chao; Li, Tao; Li, Gao; Nobusada, Katsuyuki; Zeng, Chenjie; Pang, Guangsheng; Rosi, Nathaniel L.; Jin, Rongchao (2015). "Observation of Body-Centered Cubic Gold Nanocluster". Angewandte Chemie. 127 (34): 9964–9967. Bibcode:2015AngCh.127.9964L. doi:10.1002/ange.201502667.
Au₃₈(2,4-(CH₃)₂C₆H₃S)₂₄	Chai, Jinsong; Lv, Ying; Yang, Sha; Song, Yongbo; Zan, Xiaofeng; Li, Qinzhen; Yu, Haizhu; Wu, Mingzai; Zhu, Manzhou (2017). "X-ray Crystal Structure and Optical Properties of Au_{38– x}Cu_x(2,4-(CH₃)₂C₆H₃S)₂₄ ( x = 0–6) Alloy Nanocluster". The Journal of Physical Chemistry C. 121 (39): 21665–21669. doi:10.1021/acs.jpcc.7b05074.
Au₃₈(SPh-2,4-(CH₃)₂)₂₄	Zhuang, Shengli; Liao, Lingwen; Yuan, Jinyun; Xia, Nan; Zhao, Yan; Wang, Chengming; Gan, Zibao; Yan, Nan; He, Lizhong; Li, Jin; Deng, Haiteng; Guan, Zhaoyong; Yang, Jinlong; Wu, Zhikun (2019). "FCC versus Non-FCC Structural Isomerism of Gold Nanoparticles with Kernel Atom Packing Dependent Photoluminescence". Angewandte Chemie International Edition. 58 (14): 4510–4514. doi:10.1002/anie.201813426. PMID 30719808.
[Au₃₉(PPh₃)₁₄Cl₆]²⁺	Teo, Boon K.; Shi, Xiaobo; Zhang, Hong (1992). "Pure gold cluster of 1:9:9:1:9:9:1 layered structure: A novel 39-metal-atom cluster [(Ph3P)14Au39Cl6]Cl2 with an interstitial gold atom in a hexagonal antiprismatic cage". Journal of the American Chemical Society. 114 (7): 2743–2745. doi:10.1021/ja00033a073.
Au₄₀(S-2-(CH₃)Ph)₂₄	Zeng, Chenjie; Chen, Yuxiang; Liu, Chong; Nobusada, Katsuyuki; Rosi, Nathaniel L.; Jin, Rongchao (2015). "Gold tetrahedra coil up: Kekulé-like and double helical superstructures". Science Advances. 1 (9): e1500425. Bibcode:2015SciA....1E0425Z. doi:10.1126/sciadv.1500425. PMC 4646800. PMID 26601286.
Au₄₂(S-c-C₆H₁₁)₂₆	Dong, Hongwei; Liao, Lingwen; Zhuang, Shengli; Yao, Chuanhao; Chen, Jishi; Tian, Shubo; Zhu, Min; Liu, Xu; Li, Lingling; Wu, Zhikun (2017). "A novel double-helical-kernel evolution pattern of gold nanoclusters: Alternate single-stranded growth at both ends". Nanoscale. 9 (11): 3742–3746. doi:10.1039/C6NR09724C. PMID 28134388.
Au₄₂(TBBT)₂₆	Zhuang, Shengli; Liao, Lingwen; Yuan, Jinyun; Xia, Nan; Zhao, Yan; Wang, Chengming; Gan, Zibao; Yan, Nan; He, Lizhong; Li, Jin; Deng, Haiteng; Guan, Zhaoyong; Yang, Jinlong; Wu, Zhikun (2019). "FCC versus Non-FCC Structural Isomerism of Gold Nanoparticles with Kernel Atom Packing Dependent Photoluminescence". Angewandte Chemie International Edition. 58 (14): 4510–4514. doi:10.1002/anie.201813426. PMID 30719808.
Au₄₂(TBBT)₂₆	Zhuang, Shengli; Liao, Lingwen; Zhao, Yan; Yuan, Jinyun; Yao, Chuanhao; Liu, Xu; Li, Jin; Deng, Haiteng; Yang, Jinlong; Wu, Zhikun (2018). "Is the kernel–staples match a key–lock match?". Chemical Science. 9 (9): 2437–2442. doi:10.1039/C7SC05019D. PMC 5914134. PMID 29732119.
Au₄₂(SCH_2>Ph)₃₂	Li, Yingwei; Song, Yongbo; Zhang, Xinwen; Liu, Tongyu; Xu, Tingting; Wang, He; Jiang, De-en; Jin, Rongchao (2022). "Atomically Precise Au₄₂ Nanorods with Longitudinal Excitons for an Intense Photothermal Effect". Journal of the American Chemical Society. 144 (27): 12381–12389. doi:10.1021/jacs.2c03948. PMID 35767839.
Au₄₃(C₆H₁₁)₂₅	Dong, Hongwei; Liao, Lingwen; Wu, Zhikun (2017). "Two-Way Transformation between FCC- and Nonfcc-Structured Gold Nanoclusters". The Journal of Physical Chemistry Letters. 8 (21): 5338–5343. doi:10.1021/acs.jpclett.7b02459. PMID 29039677.
Au₄₄(SPh-2,4-(CH₃)₂)₂₆	Liao, Lingwen; Zhuang, Shengli; Yao, Chuanhao; Yan, Nan; Chen, Jishi; Wang, Chengming; Xia, Nan; Liu, Xu; Li, Man-Bo; Li, Lingling; Bao, Xiaoli; Wu, Zhikun (2016). "Structure of Chiral Au₄₄(2,4-DMBT)₂₆ Nanocluster with an 18-Electron Shell Closure". Journal of the American Chemical Society. 138 (33): 10425–10428. doi:10.1021/jacs.6b07178. PMID 27490914.
Au₄₄(TBBT)₂₈	Zeng, Chenjie; Chen, Yuxiang; Iida, Kenji; Nobusada, Katsuyuki; Kirschbaum, Kristin; Lambright, Kelly J.; Jin, Rongchao (2016). "Gold Quantum Boxes: On the Periodicities and the Quantum Confinement in the Au₂₈, Au₃₆, Au₄₄, and Au₅₂ Magic Series". Journal of the American Chemical Society. 138 (12): 3950–3953. doi:10.1021/jacs.5b12747. PMID 26934618.
Au₄₄(ⁱPr₂-bimy)₉(PA)₆Br₈	Shen, Hui; Xu, Zhen; Hazer, Maryam Sabooni Asre; Wu, Qingyuan; Peng, Jian; Qin, Ruixuan; Malola, Sami; Teo, Boon K.; Häkkinen, Hannu; Zheng, Nanfeng (2021). "Surface Coordination of Multiple Ligands Endows N-Heterocyclic Carbene-Stabilized Gold Nanoclusters with High Robustness and Surface Reactivity". Angewandte Chemie International Edition. 60 (7): 3752–3758. doi:10.1002/anie.202013718. PMID 33104265.
Au₅₂(TBBT)₃₂	Zeng, Chenjie; Chen, Yuxiang; Liu, Chong; Nobusada, Katsuyuki; Rosi, Nathaniel L.; Jin, Rongchao (2015). "Gold tetrahedra coil up: Kekulé-like and double helical superstructures". Science Advances. 1 (9): e1500425. Bibcode:2015SciA....1E0425Z. doi:10.1126/sciadv.1500425. PMC 4646800. PMID 26601286.
Au₅₂(PET)₃₂	Zhuang, Shengli; Liao, Lingwen; Li, Man-Bo; Yao, Chuanhao; Zhao, Yan; Dong, Hongwei; Li, Jin; Deng, Haiteng; Li, Lingling; Wu, Zhikun (2017). "The FCC structure isomerization in gold nanoclusters". Nanoscale. 9 (39): 14809–14813. doi:10.1039/C7NR05239A. PMID 28956580.
Au₇₀S₂₀(PPh₃)₁₂	Kenzler, Sebastian; Schrenk, Claudio; Frojd, Andrew R.; Häkkinen, Hannu; Clayborne, Andre Z.; Schnepf, Andreas (2018). "Au₇₀S₂₀(PPH₃)₁₂: An intermediate sized metalloid gold cluster stabilized by the Au₄S₄ ring motif and Au-PPH₃ groups". Chemical Communications. 54 (3): 248–251. doi:10.1039/C7CC08014J. PMID 29220046.
Au₉₂(TBBT)₄₄	Zeng, Chenjie; Liu, Chong; Chen, Yuxiang; Rosi, Nathaniel L.; Jin, Rongchao (2016). "Atomic Structure of Self-Assembled Monolayer of Thiolates on a Tetragonal Au₉₂ Nanocrystal". Journal of the American Chemical Society. 138 (28): 8710–8713. doi:10.1021/jacs.6b04835. PMID 27355843.
Au₁₀₂(p-MBA)₄₄	Jadzinsky, Pablo D.; Calero, Guillermo; Ackerson, Christopher J.; Bushnell, David A.; Kornberg, Roger D. (2007). "Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 Å Resolution". Science. 318 (5849): 430–433. Bibcode:2007Sci...318..430J. doi:10.1126/science.1148624. PMID 17947577.
Au₁₀₂(p-MBA)₄₀(p-BBT)₄	Heinecke, Christine L.; Ni, Thomas W.; Malola, Sami; Mäkinen, Ville; Wong, O. Andrea; Häkkinen, Hannu; Ackerson, Christopher J. (2012). "Structural and Theoretical Basis for Ligand Exchange on Thiolate Monolayer Protected Gold Nanoclusters". Journal of the American Chemical Society. 134 (32): 13316–13322. doi:10.1021/ja3032339. PMC 4624284. PMID 22816317.
Au₁₀₃S₂(S-Nap)₄₁	Higaki, Tatsuya; Liu, Chong; Zhou, Meng; Luo, Tian-Yi; Rosi, Nathaniel L.; Jin, Rongchao (2017). "Tailoring the Structure of 58-Electron Gold Nanoclusters: Au₁₀₃S₂(S-Nap)₄₁ and Its Implications". Journal of the American Chemical Society. 139 (29): 9994–10001. doi:10.1021/jacs.7b04678. PMID 28661158.
[Au₁₁₀(p-CF₃C₆H₄CC)₄₈]^2-	Wang, Jia-Qi; Shi, Shuang; He, Rui-Lin; Yuan, Shang-Fu; Yang, Gao-Yuan; Liang, Gui-Jie; Wang, Quan-Ming (2020). "Total Structure Determination of the Largest Alkynyl-Protected FCC Gold Nanocluster Au₁₁₀ and the Study on Its Ultrafast Excited-State Dynamics". Journal of the American Chemical Society. 142 (42): 18086–18092. doi:10.1021/jacs.0c07397. PMID 32985888.
Au₁₃₀(p-MBT)₅₀	Chen, Yuxiang; Zeng, Chenjie; Liu, Chong; Kirschbaum, Kristin; Gayathri, Chakicherla; Gil, Roberto R.; Rosi, Nathaniel L.; Jin, Rongchao (2015). "Crystal Structure of Barrel-Shaped Chiral Au₁₃₀( p -MBT)₅₀ Nanocluster". Journal of the American Chemical Society. 137 (32): 10076–10079. doi:10.1021/jacs.5b05378. PMID 26244606.
Au₁₃₃(SPh^tBu)₅₂	Zeng, Chenjie; Chen, Yuxiang; Kirschbaum, Kristin; Appavoo, Kannatassen; Sfeir, Matthew Y.; Jin, Rongchao (2015). "Structural patterns at all scales in a nonmetallic chiral Au ₁₃₃ (SR) ₅₂ nanoparticle". Science Advances. 1 (2): e1500045. Bibcode:2015SciA....1E0045Z. doi:10.1126/sciadv.1500045. PMC 4643822. PMID 26601152.
Au₁₄₄(SCH₂Ph)₆₀	Yan, Nan; Xia, Nan; Liao, Lingwen; Zhu, Min; Jin, Fengming; Jin, Rongchao; Wu, Zhikun (2018). "Unraveling the long-pursued Au ₁₄₄ structure by x-ray crystallography". Science Advances. 4 (10): eaat7259. Bibcode:2018SciA....4.7259Y. doi:10.1126/sciadv.aat7259. PMC 6184749. PMID 30333988.
Au₁₄₄(CCAr)₆₀	Lei, Zhen; Li, Jiao-Jiao; Wan, Xian-Kai; Zhang, Wen-Han; Wang, Quan-Ming (2018). "Isolation and Total Structure Determination of an All-Alkynyl-Protected Gold Nanocluster Au₁₄₄". Angewandte Chemie International Edition. 57 (28): 8639–8643. doi:10.1002/anie.201804481. PMID 29771454.
Au₁₄₆(p-MBA)₅₇	Vergara, Sandra; Lukes, Dylan A.; Martynowycz, Michael W.; Santiago, Ulises; Plascencia-Villa, Germán; Weiss, Simon C.; de la Cruz, M. Jason; Black, David M.; Alvarez, Marcos M.; López-Lozano, Xochitl; Barnes, Christopher O.; Lin, Guowu; Weissker, Hans-Christian; Whetten, Robert L.; Gonen, Tamir; Yacaman, Miguel Jose; Calero, Guillermo (2017). "MicroED Structure of Au₁₄₆(p-MBA)₅₇ at Subatomic Resolution Reveals a Twinned FCC Cluster". The Journal of Physical Chemistry Letters. 8 (22): 5523–5530. doi:10.1021/acs.jpclett.7b02621. PMC 5769702. PMID 29072840.
Au₁₉₁(SPh-^tBu)₆₆	Sakthivel, Naga Arjun; Shabaninezhad, Masoud; Sementa, Luca; Yoon, Bokwon; Stener, Mauro; Whetten, Robert L.; Ramakrishna, Guda; Fortunelli, Alessandro; Landman, Uzi; Dass, Amala (2020). "The Missing Link: Au₁₉₁(SPH- t Bu)₆₆ Janus Nanoparticle with Molecular and Bulk-Metal-like Properties". Journal of the American Chemical Society. 142 (37): 15799–15814. doi:10.1021/jacs.0c05685. PMID 32881489.
Au₂₄₆(p-MBT)₈₀	Zeng, Chenjie; Chen, Yuxiang; Kirschbaum, Kristin; Lambright, Kelly J.; Jin, Rongchao (2016). "Emergence of hierarchical structural complexities in nanoparticles and their assembly". Science. 354 (6319): 1580–1584. Bibcode:2016Sci...354.1580Z. doi:10.1126/science.aak9750. PMID 28008066.
Au₂₇₉(SPh-^tBu)₈₄	Sakthivel, Naga Arjun; Theivendran, Shevanuja; Ganeshraj, Vigneshraja; Oliver, Allen G.; Dass, Amala (2017). "Crystal Structure of Faradaurate-279: Au₂₇₉(SPH- t Bu)₈₄ Plasmonic Nanocrystal Molecules". Journal of the American Chemical Society. 139 (43): 15450–15459. doi:10.1021/jacs.7b08651. PMID 28991464.

Silver

Table of the crystal structures of silver MPCs.
Formula	References
[{Ag(Ph₂PS₂)(dppe)}₂]	Shafaei-Fallah, Maryam; Anson, Christopher E.; Fenske, Dieter; Rothenberger, Alexander (2005). "Functionalised trimethylsilyl reagents in cluster synthesis: Reactions of Ph2P(S)SSiMe3 with group 11 salts". Dalton Transactions (13): 2300–2304. doi:10.1039/B501360G. PMID 15962051.
[{Ag(Ph₂PS₂)(dppe)}₄]⁺	Shafaei-Fallah, Maryam; Anson, Christopher E.; Fenske, Dieter; Rothenberger, Alexander (2005). "Functionalised trimethylsilyl reagents in cluster synthesis: Reactions of Ph2P(S)SSiMe3 with group 11 salts". Dalton Transactions (13): 2300–2304. doi:10.1039/B501360G. PMID 15962051.
[Ag₈(F){S₂P(CH₂CH₂Ph)₂}₆]⁺	Liao, Jian-Hong; Latouche, Camille; Li, Bing; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2014). "A Twelve-Coordinated Iodide in a Cuboctahedral Silver(I) Skeleton". Inorganic Chemistry. 53 (4): 2260–2267. doi:10.1021/ic402960e. PMID 24476137.
[Ag₈(Cl){S₂P(CH₂CH₂Ph)₂}₆]⁺	Liao, Jian-Hong; Latouche, Camille; Li, Bing; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2014). "A Twelve-Coordinated Iodide in a Cuboctahedral Silver(I) Skeleton". Inorganic Chemistry. 53 (4): 2260–2267. doi:10.1021/ic402960e. PMID 24476137.
[Ag₈(Br){S₂P(CH₂CH₂Ph)₂}₆]⁺	Liao, Jian-Hong; Latouche, Camille; Li, Bing; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2014). "A Twelve-Coordinated Iodide in a Cuboctahedral Silver(I) Skeleton". Inorganic Chemistry. 53 (4): 2260–2267. doi:10.1021/ic402960e. PMID 24476137.
[Ag₈(pfga)₆]^6-	Liu, Kuan-Guan; Gao, Xue-Mei; Liu, Tongyu; Hu, Mao-Lin; Jiang, De-en (2020). "All-Carboxylate-Protected Superatomic Silver Nanocluster with an Unprecedented Rhombohedral Ag₈ Core". Journal of the American Chemical Society. 142 (40): 16905–16909. doi:10.1021/jacs.0c06682. PMID 32941019.
[{Ag(Ph₂PS₂)(dppe)}₁₀]	Shafaei-Fallah, Maryam; Anson, Christopher E.; Fenske, Dieter; Rothenberger, Alexander (2005). "Functionalised trimethylsilyl reagents in cluster synthesis: Reactions of Ph2P(S)SSiMe3 with group 11 salts". Dalton Transactions (13): 2300–2304. doi:10.1039/B501360G. PMID 15962051.
[Ag₁₂(μ₁₂-I)(μ₃-I)₄{S₂P(CH₂CH₂Ph)₂}₆]⁺	Liao, Jian-Hong; Latouche, Camille; Li, Bing; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2014). "A Twelve-Coordinated Iodide in a Cuboctahedral Silver(I) Skeleton". Inorganic Chemistry. 53 (4): 2260–2267. doi:10.1021/ic402960e. PMID 24476137.
Ag₁₂(SCH₂C₁₀H₇)₆(CF₃CO₂)₆(CH₃CN)₆	Xu, Qing-Qing; Dong, Xi-Yan; Huang, Ren-Wu; Li, Bo; Zang, Shuang-Quan; Mak, Thomas C. W. (2015). "A thermochromic silver nanocluster exhibiting dual emission character". Nanoscale. 7 (5): 1650–1654. Bibcode:2015Nanos...7.1650X. doi:10.1039/C4NR05122J. PMID 25556676.
Ag₁₄(SC₆H₃F₂)₁₂(PPh₃)₈	Yang, Huayan; Lei, Jing; Wu, Binghui; Wang, Yu; Zhou, Meng; Xia, Andong; Zheng, Lansun; Zheng, Nanfeng (2013). "Crystal structure of a luminescent thiolated Ag nanocluster with an octahedral Ag₆⁴⁺core". Chem. Commun. 49 (3): 300–302. doi:10.1039/C2CC37347E. PMID 23183545.
Ag₁₆(DPPE)₄(SC₆H₃F₂)₁₄	Yang, Huayan; Wang, Yu; Zheng, Nanfeng (2013). "Stabilizing subnanometer Ag(0) nanoclusters by thiolate and diphosphine ligands and their crystal structures". Nanoscale. 5 (7): 2674–2677. Bibcode:2013Nanos...5.2674Y. doi:10.1039/C3NR34328F. PMID 23467729.
DNA-Ag₈	Huard, Dustin J. E.; Demissie, Aida; Kim, Dahye; Lewis, David; Dickson, Robert M.; Petty, Jeffrey T.; Lieberman, Raquel L. (2019). "Atomic Structure of a Fluorescent Ag₈ Cluster Templated by a Multistranded DNA Scaffold". Journal of the American Chemical Society. 141 (29): 11465–11470. doi:10.1021/jacs.8b12203. PMC 6606393. PMID 30562465. (PDB: 6NIZ)
DNA-Ag₁₆-NC	Cerretani, Cecilia; Kanazawa, Hiroki; Vosch, Tom; Kondo, Jiro (2019). "Crystal structure of a NIR-Emitting DNA-Stabilized Ag₁₆ Nanocluster". Angewandte Chemie International Edition. 58 (48): 17153–17157. doi:10.1002/anie.201906766. PMID 31411360. (PDB: 6JR4)
DNA-A₁₀:Ag₁₆	Cerretani, Cecilia; Kondo, Jiro; Vosch, Tom (2020). "Removal of the A₁₀ adenosine in a DNA-stabilized Ag₁₆ nanocluster". RSC Advances. 10 (40): 23854–23860. Bibcode:2020RSCAd..1023854C. doi:10.1039/D0RA02672G. PMC 9054913. PMID 35517326. (PDB: 6M2P)
DNA(A5)-Ag₁₆	Cerretani, Cecilia; Kondo, Jiro; Vosch, Tom (2020). "Mutation of position 5 as a crystal engineering tool for a NIR-emitting DNA-stabilized Ag₁₆ nanocluster". CrystEngComm. 22 (46): 8136–8141. doi:10.1039/D0CE01225D. (PDB: 7BSE)
DNA(C5)-Ag₁₆	Cerretani, Cecilia; Kondo, Jiro; Vosch, Tom (2020). "Mutation of position 5 as a crystal engineering tool for a NIR-emitting DNA-stabilized Ag₁₆ nanocluster". CrystEngComm. 22 (46): 8136–8141. doi:10.1039/D0CE01225D. (PDB: 7BSF)
DNA(G5-NIR)-Ag₁₆	Cerretani, Cecilia; Kondo, Jiro; Vosch, Tom (2020). "Mutation of position 5 as a crystal engineering tool for a NIR-emitting DNA-stabilized Ag₁₆ nanocluster". CrystEngComm. 22 (46): 8136–8141. doi:10.1039/D0CE01225D. (PDB: 7BSG)
DNA(X5)-Ag₁₆	Cerretani, Cecilia; Kondo, Jiro; Vosch, Tom (2020). "Mutation of position 5 as a crystal engineering tool for a NIR-emitting DNA-stabilized Ag₁₆ nanocluster". CrystEngComm. 22 (46): 8136–8141. doi:10.1039/D0CE01225D. (PDB: 7BSH)
DNA-Ag₁₆	Cerretani, Cecilia; Liisberg, Mikkel B.; Rück, Vanessa; Kondo, Jiro; Vosch, Tom (2022). "The effect of inosine on the spectroscopic properties and crystal structure of a NIR-emitting DNA-stabilized silver nanocluster". Nanoscale Advances. 4 (15): 3212–3217. Bibcode:2022NanoA...4.3212C. doi:10.1039/D2NA00325B. PMC 9416947. PMID 36132821. (PDB: 6JR4)
DNA-Ag₁₆	Cerretani, Cecilia; Liisberg, Mikkel B.; Rück, Vanessa; Kondo, Jiro; Vosch, Tom (2022). "The effect of inosine on the spectroscopic properties and crystal structure of a NIR-emitting DNA-stabilized silver nanocluster". Nanoscale Advances. 4 (15): 3212–3217. Bibcode:2022NanoA...4.3212C. doi:10.1039/D2NA00325B. PMC 9416947. PMID 36132821. (PDB: 7XLV)
[Ag₂₀{S₂P(OPr)₂}₁₂]	Dhayal, Rajendra S.; Lin, Yan-Ru; Liao, Jian-Hong; Chen, Yuan-Jang; Liu, Yu-Chiao; Chiang, Ming-Hsi; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2016). "[Ag₂₀{S₂P(OR)₂}₁₂]: A Superatom Complex with a Chiral Metallic Core and High Potential for Isomerism" (PDF). Chemistry – A European Journal. 22 (29): 9943–9947. doi:10.1002/chem.201602275. PMID 27189869.
[Ag₂₀{S₂P(OⁱPr)₂}₁₂]	Dhayal, Rajendra S.; Lin, Yan-Ru; Liao, Jian-Hong; Chen, Yuan-Jang; Liu, Yu-Chiao; Chiang, Ming-Hsi; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2016). "[Ag₂₀{S₂P(OR)₂}₁₂]: A Superatom Complex with a Chiral Metallic Core and High Potential for Isomerism" (PDF). Chemistry – A European Journal. 22 (29): 9943–9947. doi:10.1002/chem.201602275. PMID 27189869.
[Ag₂₁{S₂P(OiPr)₂}₁₂]⁺	Dhayal, Rajendra S.; Liao, Jian-Hong; Liu, Yu-Chiao; Chiang, Ming-His; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2015). "[Ag₂₁{S₂P(O i Pr)₂}₁₂]⁺: An Eight-Electron Superatom". Angewandte Chemie International Edition. 54 (12): 3702–3706. doi:10.1002/anie.201410332. PMID 25631754.
Ag₂₃(PPh₃)₈(SC₂H₄Ph)₁₈	Liu, Chao; Li, Tao; Abroshan, Hadi; Li, Zhimin; Zhang, Chen; Kim, Hyung J.; Li, Gao; Jin, Rongchao (2018). "Chiral Ag23 nanocluster with open shell electronic structure and helical face-centered cubic framework". Nature Communications. 9 (1): 744. doi:10.1038/s41467-018-03136-9. PMC 5821857. PMID 29467372.
[Ag₂₄(PS₄)(iPrSPS₃)₄{S(tol)}₁₂(dppe)₆)]⁺	Rothenberger, Alexander; Shafaei-Fallah, Maryam; Shi, Weifeng (2007). "A recipe for new organometallic polymers and oligomers? Synthesis and structure of an oligo- and a polymeric arrangement of P–S anions". Chem. Commun. (15): 1499–1501. doi:10.1039/B617177J. PMID 17406686.
[Ag₂₅(SPh(CH₃)₂)₁₈]^-	Joshi, Chakra P.; Bootharaju, Megalamane S.; Alhilaly, Mohammad J.; Bakr, Osman M. (2015). "[Ag₂₅(SR)₁₈]⁻: The "Golden" Silver Nanoparticle". Journal of the American Chemical Society. 137 (36): 11578–11581. doi:10.1021/jacs.5b07088. hdl:10754/576875. PMID 26322865.
[Ag₂₈(S^tBu)₂₃]⁵⁺	Zhou, Kun; Qin, Chao; Wang, Xin-Long; Shao, Kui-Zhan; Yan, Li-Kai; Su, Zhong-Min (2014). "Self-assembly of an all-thiol-stabilized {Ag28S23} high-nuclearity luminescent nanocluster with a "crab-like" shape". Dalton Transactions. 43 (28): 10695–10699. doi:10.1039/C4DT00762J. PMID 24921974.
Ag₂₉(BDT)₁₂(TPP)₄	Abdulhalim, Lina G.; Bootharaju, Megalamane S.; Tang, Qing; Del Gobbo, Silvano; Abdulhalim, Rasha G.; Eddaoudi, Mohamed; Jiang, De-en; Bakr, Osman M. (2015). "Ag₂₉(BDT)₁₂(TPP)₄: A Tetravalent Nanocluster". Journal of the American Chemical Society. 137 (37): 11970–11975. doi:10.1021/jacs.5b04547. hdl:10754/558586. PMID 26104755.
[Ag₂₉(BDT)₁₂(TPP)₄]^3-	Nag, Abhijit; Chakraborty, Papri; Bodiuzzaman, Mohammad; Ahuja, Tripti; Antharjanam, Sudhadevi; Pradeep, Thalappil (2018). "Polymorphism of Ag₂₉(BDT)₁₂(TPP)₄³⁻ cluster: Interactions of secondary ligands and their effect on solid state luminescence". Nanoscale. 10 (21): 9851–9855. doi:10.1039/C8NR02629G. PMID 29790561.
[Ag₃₂(DPPE)₅(SC₆H₄CF₃)₂₄]^2-	Yang, Huayan; Wang, Yu; Zheng, Nanfeng (2013). "Stabilizing subnanometer Ag(0) nanoclusters by thiolate and diphosphine ligands and their crystal structures". Nanoscale. 5 (7): 2674–2677. Bibcode:2013Nanos...5.2674Y. doi:10.1039/C3NR34328F. PMID 23467729.
[Ag₃₂(Dppm)₅(SAdm)₁₃Cl₈]³⁺	Zou, Xuejuan; Jin, Shan; Du, Wenjun; Li, Yangfeng; Li, Peng; Wang, Shuxin; Zhu, Manzhou (2017). "Multi-ligand-directed synthesis of chiral silver nanoclusters". Nanoscale. 9 (43): 16800–16805. doi:10.1039/C7NR06338E. PMID 29072749.
Ag₃₈(SPhF₂)₂₆(PPh₃)₈	Yang, Huayan; Yan, Juanzhu; Wang, Yu; Su, Haifeng; Gell, Lars; Zhao, Xiaojing; Xu, Chaofa; Teo, Boon K.; Häkkinen, Hannu; Zheng, Nanfeng (2017). "Embryonic Growth of Face-Center-Cubic Silver Nanoclusters Shaped in Nearly Perfect Half-Cubes and Cubes". Journal of the American Chemical Society. 139 (1): 31–34. doi:10.1021/jacs.6b10053. PMID 27992210.
Ag₃₈(SPhF₂)₂₆(PⁿBu₃)₈	Yang, Huayan; Yan, Juanzhu; Wang, Yu; Su, Haifeng; Gell, Lars; Zhao, Xiaojing; Xu, Chaofa; Teo, Boon K.; Häkkinen, Hannu; Zheng, Nanfeng (2017). "Embryonic Growth of Face-Center-Cubic Silver Nanoclusters Shaped in Nearly Perfect Half-Cubes and Cubes". Journal of the American Chemical Society. 139 (1): 31–34. doi:10.1021/jacs.6b10053. PMID 27992210.
[Ag₄₀(SPh(CH₃)₂)₂₄(PPh₃)₈]²⁺	Bodiuzzaman, Mohammad; Ghosh, Atanu; Sugi, Korath Shivan; Nag, Abhijit; Khatun, Esma; Varghese, Babu; Paramasivam, Ganesan; Antharjanam, Sudhadevi; Natarajan, Ganapati; Pradeep, Thalappil (2019). "Camouflaging Structural Diversity: Co-crystallization of Two Different Nanoparticles Having Different Cores but the Same Shell". Angewandte Chemie International Edition. 58 (1): 189–194. doi:10.1002/anie.201809469. PMID 30411444.
[Ag₄₀(DMBT)₂₄(PPh₃)₈H₁₂]²⁺	Yuan, Xiting; Sun, Cunfa; Li, Xihua; Malola, Sami; Teo, Boon K.; Häkkinen, Hannu; Zheng, Lan-Sun; Zheng, Nanfeng (2019). "Combinatorial Identification of Hydrides in a Ligated Ag₄₀ Nanocluster with Noncompact Metal Core". Journal of the American Chemical Society. 141 (30): 11905–11911. doi:10.1021/jacs.9b03009. PMID 31294970.
[Ag₄₄(p-MBA)₃₀]^4-	Desireddy, Anil; Conn, Brian E.; Guo, Jingshu; Yoon, Bokwon; Barnett, Robert N.; Monahan, Bradley M.; Kirschbaum, Kristin; Griffith, Wendell P.; Whetten, Robert L.; Landman, Uzi; Bigioni, Terry P. (2013). "Ultrastable silver nanoparticles". Nature. 501 (7467): 399–402. Bibcode:2013Natur.501..399D. doi:10.1038/nature12523. PMID 24005327.
[Ag₄₄(SPhF)₃₀]^4-	Yang, Huayan; Wang, Yu; Huang, Huaqi; Gell, Lars; Lehtovaara, Lauri; Malola, Sami; Häkkinen, Hannu; Zheng, Nanfeng (2013). "All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures". Nature Communications. 4: 2422. doi:10.1038/ncomms3422. PMID 24005600.
[Ag₄₄(SPhF₂)₃₀]^4-	Yang, Huayan; Wang, Yu; Huang, Huaqi; Gell, Lars; Lehtovaara, Lauri; Malola, Sami; Häkkinen, Hannu; Zheng, Nanfeng (2013). "All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures". Nature Communications. 4: 2422. doi:10.1038/ncomms3422. PMID 24005600.
[Ag₄₄(SPhF₃)₃₀]^4-	Yang, Huayan; Wang, Yu; Huang, Huaqi; Gell, Lars; Lehtovaara, Lauri; Malola, Sami; Häkkinen, Hannu; Zheng, Nanfeng (2013). "All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures". Nature Communications. 4: 2422. doi:10.1038/ncomms3422. PMID 24005600.
Ag₄₄(EBT)₂₆(TPP)₄	Bootharaju, Megalamane S.; Lee, Sanghwa; Deng, Guocheng; Malola, Sami; Baek, Woonhyuk; Häkkinen, Hannu; Zheng, Nanfeng; Hyeon, Taeghwan (2021). "Ag₄₄(EBT)₂₆(TPP)₄ Nanoclusters with Tailored Molecular and Electronic Structure". Angewandte Chemie International Edition. 60 (16): 9038–9044. doi:10.1002/anie.202015907. PMID 33372362.
[Ag₄₅(Dppm)₄(S^tBu)₁₆Br₁₂]³⁺	Zou, Xuejuan; Jin, Shan; Du, Wenjun; Li, Yangfeng; Li, Peng; Wang, Shuxin; Zhu, Manzhou (2017). "Multi-ligand-directed synthesis of chiral silver nanoclusters". Nanoscale. 9 (43): 16800–16805. doi:10.1039/C7NR06338E. PMID 29072749.
[Ag₄₆(SPh(CH₃)₂)₂₄(PPh₃)₈]²⁺	Bodiuzzaman, Mohammad; Ghosh, Atanu; Sugi, Korath Shivan; Nag, Abhijit; Khatun, Esma; Varghese, Babu; Paramasivam, Ganesan; Antharjanam, Sudhadevi; Natarajan, Ganapati; Pradeep, Thalappil (2019). "Camouflaging Structural Diversity: Co-crystallization of Two Different Nanoparticles Having Different Cores but the Same Shell". Angewandte Chemie International Edition. 58 (1): 189–194. doi:10.1002/anie.201809469. PMID 30411444.
Ag₅₀(Dppm)₆(SPh-^tBu)₃₀	Du, Wenjun; Jin, Shan; Xiong, Lin; Chen, Man; Zhang, Jun; Zou, Xuejuan; Pei, Yong; Wang, Shuxin; Zhu, Manzhou (2017). "Ag₅₀(DPPM)₆(SR)₃₀ and Its Homologue Au_xAg_{50– x}(DPPM)₆(SR)₃₀ Alloy Nanocluster: Seeded Growth, Structure Determination, and Differences in Properties". Journal of the American Chemical Society. 139 (4): 1618–1624. doi:10.1021/jacs.6b11681. PMID 28111946.
[Ag₅₁(Dppm)₄(S^tBu)₁₆Br₆]³⁺	Zou, Xuejuan; Jin, Shan; Du, Wenjun; Li, Yangfeng; Li, Peng; Wang, Shuxin; Zhu, Manzhou (2017). "Multi-ligand-directed synthesis of chiral silver nanoclusters". Nanoscale. 9 (43): 16800–16805. doi:10.1039/C7NR06338E. PMID 29072749.
[Ag₆₂S₁₂(S^tBu)₃₂]²⁺	Jin, Shan; Wang, Shuxin; Song, Yongbo; Zhou, Meng; Zhong, Juan; Zhang, Jun; Xia, Andong; Pei, Yong; Chen, Man; Li, Peng; Zhu, Manzhou (2014). "Crystal Structure and Optical Properties of the [Ag₆₂S₁₂(SBu^t)₃₂]²⁺ Nanocluster with a Complete Face-Centered Cubic Kernel". Journal of the American Chemical Society. 136 (44): 15559–15565. doi:10.1021/ja506773d. PMID 25343538.
[Ag₅₂(SAdm)₃₁Cl₁₃]²⁺	Zou, Xuejuan; Lv, Ying; Kang, Xi; Yu, Haizhu; Jin, Shan; Zhu, Manzhou (2021). "Structure Determination of the Cl-Enriched [Ag₅₂(SAdm)₃₁Cl₁₃]²⁺ Nanocluster". Inorganic Chemistry. 60 (19): 14803–14809. doi:10.1021/acs.inorgchem.1c02067. PMID 34516083.
[Ag₆₂S₁₃(S-^tBu)₃₂]⁴⁺	Li, Gen; Lei, Zhen; Wang, Quan-Ming (2010). "Luminescent Molecular Ag−S Nanocluster [Ag₆₂S₁₃(SBu^t)₃₂](BF₄)₄". Journal of the American Chemical Society. 132 (50): 17678–17679. doi:10.1021/ja108684m. PMID 21114326.
[Ag₆₃(SPhF₂)₃₆(PPh₃)₈]⁺	Yang, Huayan; Yan, Juanzhu; Wang, Yu; Su, Haifeng; Gell, Lars; Zhao, Xiaojing; Xu, Chaofa; Teo, Boon K.; Häkkinen, Hannu; Zheng, Nanfeng (2017). "Embryonic Growth of Face-Center-Cubic Silver Nanoclusters Shaped in Nearly Perfect Half-Cubes and Cubes". Journal of the American Chemical Society. 139 (1): 31–34. doi:10.1021/jacs.6b10053. PMID 27992210.
[Ag₆₃(SPhF₂)₃₆(PⁿBu₃)₈]⁺	Yang, Huayan; Yan, Juanzhu; Wang, Yu; Su, Haifeng; Gell, Lars; Zhao, Xiaojing; Xu, Chaofa; Teo, Boon K.; Häkkinen, Hannu; Zheng, Nanfeng (2017). "Embryonic Growth of Face-Center-Cubic Silver Nanoclusters Shaped in Nearly Perfect Half-Cubes and Cubes". Journal of the American Chemical Society. 139 (1): 31–34. doi:10.1021/jacs.6b10053. PMID 27992210.
[Ag₆₇(SPhMe₂)₃₂(PPh₃)₈]³⁺	Alhilaly, Mohammad J.; Bootharaju, Megalamane S.; Joshi, Chakra P.; Besong, Tabot M.; Emwas, Abdul-Hamid; Juarez-Mosqueda, Rosalba; Kaappa, Sami; Malola, Sami; Adil, Karim; Shkurenko, Aleksander; Häkkinen, Hannu; Eddaoudi, Mohamed; Bakr, Osman M. (2016). "[Ag₆₇(SPhMe₂)₃₂(PPH₃)₈]³⁺: Synthesis, Total Structure, and Optical Properties of a Large Box-Shaped Silver Nanocluster". Journal of the American Chemical Society. 138 (44): 14727–14732. doi:10.1021/jacs.6b09007. hdl:10754/622496. PMID 27733038.
Ag₇₀S₁₆(SPh)₃₄(PhCO₂)₄(triphos)₄	Wang, Xiu-Jian; Langetepe, Timo; Persau, Claudia; Kang, Bei-Sheng; Sheldrick, George M.; Fenske, Dieter (2002). "Syntheses and Crystal Structures of the New Ag–S Clusters [Ag70S16(SPH)34(PhCO2)4(triphos)4] and [Ag188S94(PR3)30]". Angewandte Chemie International Edition. 41 (20): 3818–3822. doi:10.1002/1521-3773(20021018)41:20<3818::AID-ANIE3818>3.0.CO;2-R. PMID 12386858.
Ag₇₈(DPPP)₆(SPhCF₃)₄₂	Yang, Huayan; Yan, Juanzhu; Wang, Yu; Deng, Guocheng; Su, Haifeng; Zhao, Xiaojing; Xu, Chaofa; Teo, Boon K.; Zheng, Nanfeng (2017). "From Racemic Metal Nanoparticles to Optically Pure Enantiomers in One Pot". Journal of the American Chemical Society. 139 (45): 16113–16116. doi:10.1021/jacs.7b10448. PMID 29053274.
Ag₇₈(R-BDPP)₆(SPhCF₃)₄₂	Yang, Huayan; Yan, Juanzhu; Wang, Yu; Deng, Guocheng; Su, Haifeng; Zhao, Xiaojing; Xu, Chaofa; Teo, Boon K.; Zheng, Nanfeng (2017). "From Racemic Metal Nanoparticles to Optically Pure Enantiomers in One Pot". Journal of the American Chemical Society. 139 (45): 16113–16116. doi:10.1021/jacs.7b10448. PMID 29053274.
Ag₇₈(S-BDPP)₆(SPhCF₃)₄₂	Yang, Huayan; Yan, Juanzhu; Wang, Yu; Deng, Guocheng; Su, Haifeng; Zhao, Xiaojing; Xu, Chaofa; Teo, Boon K.; Zheng, Nanfeng (2017). "From Racemic Metal Nanoparticles to Optically Pure Enantiomers in One Pot". Journal of the American Chemical Society. 139 (45): 16113–16116. doi:10.1021/jacs.7b10448. PMID 29053274.
SD/Ag90a	Su, Yan-Min; Wang, Zhi; Schein, Stan; Tung, Chen-Ho; Sun, Di (2020). "A Keplerian Ag90 nest of Platonic and Archimedean polyhedra in different symmetry groups". Nature Communications. 11 (1): 3316. doi:10.1038/s41467-020-17198-1. PMC 7335041. PMID 32620807.
SD/Ag90b	Su, Yan-Min; Wang, Zhi; Schein, Stan; Tung, Chen-Ho; Sun, Di (2020). "A Keplerian Ag90 nest of Platonic and Archimedean polyhedra in different symmetry groups". Nature Communications. 11 (1): 3316. doi:10.1038/s41467-020-17198-1. PMC 7335041. PMID 32620807.
[Ag₁₁₅S₃₄(SCH₂C₆H₄^tBu)₄₇(dpph)₆]	Bestgen, Sebastian; Fuhr, Olaf; Breitung, Ben; Kiran Chakravadhanula, Venkata Sei; Guthausen, Gisela; Hennrich, Frank; Yu, Wen; Kappes, Manfred M.; Roesky, Peter W.; Fenske, Dieter (2017). "[Ag₁₁₅S₃₄(SCH₂C₆H₄^tBu)₄₇(DPPH)₆]: Synthesis, crystal structure and NMR investigations of a soluble silver chalcogenide nanocluster". Chemical Science. 8 (3): 2235–2240. doi:10.1039/C6SC04578B. PMC 5408567. PMID 28507679.
Ag₁₂₃S₃₅(S^tBu)₅₀	Fenske, Dieter; Anson, Christopher E.; Eichhöfer, Andreas; Fuhr, Olaf; Ingendoh, Arnd; Persau, Claudia; Richert, Clemens (2005). "Syntheses and Crystal Structures of [Ag₁₂₃S₃₅(S t Bu)₅₀] and [Ag₃₄₄S₁₂₄(S t Bu)₉₆]". Angewandte Chemie International Edition. 44 (33): 5242–5246. doi:10.1002/anie.200501414. PMID 16052644.
[Ag₁₃₆(SPh-^tBu)₆₄Cl₃]^-	Yang, Huayan; Wang, Yu; Chen, Xi; Zhao, Xiaojing; Gu, Lin; Huang, Huaqi; Yan, Juanzhu; Xu, Chaofa; Li, Gang; Wu, Junchao; Edwards, Alison J.; Dittrich, Birger; Tang, Zichao; Wang, Dongdong; Lehtovaara, Lauri; Häkkinen, Hannu; Zheng, Nanfeng (2016). "Plasmonic twinned silver nanoparticles with molecular precision". Nature Communications. 7: 12809. Bibcode:2016NatCo...712809Y. doi:10.1038/ncomms12809. PMC 5023969. PMID 27611564.
[Ag₁₄₁Cl₁₂(S-Adm)₄₀]³⁺	Ren, Liting; Yuan, Peng; Su, Haifeng; Malola, Sami; Lin, Shuichao; Tang, Zichao; Teo, Boon K.; Häkkinen, Hannu; Zheng, Lansun; Zheng, Nanfeng (2017). "Bulky Surface Ligands Promote Surface Reactivities of [Ag₁₄₁X₁₂(S-Adm)₄₀]³⁺ (X = Cl, Br, I) Nanoclusters: Models for Multiple-Twinned Nanoparticles". Journal of the American Chemical Society. 139 (38): 13288–13291. doi:10.1021/jacs.7b07926. PMID 28892364.
[Ag₁₄₁Br₁₂(S-Adm)₄₀]³⁺	Ren, Liting; Yuan, Peng; Su, Haifeng; Malola, Sami; Lin, Shuichao; Tang, Zichao; Teo, Boon K.; Häkkinen, Hannu; Zheng, Lansun; Zheng, Nanfeng (2017). "Bulky Surface Ligands Promote Surface Reactivities of [Ag₁₄₁X₁₂(S-Adm)₄₀]³⁺ (X = Cl, Br, I) Nanoclusters: Models for Multiple-Twinned Nanoparticles". Journal of the American Chemical Society. 139 (38): 13288–13291. doi:10.1021/jacs.7b07926. PMID 28892364.
Ag₁₈₈S₉₄(P(C₃H₇)₃)₃₀	Wang, Xiu-Jian; Langetepe, Timo; Persau, Claudia; Kang, Bei-Sheng; Sheldrick, George M.; Fenske, Dieter (2002). "Syntheses and Crystal Structures of the New Ag–S Clusters [Ag70S16(SPH)34(PhCO2)4(triphos)4] and [Ag188S94(PR3)30]". Angewandte Chemie International Edition. 41 (20): 3818–3822. doi:10.1002/1521-3773(20021018)41:20<3818::AID-ANIE3818>3.0.CO;2-R. PMID 12386858.
Ag₂₁₀(SPhⁱPr)₇₁(PPh₃)₅Cl	Liu, Jun-Yan; Alkan, Fahri; Wang, Zhi; Zhang, Zhen-Yi; Kurmoo, Mohamedally; Yan, Zier; Zhao, Quan-Qin; Aikens, Christine M.; Tung, Chen-Ho; Sun, Di (2019). "Different Silver Nanoparticles in One Crystal: Ag₂₁₀(ⁱPRPHS)₇₁(Ph₃P)₅Cl and Ag₂₁₁(ⁱPRPHS)₇₁(Ph₃P)₆Cl". Angewandte Chemie International Edition. 58 (1): 195–199. doi:10.1002/anie.201810772. PMID 30411441.
Ag₂₁₁(SPhⁱPr)₇₁(PPh₃)₆Cl	Liu, Jun-Yan; Alkan, Fahri; Wang, Zhi; Zhang, Zhen-Yi; Kurmoo, Mohamedally; Yan, Zier; Zhao, Quan-Qin; Aikens, Christine M.; Tung, Chen-Ho; Sun, Di (2019). "Different Silver Nanoparticles in One Crystal: Ag₂₁₀(ⁱPRPHS)₇₁(Ph₃P)₅Cl and Ag₂₁₁(ⁱPRPHS)₇₁(Ph₃P)₆Cl". Angewandte Chemie International Edition. 58 (1): 195–199. doi:10.1002/anie.201810772. PMID 30411441.
Ag₃₄₄S₁₂₄(S^tBu)₉₆	Fenske, Dieter; Anson, Christopher E.; Eichhöfer, Andreas; Fuhr, Olaf; Ingendoh, Arnd; Persau, Claudia; Richert, Clemens (2005). "Syntheses and Crystal Structures of [Ag₁₂₃S₃₅(S t Bu)₅₀] and [Ag₃₄₄S₁₂₄(S t Bu)₉₆]". Angewandte Chemie International Edition. 44 (33): 5242–5246. doi:10.1002/anie.200501414. PMID 16052644.
[Ag₃₇₄(SPh-^tBu)₁₁₃Br₂Cl₂]^-	Yang, Huayan; Wang, Yu; Chen, Xi; Zhao, Xiaojing; Gu, Lin; Huang, Huaqi; Yan, Juanzhu; Xu, Chaofa; Li, Gang; Wu, Junchao; Edwards, Alison J.; Dittrich, Birger; Tang, Zichao; Wang, Dongdong; Lehtovaara, Lauri; Häkkinen, Hannu; Zheng, Nanfeng (2016). "Plasmonic twinned silver nanoparticles with molecular precision". Nature Communications. 7: 12809. Bibcode:2016NatCo...712809Y. doi:10.1038/ncomms12809. PMC 5023969. PMID 27611564.

Copper

Table of the crystal structures of copper MPCs.
Formula	References
[(Me₃-tach)₃Cu₆-(μ₆-H)Cl₄]²⁺	Köhn, Randolf D.; Pan, Zhida; Mahon, Mary F.; Kociok-Köhn, Gabriele (2003). "Trimethyltriazacyclohexane as bridging ligand for triangular Cu₃units and C–H hydride abstraction into a Cu₆cluster". Chem. Commun. (11): 1272–1273. doi:10.1039/B302670A. PMID 12809226.
[Cu₇(H){S₂C(aza-15-crown-5)}₆]⁺	Liao, Ping-Kuei; Fang, Ching-Shiang; Edwards, Alison J.; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2012). "Hydrido Copper Clusters Supported by Dithiocarbamates: Oxidative Hydride Removal and Neutron Diffraction Analysis of [Cu₇(H){S₂C(aza-15-crown-5)}₆]". Inorganic Chemistry. 51 (12): 6577–6591. doi:10.1021/ic300135w. PMID 22663192.
[Cu₇(H)S(C₅H₉)₇(PPh₃)₃]	Biswass, Sourav; Pal, Amit; Jena, Milan Kumar; Hossain, Sakiat; Jin, Sakai; Das, Saikat; Sahoo, Basudev; Pathak, Biswarup; Negishi, Yuichi (2024). "Luminescent Hydride-Free [Cu₇(H)S(C₅H₉)₇(PPh₃)₃] Nanocluster: Facilitating Highly Selective C–C Bond Formation". Journal of the American Chemical Society. 146 (30): 20937–20944. doi:10.1021/jacs.4c05678.
[Cu₈(H){S₂(NEt₂)}₆]⁺	Liao, Ping-Kuei; Fang, Ching-Shiang; Edwards, Alison J.; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2012). "Hydrido Copper Clusters Supported by Dithiocarbamates: Oxidative Hydride Removal and Neutron Diffraction Analysis of [Cu₇(H){S₂C(aza-15-crown-5)}₆]". Inorganic Chemistry. 51 (12): 6577–6591. doi:10.1021/ic300135w. PMID 22663192.
[Cu₈(H){S₂(NⁿPr₂)}₆]⁺	Liao, Ping-Kuei; Fang, Ching-Shiang; Edwards, Alison J.; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2012). "Hydrido Copper Clusters Supported by Dithiocarbamates: Oxidative Hydride Removal and Neutron Diffraction Analysis of [Cu₇(H){S₂C(aza-15-crown-5)}₆]". Inorganic Chemistry. 51 (12): 6577–6591. doi:10.1021/ic300135w. PMID 22663192.
Cu₁₁H₃(Tf-dpf)₆(OAc)₂	Liu, Chun-Yu; Yuan, Shang-Fu; Wang, Song; Guan, Zong-Jie; Jiang, De-en; Wang, Quan-Ming (2022). "Structural transformation and catalytic hydrogenation activity of amidinate-protected copper hydride clusters". Nature Communications. 13 (1): 2082. Bibcode:2022NatCo..13.2082L. doi:10.1038/s41467-022-29819-y. PMC 9018778. PMID 35440582.
Cu₁₂S₆(dppo)₄	Yang, Xiao-Xun; Issac, Ibrahim; Lebedkin, Sergej; Kühn, Michael; Weigend, Florian; Fenske, Dieter; Fuhr, Olaf; Eichhöfer, Andreas (2014). "Red-luminescent biphosphine stabilized 'Cu₁₂S₆' cluster molecules". Chemical Communications. 50 (75): 11043–11045. doi:10.1039/C4CC04702H. PMID 25098944.
[Cu₁₂H₃(Tf-dpf)₆(OAc)₂]⁺	Liu, Chun-Yu; Yuan, Shang-Fu; Wang, Song; Guan, Zong-Jie; Jiang, De-en; Wang, Quan-Ming (2022). "Structural transformation and catalytic hydrogenation activity of amidinate-protected copper hydride clusters". Nature Communications. 13 (1): 2082. Bibcode:2022NatCo..13.2082L. doi:10.1038/s41467-022-29819-y. PMC 9018778. PMID 35440582.
[Cu₁₃(S₂CNⁿBu₂)₆(CC(C(O)OCH₃))₄]⁺	Chakrahari, Kiran Kumarvarma; Liao, Jian-Hong; Kahlal, Samia; Liu, Yu-Chiao; Chiang, Ming-Hsi; Saillard, Jean-Yves; Liu, C. W. (2016). "[Cu₁₃{S₂CNⁿBu₂}₆(acetylide)₄]⁺: A Two-Electron Superatom" (PDF). Angewandte Chemie International Edition. 55 (47): 14704–14708. doi:10.1002/anie.201608609. PMID 27781357.
[Cu₁₃(S₂CNⁿBu₂)₆(CC(C₆H₄F))₄]⁺	Chakrahari, Kiran Kumarvarma; Liao, Jian-Hong; Kahlal, Samia; Liu, Yu-Chiao; Chiang, Ming-Hsi; Saillard, Jean-Yves; Liu, C. W. (2016). "[Cu₁₃{S₂CNⁿBu₂}₆(acetylide)₄]⁺: A Two-Electron Superatom" (PDF). Angewandte Chemie International Edition. 55 (47): 14704–14708. doi:10.1002/anie.201608609. PMID 27781357.
[Cu₁₄H₁₂(phen)₆(PPh₃)₄]²⁺	Nguyen, Thuy-Ai D.; Goldsmith, Bryan R.; Zaman, Homaira T.; Wu, Guang; Peters, Baron; Hayton, Trevor W. (2015). "Synthesis and Characterization of a Cu₁₄ Hydride Cluster Supported by Neutral Donor Ligands". Chemistry – A European Journal. 21 (14): 5341–5344. doi:10.1002/chem.201500422. PMID 25702682.
[Cu₁₇(^tBuCC)₁₆(MeOH)]⁺	Zhang, Li-Min; Mak, Thomas C. W. (2016). "Comproportionation Synthesis of Copper(I) Alkynyl Complexes Encapsulating Polyoxomolybdate Templates: Bowl-Shaped Cu₃₃ and Peanut-Shaped Cu₆₂ Nanoclusters". Journal of the American Chemical Society. 138 (9): 2909–2912. doi:10.1021/jacs.5b12103. PMID 26899875.
[Cu₁₈(^tBuCC)₁₆(H₂O)₂]²⁺	Zhang, Li-Min; Mak, Thomas C. W. (2016). "Comproportionation Synthesis of Copper(I) Alkynyl Complexes Encapsulating Polyoxomolybdate Templates: Bowl-Shaped Cu₃₃ and Peanut-Shaped Cu₆₂ Nanoclusters". Journal of the American Chemical Society. 138 (9): 2909–2912. doi:10.1021/jacs.5b12103. PMID 26899875.
Cu₁₈H₇(S(C₆H₄)PPh₂)₁₀I	Huertos, Miguel A.; Cano, Israel; Bandeira, Nuno A. G.; Benet-Buchholz, Jordi; Bo, Carles; Van Leeuwen, Piet W. N. M. (2014). "Phosphinothiolates as Ligands for Polyhydrido Copper Nanoclusters". Chemistry – A European Journal. 20 (49): 16121–16127. doi:10.1002/chem.201404763. PMID 25284300.
[Cu₁₈H₁₇(PPh₃)₁₀]⁺	Nguyen, Thuy-Ai D.; Jones, Zachary R.; Goldsmith, Bryan R.; Buratto, William R.; Wu, Guang; Scott, Susannah L.; Hayton, Trevor W. (2015). "A Cu₂₅ Nanocluster with Partial Cu(0) Character". Journal of the American Chemical Society. 137 (41): 13319–13324. doi:10.1021/jacs.5b07574. PMID 26422670.
Cu₂₀(H)₁₁(S₂P(OⁱPr)₂)₉	Dhayal, Rajendra S.; Liao, Jian-Hong; Lin, Yan-Ru; Liao, Ping-Kuei; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2013). "A Nanospheric Polyhydrido Copper Cluster of Elongated Triangular Orthobicupola Array: Liberation of H₂ from Solar Energy". Journal of the American Chemical Society. 135 (12): 4704–4707. doi:10.1021/ja401576s. PMID 23472670.
Cu₂₃(^tBuCC)₁₃(CF₃COO)₆	Han, Bao-Liang; Liu, Zhen; Feng, Lei; Wang, Zhi; Gupta, Rakesh Kumar; Aikens, Christine M.; Tung, Chen-Ho; Sun, Di (2020). "Polymorphism in Atomically Precise Cu₂₃ Nanocluster Incorporating Tetrahedral [Cu₄]⁰ Kernel". Journal of the American Chemical Society. 142 (12): 5834–5841. doi:10.1021/jacs.0c01053. PMID 32126754.
[Cu₂₃(^tBuCC)₁₃(CF₃COO)₆]·CHCl₃	Han, Bao-Liang; Liu, Zhen; Feng, Lei; Wang, Zhi; Gupta, Rakesh Kumar; Aikens, Christine M.; Tung, Chen-Ho; Sun, Di (2020). "Polymorphism in Atomically Precise Cu₂₃ Nanocluster Incorporating Tetrahedral [Cu₄]⁰ Kernel". Journal of the American Chemical Society. 142 (12): 5834–5841. doi:10.1021/jacs.0c01053. PMID 32126754.
[Cu₂₅H₂₂(PPh₃)₁₂]⁺	Nguyen, Thuy-Ai D.; Jones, Zachary R.; Goldsmith, Bryan R.; Buratto, William R.; Wu, Guang; Scott, Susannah L.; Hayton, Trevor W. (2015). "A Cu₂₅ Nanocluster with Partial Cu(0) Character". Journal of the American Chemical Society. 137 (41): 13319–13324. doi:10.1021/jacs.5b07574. PMID 26422670.
[Cu₂₅H₁₀(SPhCl₂)₁₈]^3–	Sun, Cunfa; Mammen, Nisha; Kaappa, Sami; Yuan, Peng; Deng, Guocheng; Zhao, Chaowei; Yan, Juanzhu; Malola, Sami; Honkala, Karoliina; Häkkinen, Hannu; Teo, Boon K.; Zheng, Nanfeng (2019). "Atomically Precise, Thiolated Copper–Hydride Nanoclusters as Single-Site Hydrogenation Catalysts for Ketones in Mild Conditions". ACS Nano. 13 (5): 5975–5986. doi:10.1021/acsnano.9b02052. PMC 6750866. PMID 31067029.
[Cu₂₈(H)₁₅15(S₂CNR)₁₂]⁺	Edwards, Alison J.; Dhayal, Rajendra S.; Liao, Ping-Kuei; Liao, Jian-Hong; Chiang, Ming-Hsi; Piltz, Ross O.; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2014). "Chinese Puzzle Molecule: A 15 Hydride, 28 Copper Atom Nanoball". Angewandte Chemie International Edition. 53 (28): 7214–7218. doi:10.1002/anie.201403324. PMID 24803070.
[Cu₂₈H₂₀(S₂P(OiPr)₂)₉]^-	Liu, Xianhu; Shen, Hui; Gao, Yang; Deng, Guocheng; Deng, Hongwen; Han, Ying-Zi; Teo, Boon K.; Zheng, Nanfeng (2022). "Cu₂₈H₂₀: A peculiar chiral nanocluster with an exposed Cu atom and 13 surface hydrides". Chemical Communications. 58 (55): 7670–7673. doi:10.1039/D1CC06415K. PMID 35727172.
[Cu₂₉Cl₄H₂₂(Ph₂phen)₁₂]+	Nguyen, Thuy-Ai D.; Jones, Zachary R.; Leto, Domenick F.; Wu, Guang; Scott, Susannah L.; Hayton, Trevor W. (2016). "Ligand-Exchange-Induced Growth of an Atomically Precise Cu₂₉ Nanocluster from a Smaller Cluster". Chemistry of Materials. 28 (22): 8385–8390. doi:10.1021/acs.chemmater.6b03879.
Cu₃₂(H)₂₀(S₂P(OⁱPr)₂)₁₂	Dhayal, Rajendra S.; Liao, Jian-Hong; Kahlal, Samia; Wang, Xiaoping; Liu, Yu-Chiao; Chiang, Ming-Hsi; Van Zyl, Werner E.; Saillard, Jean-Yves; Liu, C. W. (2015). "[Cu₃₂(H)₂₀{S₂P(O i Pr)₂}₁₂]: The Largest Number of Hydrides Recorded in a Molecular Nanocluster by Neutron Diffraction". Chemistry – A European Journal. 21 (23): 8369–8374. doi:10.1002/chem.201501122. OSTI 1261439. PMID 25899822.
[Cu₃₂(PET)₂₄H₈Cl₂]^2-	Lee, Sanghwa; Bootharaju, Megalamane S.; Deng, Guocheng; Malola, Sami; Baek, Woonhyuk; Häkkinen, Hannu; Zheng, Nanfeng; Hyeon, Taeghwan (2020). "[Cu₃₂(PET)₂₄H₈Cl₂](PPH₄)₂: A Copper Hydride Nanocluster with a Bisquare Antiprismatic Core". Journal of the American Chemical Society. 142 (32): 13974–13981. doi:10.1021/jacs.0c06577. PMID 32672452.
[Cu₃₃(^tBuCC)₂₄(Mo₄O₁₆)]⁺	Zhang, Li-Min; Mak, Thomas C. W. (2016). "Comproportionation Synthesis of Copper(I) Alkynyl Complexes Encapsulating Polyoxomolybdate Templates: Bowl-Shaped Cu₃₃ and Peanut-Shaped Cu₆₂ Nanoclusters". Journal of the American Chemical Society. 138 (9): 2909–2912. doi:10.1021/jacs.5b12103. PMID 26899875.
[Cu₄₈S₂₀(O^tBu)₂(Ph₂PS₂)₂(dppm⁻)₄(dppm)₄]	Shafaei-Fallah, Maryam; Anson, Christopher E.; Fenske, Dieter; Rothenberger, Alexander (2005). "Functionalised trimethylsilyl reagents in cluster synthesis: Reactions of Ph2P(S)SSiMe3 with group 11 salts". Dalton Transactions (13): 2300–2304. doi:10.1039/B501360G. PMID 15962051.
[Cu₅₃(COOCF₃)₁₀(CC^tBu)₂₀Cl₂H₁₈]⁺	Yuan, Peng; Chen, Ruihao; Zhang, Xiaomin; Chen, Fengjiao; Yan, Juanzhu; Sun, Cunfa; Ou, Daohui; Peng, Jian; Lin, Shuichao; Tang, Zichao; Teo, Boon K.; Zheng, Lan-Sun; Zheng, Nanfeng (2019). "Ether-Soluble Cu₅₃ Nanoclusters as an Effective Precursor of High-Quality CuI Films for Optoelectronic Applications". Angewandte Chemie International Edition. 58 (3): 835–839. doi:10.1002/anie.201812236. PMID 30406951.
[Cu₆₂(^tBuCC)₁₆(Mo₅O₁₉)₂(MoO₄)₂(OTf)₂(OH)₄]²⁺	Zhang, Li-Min; Mak, Thomas C. W. (2016). "Comproportionation Synthesis of Copper(I) Alkynyl Complexes Encapsulating Polyoxomolybdate Templates: Bowl-Shaped Cu₃₃ and Peanut-Shaped Cu₆₂ Nanoclusters". Journal of the American Chemical Society. 138 (9): 2909–2912. doi:10.1021/jacs.5b12103. PMID 26899875.

Aluminium

Table of the crystal structures of aluminum MPCs.
Formula	References
{Al(μ⁵-C₅Me₅)}₄	Dohmeier, Carsten; Robl, Christian; Tacke, Matthias; Schnöckel, Hansgeorg (1991). "The Tetrameric Aluminum(<SCP>I</SCP>) Compound [{Al(η⁵-C₅Me₅)}₄]". Angewandte Chemie International Edition in English. 30 (5): 564–565. doi:10.1002/anie.199105641.
Al₄[Si(^tBu)₃]₄	Purath, Andreas; Dohmeier, Carsten; Ecker, Achim; Schnöckel, Hansgeorg; Amelunxen, Kerstin; Passler, Thomas; Wiberg, Nils (1998). "Synthesis and Crystal Structure of the Tetraaluminatetrahedrane Al₄[Si( t -Bu)₃]₄, the Second Al₄R₄ Compound". Organometallics. 17 (9): 1894–1896. doi:10.1021/om971015h.
[Al₇{N(SiMe₃)₂}₆]^-	Purath, Andreas; Köppe, Ralf; Schnöckel, Hansgeorg (1999). "[Al7{N(SiMe3)2}6]−: A First Step towards Aluminum Metal Formation by Disproportionation". Angewandte Chemie International Edition. 38 (19): 2926–2928. doi:10.1002/(SICI)1521-3773(19991004)38:19<2926::AID-ANIE2926>3.0.CO;2-B. PMID 10540395.
[Al₁₂(^tBu)₁₂]^2-	Klinkhammer, Karl-Wilhelm; Uhl, Werner; Wagner, Jürgen; Hiller, Wolfgang (1991). "K₂[Al₁₂ i Bu₁₂], a Compound with Al₁₂ Icosahedra". Angewandte Chemie International Edition in English. 30 (2): 179–180. doi:10.1002/anie.199101791.
[Al₁₂(N(SiMe₃)₂)₁₈]^1-	Purath, Andreas; Köppe, Ralf; Schnöckel, Hansgeorg (1999). "An Al12R8− cluster as an intermediate on the way from aluminium(I) compounds to aluminium metal†". Chemical Communications (19): 1933–1934. doi:10.1039/A904247D.
[Al₁₄{N(SiMe₃)₂}₆I₆]²⁻	Köhnlein, Harald; Stösser, Gregor; Baum, Elke; Möllhausen, Evelyn; Huniar, Uwe; Schnöckel, Hansgeorg (2000). "A Metalloid Al14 Cluster with the Structure of a "Nano-Wheel"". Angewandte Chemie International Edition. 39 (4): 799–801. doi:10.1002/(SICI)1521-3773(20000218)39:4<799::AID-ANIE799>3.0.CO;2-B. PMID 10760874.
Al₂₂Cl₂₀(THF)₁₂	Klemp, Christoph; Bruns, Michael; Gauss, Jürgen; Häussermann, Ulrich; Stösser, Gregor; Van Wüllen, Leo; Jansen, Martin; Schnöckel, Hansgeorg (2001). "Al₂₂Cl₂₀·12L (L = THF, THP): The First Polyhedral Aluminum Chlorides". Journal of the American Chemical Society. 123 (37): 9099–9106. doi:10.1021/ja004022x. PMID 11552817.
Al₂₂Cl₂₀(THP)₁₂	Klemp, Christoph; Bruns, Michael; Gauss, Jürgen; Häussermann, Ulrich; Stösser, Gregor; Van Wüllen, Leo; Jansen, Martin; Schnöckel, Hansgeorg (2001). "Al₂₂Cl₂₀·12L (L = THF, THP): The First Polyhedral Aluminum Chlorides". Journal of the American Chemical Society. 123 (37): 9099–9106. doi:10.1021/ja004022x. PMID 11552817.
Al₅₀(C₅Me₅)₁₂	Vollet, Jean; Hartig, Jens R.; Schnöckel, Hansgeorg (2004). "Al₅₀C₁₂₀H₁₈₀: A Pseudofullerene Shell of 60 Carbon Atoms and 60 Methyl Groups Protecting a Cluster Core of 50 Aluminum Atoms". Angewandte Chemie International Edition. 43 (24): 3186–3189. doi:10.1002/anie.200453754. PMID 15199573.
[Al₆₉{N(SiMe₃)₂}₁₈]^3-	Köhnlein, H.; Purath, A.; Klemp, C.; Baum, E.; Krossing, I.; Stösser, G.; Schnöckel, H. (2001). "Synthesis and Characterization of an Al₆₉^3- Cluster with 51 Naked al Atoms: Analogies and Differences to the Previously Characterized Al₇₇^2- Cluster". Inorganic Chemistry. 40 (19): 4830–4838. doi:10.1021/ic0104297. PMID 11531428.
[Al₇₇(N(SiMe₃)₂)₂₀]^2-	Ecker, A.; Weckert, E.; Schnöckel, H. (1997). "Synthesis and structural characterization of an AI77 cluster". Nature. 387 (6631): 379–381. doi:10.1038/387379a0.

Gallium

Table of the crystal structures of gallium MPCs.
Formula	References
Ga₄(Si(SiMe₃)₃)₄	Linti, Gerald (1996). "Zur chemie des galliums, 61: Tris(trimethylsilyl) silylgallium(I) —eine experimentelle und theoretische studie". Journal of Organometallic Chemistry. 520 (1–2): 107–113. doi:10.1016/0022-328X(96)06317-6.
Ga₈(C(SiMe₃)₃)₆	Schnepf, Andreas; Köppe, Ralf; Schnöckel, Hansgeorg (2001). "A Ga8R6 Cluster as an Ideal Model for a Metal-Metal Bond?". Angewandte Chemie International Edition. 40 (7): 1241–1243. doi:10.1002/1521-3773(20010401)40:7<1241::AID-ANIE1241>3.0.CO;2-J. PMID 11301437.
Ga₉(^tBu)₉	Uhl, Werner; Cuypers, Lars; Harms, Klaus; Kaim, Wolfgang; Wanner, Matthias; Winter, Rainer; Koch, Rainer; Saak, Wolfgang (2001). "Ga9(CMe3)9, an Important New Building Block in the Structural Chemistry of the Alkylelement(I) Compounds EnRn (E=B-In)". Angewandte Chemie International Edition. 40 (3): 566–568. doi:10.1002/1521-3773(20010202)40:3<566::AID-ANIE566>3.0.CO;2-T.
Ga₁₀[Si(SiMe₃)₃]₆	Kehrwald, Michael; Köstler, Wolfgang; Rodig, Alexander; Linti, Gerald; Blank, Thomas; Wiberg, Nils (2001). "Ga₁₀[Si(SiMe₃)₃]₆, [Ga₁₀(Si t Bu₃)₆]^-, and [Ga₁₃(Si t Bu₃)₆]^-Syntheses and Structural Characterization of Novel Gallium Cluster Compounds". Organometallics. 20 (5): 860–867. doi:10.1021/om000703p.
[Ga₁₀(Si^tBu₃)₆]^-	Kehrwald, Michael; Köstler, Wolfgang; Rodig, Alexander; Linti, Gerald; Blank, Thomas; Wiberg, Nils (2001). "Ga₁₀[Si(SiMe₃)₃]₆, [Ga₁₀(Si t Bu₃)₆]^-, and [Ga₁₃(Si t Bu₃)₆]^-Syntheses and Structural Characterization of Novel Gallium Cluster Compounds". Organometallics. 20 (5): 860–867. doi:10.1021/om000703p.
[Ga₁₂(C₁₃H₉)₁₀]²⁻	Schnepf, Andreas; Stößer, Gregor; Köppe, Ralf; Schnöckel, Hansgeorg (2000). "[Li(THF)4]2+[Ga12(C13H9)10]2−: The First Molecular Compound with an Icosahedral Ga12 Framework". Angewandte Chemie International Edition. 39 (9): 1637–1639. doi:10.1002/(SICI)1521-3773(20000502)39:9<1637::AID-ANIE1637>3.0.CO;2-O. PMID 10820460.
[Ga₁₈(Si^tBu₃)8]	Donchev, Alexander; Schnepf, Andreas; Stößer, Gregor; Baum, Elke; Schnöckel, Hansgeorg; Blank, Thomas; Wiberg, Nils (2001). "[Ga18(SitBu3)8] and [Ga22(SitBu3)8]—Syntheses and Structural Characterization of Novel Gallium Cluster Compounds". Chemistry - A European Journal. 7 (15): 3348–3353. doi:10.1002/1521-3765(20010803)7:15<3348::AID-CHEM3348>3.0.CO;2-8. PMID 11531121.
[Ga₁₉(C(SiMe₃)₃)₆]^-	Schnepf, A.; Stösser, G.; Schnöckel, H. (2000). "Synthesis, Structure, and Bonding of a Molecular Metalloid Ga₁₉ Cluster Anion". Journal of the American Chemical Society. 122 (38): 9178–9181. doi:10.1021/ja000990o.
[Ga₂₂(Si^tBu₃)8]	Donchev, Alexander; Schnepf, Andreas; Stößer, Gregor; Baum, Elke; Schnöckel, Hansgeorg; Blank, Thomas; Wiberg, Nils (2001). "[Ga18(SitBu3)8] and [Ga22(SitBu3)8]—Syntheses and Structural Characterization of Novel Gallium Cluster Compounds". Chemistry - A European Journal. 7 (15): 3348–3353. doi:10.1002/1521-3765(20010803)7:15<3348::AID-CHEM3348>3.0.CO;2-8. PMID 11531121.
[Ga₂₂{N(SiMe₃)₂}₁₀]²⁻	Schnepf, Andreas; Stößer, Gregor; Schnöckel, Hansgeorg (2002). "[Ga22{N(SiMe3)2}10]2−: A Metalloid Cluster Compound with a Variation of the Ga22 Framework This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemische Industrie". Angewandte Chemie International Edition. 41 (11): 1882. doi:10.1002/1521-3773(20020603)41:11<1882::AID-ANIE1882>3.0.CO;2-N.
Ga₂₃{N(SiMe₃)₂}₁₁	Hartig, Jens; Stößer, Anna; Hauser, Petra; Schnöckel, Hansgeorg (2007). "A Metalloid [Ga₂₃{N(SiMe₃)₂}₁₁] Cluster: The Jellium Model Put to Test". Angewandte Chemie International Edition. 46 (10): 1658–1662. doi:10.1002/anie.200604311. PMID 17230594.
[Ga₂₆(Si(SiMe₃)₃)₈]^-	Rodig, Alexander; Linti, Gerald (2000). "Synthesis and Structure of an Anionic Ga26R8 Cluster with a Metalloid Core". Angewandte Chemie. 39 (16): 2952–2954. Bibcode:2000AngCh..39.2952R. doi:10.1002/1521-3773(20000818)39:16<2952::AID-ANIE2952>3.0.CO;2-M. PMID 11028022.
[Ga₈₄{N(SiMe₃)₂}₂₀]⁴⁻	Schnepf, Andreas; Schnöckel, Hansgeorg (2001). "Synthesis and Structure of a Ga84R204− Cluster-A Link between Metalloid Clusters and Fullerenes?". Angewandte Chemie International Edition. 40 (4): 711–715. doi:10.1002/1521-3773(20010216)40:4<711::AID-ANIE7110>3.0.CO;2-K. PMID 11241599.

Germanium

Table of the crystal structures of germanium MPCs.
Formula	References
[Ge₉{Si(SiMe₃)₃}₃]⁻	Schnepf, Andreas (2003). "[Ge₉{Si(SiMe₃)₃}₃]⁻: A Soluble Polyhedral Ge₉ Cluster Stabilized by Only Three Silyl Ligands". Angewandte Chemie International Edition. 42 (23): 2624–2625. doi:10.1002/anie.200250683. PMID 12813736.
ZnGe₁₈{Si(SiMe₃)₃}₄{Ge(SiMe₃)₃}₂	Kysliak, Oleksandr; Schnepf, Andreas (2019). "[Ge₉{Si(SiMe₃)₃}₂{Ge(SiMe₃)₃}]^–: The Mixed Substituted Metalloid Germanium Cluster and the Intermetalloid Cluster [ZnGe₁₈{Si(SiMe₃)₃}₄{Ge(SiMe₃)₃}₂]". Zeitschrift für Anorganische und Allgemeine Chemie. 645 (3): 335–339. doi:10.1002/zaac.201800296.
[Ge₉(Si(SiMe₃)₂(SiPh₃))₂]^–	Kysliak, Oleksandr; Kunz, Tanja; Schnepf, Andreas (2017). "Metalloid Ge₉R₃^– Clusters with Various Silyl Substituents: From Shielded to Open Cluster Cores". European Journal of Inorganic Chemistry. 2017 (4): 805–810. doi:10.1002/ejic.201601134.
[Ge₉(Si(SiMe₃)₃)(Si(SiMe₃)₂(SiPh₃))₂]^–	Kysliak, Oleksandr; Kunz, Tanja; Schnepf, Andreas (2017). "Metalloid Ge₉R₃^– Clusters with Various Silyl Substituents: From Shielded to Open Cluster Cores". European Journal of Inorganic Chemistry. 2017 (4): 805–810. doi:10.1002/ejic.201601134.
[Ge₉(Si(SiMe₃)₂(SiiPr₃))₃]^–	Kysliak, Oleksandr; Kunz, Tanja; Schnepf, Andreas (2017). "Metalloid Ge₉R₃^– Clusters with Various Silyl Substituents: From Shielded to Open Cluster Cores". European Journal of Inorganic Chemistry. 2017 (4): 805–810. doi:10.1002/ejic.201601134.
[Ge₉(SiH^tBu₂)₃]^–	Kysliak, Oleksandr; Kunz, Tanja; Schnepf, Andreas (2017). "Metalloid Ge₉R₃^– Clusters with Various Silyl Substituents: From Shielded to Open Cluster Cores". European Journal of Inorganic Chemistry. 2017 (4): 805–810. doi:10.1002/ejic.201601134.
(Ge₉{Si(TMS)₃}₂)(P^tBu₂CuNHC^Mes)	Geitner, Felix S.; Wallach, Christoph; Fässler, Thomas F. (2018). "On the Variable Reactivity of Phosphine-Functionalized [Ge₉] Clusters: Zintl Cluster-Substituted Phosphines or Phosphine-Substituted Zintl Clusters". Chemistry – A European Journal. 24 (16): 4103–4110. doi:10.1002/chem.201705678. PMID 29322565.
NHC^DippCu[η³-(Ge₉{Si(TMS)₃}₂)(PMes₂)]	Geitner, Felix S.; Wallach, Christoph; Fässler, Thomas F. (2018). "On the Variable Reactivity of Phosphine-Functionalized [Ge₉] Clusters: Zintl Cluster-Substituted Phosphines or Phosphine-Substituted Zintl Clusters". Chemistry – A European Journal. 24 (16): 4103–4110. doi:10.1002/chem.201705678. PMID 29322565.
[(Ge₉{Si(TMS)₃}₂)(^tBu₂PCu)Ge₉(Si(TMS)₃)₂]	Geitner, Felix S.; Wallach, Christoph; Fässler, Thomas F. (2018). "On the Variable Reactivity of Phosphine-Functionalized [Ge₉] Clusters: Zintl Cluster-Substituted Phosphines or Phosphine-Substituted Zintl Clusters". Chemistry – A European Journal. 24 (16): 4103–4110. doi:10.1002/chem.201705678. PMID 29322565.
Ge₁₈[Si(SiMe₃)₃]₆	Kysliak, Oleksandr; Schrenk, Claudio; Schnepf, Andreas (2016). "The Largest Metalloid Group 14 Cluster, Ge₁₈[Si(SiMe₃)₃]₆: An Intermediate on the Way to Elemental Germanium". Angewandte Chemie International Edition. 55 (9): 3216–3219. doi:10.1002/anie.201510831. PMID 26822765.

Palladium

Table of the crystal structures of palladium MPCs.
Formula	References
[Pd₁₀(μ-CO)₈(μ₃-CO)₄(PEt₃)₆]	D. Michael P. Mingos and Christopher M. Hill. Synthesis and Characterisation of [Pd₁₀(μ-CO)(μ₃-CO)₄(PEt₃)₆] and [Pd₁₀(μ-CO)6(μ₃-CO)₂(μ-CNXylyl)₂(PEt₃)₆]. Croat. Chem. Acta 1995, 68, 4, 745-767^[7]
[Pd₁₀(μ-CO)6(μ₃-CO)₂(μ-CNXylyl)₂(PEt₃)₆]	D. Michael P. Mingos and Christopher M. Hill. Synthesis and Characterisation of [Pd₁₀(μ-CO)(μ₃-CO)₄(PEt₃)₆] and [Pd₁₀(μ-CO)6(μ₃-CO)₂(μ-CNXylyl)₂(PEt₃)₆]. Croat. Chem. Acta 1995, 68, 4, 745-767^[7]
Pd₁₀(CO)₁₄(PBuⁿ₃)₄	Mednikov, E.G.; Eremenko, N.K.; Slovokhotov, Yu.L.; Struchkov, Yu.T.; Gubin, S.P. (1983). "Synthesis and x-ray structure of 10-vertex palladium carbonylphosphine cluster with minimal PBun3 content". Journal of Organometallic Chemistry. 258 (2): 247–255. doi:10.1016/S0022-328X(00)99262-3.
Pd₁₂(CO)₁₂(PBuⁿ₃)₆	Mednikov, E.G; Struchkov, Yu.T; Slovokhotov, Yu.L (1998). "Synthesis and X-ray structure of a novel 12-nuclear cluster Pd12(CO)12(PBun3)6". Journal of Organometallic Chemistry. 566 (1–2): 15–20. doi:10.1016/S0022-328X(98)00633-0.
Pd₁₂(CO)₁₂(PPh₃)₆	Kawano, Masaki; Bacon, Jeffrey W.; Campana, Charles F.; Winger, Brian E.; Dudek, James D.; Sirchio, Scott A.; Scruggs, Sabrina L.; Geiser, Urs; Dahl, Lawrence F. (2001). "High-Nuclearity Close-Packed Palladium-Nickel Carbonyl Phosphine Clusters: Heteropalladium [Pd₁₆Ni₄(CO)₂₂(PPH₃)₄]^2-and [Pd₃₃Ni₉(CO)₄₁(PPH₃)₆]^4-Containing Pseudo- T _d CCP Pd₁₆Ni₄and Pseudo- D ₃ _h HCP Pd₃₃Ni₉Cores". Inorganic Chemistry. 40 (11): 2554–2569. doi:10.1021/ic000979p. PMID 11350234.
Pd₁₆(CO)₁₃(PMe₃)₉	Tran, Nguyet T.; Kawano, Masaki; Dahl, Lawrence F. (2001). "High-nuclearity palladium carbonyl trimethylphosphine clusters containing unprecedented face-condensed icosahedral-based transition-metal core geometries: Proposed growth patterns from a centered Pd13 icosahedron†". Journal of the Chemical Society, Dalton Transactions (19): 2731–2748. doi:10.1039/B103547A.
[Pd₂₉(CO)₂₈(PPh₃)₇]^2-	Kawano, Masaki; Bacon, Jeffrey W.; Campana, Charles F.; Winger, Brian E.; Dudek, James D.; Sirchio, Scott A.; Scruggs, Sabrina L.; Geiser, Urs; Dahl, Lawrence F. (2001). "High-Nuclearity Close-Packed Palladium-Nickel Carbonyl Phosphine Clusters: Heteropalladium [Pd₁₆Ni₄(CO)₂₂(PPH₃)₄]^2-and [Pd₃₃Ni₉(CO)₄₁(PPH₃)₆]^4-Containing Pseudo- T _d CCP Pd₁₆Ni₄and Pseudo- D ₃ _h HCP Pd₃₃Ni₉Cores". Inorganic Chemistry. 40 (11): 2554–2569. doi:10.1021/ic000979p. PMID 11350234.
Pd₃₀(CO)₂₆(PEt₃)₁₀	Mednikov, Eugeny G.; Ivanov, Sergei A.; Dahl, Lawrence F. (2003). "[Pd₃₀(CO)₂₆(PEt₃)₁₀] and [Pd₅₄(CO)₄₀(PEt₃)₁₄]: Generation of Nanosized Pd₃₀- and Pd₅₄-Core Geometries Containing Interpenetrating Cuboctahedral-Based Metal Polyhedra". Angewandte Chemie International Edition. 42 (3): 323–327. doi:10.1002/anie.200390107. PMID 12548690.
Pd₃₅(CO)₂₃(PMe₃)₁₅	Tran, Nguyet T.; Kawano, Masaki; Dahl, Lawrence F. (2001). "High-nuclearity palladium carbonyl trimethylphosphine clusters containing unprecedented face-condensed icosahedral-based transition-metal core geometries: Proposed growth patterns from a centered Pd13 icosahedron†". Journal of the Chemical Society, Dalton Transactions (19): 2731–2748. doi:10.1039/B103547A.
Pd₃₉(CO)₂₃(PMe₃)₁₆	Tran, Nguyet T.; Kawano, Masaki; Dahl, Lawrence F. (2001). "High-nuclearity palladium carbonyl trimethylphosphine clusters containing unprecedented face-condensed icosahedral-based transition-metal core geometries: Proposed growth patterns from a centered Pd13 icosahedron†". Journal of the Chemical Society, Dalton Transactions (19): 2731–2748. doi:10.1039/B103547A.
Pd₅₄(CO)₄₀(PEt₃)₁₄	Mednikov, Eugeny G.; Ivanov, Sergei A.; Dahl, Lawrence F. (2003). "[Pd₃₀(CO)₂₆(PEt₃)₁₀] and [Pd₅₄(CO)₄₀(PEt₃)₁₄]: Generation of Nanosized Pd₃₀- and Pd₅₄-Core Geometries Containing Interpenetrating Cuboctahedral-Based Metal Polyhedra". Angewandte Chemie International Edition. 42 (3): 323–327. doi:10.1002/anie.200390107. PMID 12548690.
Pd₅₅(PⁱPr₃)₁₂(μ₃-CO)₂₀	Erickson, Jeremiah D.; Mednikov, Evgueni G.; Ivanov, Sergei A.; Dahl, Lawrence F. (2016). "Isolation and Structural Characterization of a Mackay 55-Metal-Atom Two-Shell Icosahedron of Pseudo- I _h Symmetry, Pd₅₅L₁₂(μ₃-CO)₂₀ (L = PR₃, R = Isopropyl): Comparative Analysis with Interior Two-Shell Icosahedral Geometries in Capped Three-Shell Pd₁₄₅, Pt-Centered Four-Shell Pd–Pt M₁₆₅, and Four-Shell Au₁₃₃ Nanoclusters". Journal of the American Chemical Society. 138 (5): 1502–1505. doi:10.1021/jacs.5b13076. PMID 26790717.
Pd₅₉(CO)₃₂(PMe₃)₂₁	Tran, Nguyet T.; Kawano, Masaki; Powell, Douglas R.; Dahl, Lawrence F. (1998). "Pd₅₉(CO)₃₂(PMe₃)₂₁: A Nanosized Metal Cluster Containing a Trigonal D ₃ Pd₅₉ Core with 11 Interior Palladium Atoms". Journal of the American Chemical Society. 120 (42): 10986–10987. doi:10.1021/ja9827346.
Pd₅₉(CO)₃₂(PMe₃)₂₁	Tran, Nguyet T.; Kawano, Masaki; Dahl, Lawrence F. (2001). "High-nuclearity palladium carbonyl trimethylphosphine clusters containing unprecedented face-condensed icosahedral-based transition-metal core geometries: Proposed growth patterns from a centered Pd13 icosahedron†". Journal of the Chemical Society, Dalton Transactions (19): 2731–2748. doi:10.1039/B103547A.
Pd₆₉(CO)₃₆(PEt₃)₁₈	Tran, Nguyet T.; Dahl, Lawrence F. (2003). "Nanosized [Pd₆₉(CO)₃₆(PEt₃)₁₈]: Metal-Core Geometry Containing a Linear Assembly of Three Face-Sharing Centered Pd₃₃ Icosahedra Inside of a Hexagonal-Shaped Pd₃₀ Tube". Angewandte Chemie International Edition. 42 (30): 3533–3537. doi:10.1002/anie.200351738. PMID 12900974.
Pd₁₄₅(CO)₅₁(PEt₃)₃₀	Tran, Nguyet T.; Powell, Douglas R.; Dahl, Lawrence F. (2000). "Nanosized Pd145(CO)x(PEt3)30 Containing a Capped Three-Shell 145-Atom Metal-Core Geometry of Pseudo Icosahedral Symmetry". Angewandte Chemie. 39 (22): 4121–4125. Bibcode:2000AngCh..39.4121T. doi:10.1002/1521-3773(20001117)39:22<4121::AID-ANIE4121>3.0.CO;2-A. PMID 11093227.

Mixed metal

Table of the crystal structures of alloy and doped MPCs.
Formula	References
[Au{Pt₃(μ-CO)₃(PPh₃)₃}₂]⁺	Hallam, Malcolm F.; Mingos, D. Michael P.; Adatia, Trushar; McPartlin, Mary (1988). "Synthesis of Group 1B sandwich cluster compounds with [Pt₃(μ-CO)₃(PPH₃)₃] and the structural characterisation of [M{Pt₃(μ-CO)₃(PPH₃)₃}₂]PF₆(M = Au or Cu) by single-crystal X-ray techniques". J. Chem. Soc., Dalton Trans. (2): 335–340. doi:10.1039/DT9880000335.
[Cu{Pt₃(μ-CO)₃(PPh₃)₃}₂]⁺	Hallam, Malcolm F.; Mingos, D. Michael P.; Adatia, Trushar; McPartlin, Mary (1988). "Synthesis of Group 1B sandwich cluster compounds with [Pt₃(μ-CO)₃(PPH₃)₃] and the structural characterisation of [M{Pt₃(μ-CO)₃(PPH₃)₃}₂]PF₆(M = Au or Cu) by single-crystal X-ray techniques". J. Chem. Soc., Dalton Trans. (2): 335–340. doi:10.1039/DT9880000335.
Au₂Cu₆(SAdm)₆(PPh₃)₂	Kang, Xi; Wang, Shuxin; Song, Yongbo; Jin, Shan; Sun, Guodong; Yu, Haizhu; Zhu, Manzhou (2016). "Bimetallic Au₂Cu₆ Nanoclusters: Strong Luminescence Induced by the Aggregation of Copper(I) Complexes with Gold(0) Species". Angewandte Chemie International Edition. 55 (11): 3611–3614. doi:10.1002/anie.201600241. PMID 26890334.
[Au₄Cu₄(DPPM)₂(SAdm)₅]⁺	Yu, Wei; Hu, Daqiao; Xiong, Lin; Li, Yangfeng; Kang, Xi; Chen, Shuang; Wang, Shuxin; Pei, Yong; Zhu, Manzhou (2019). "Isomer Structural Transformation in Au–Cu Alloy Nanoclusters: Water Ripple-Like Transfer of Thiol Ligands". Particle & Particle Systems Characterization. 36 (5). doi:10.1002/ppsc.201800494.
[Au₄Cu₅(C₆H₁₁S)₆(DPPM)₂]⁺	Zhou, Manman; Jin, Shan; Wei, Xiao; Yuan, Qianqin; Wang, Shuxin; Du, Yuanxin; Zhu, Manzhou (2020). "Reversible Cu–S Motif Transformation and Au₄ Distortion via Thiol Ligand Exchange Engineering". The Journal of Physical Chemistry C. 124 (13): 7531–7538. doi:10.1021/acs.jpcc.0c00204.
Au₅Cu₆(Dppf)₂(SAdm)₆)	Deng, Huijuan; Bai, Yuyuan; Zhou, Manman; Bao, Yizheng; Jin, Shan; Li, Xiaowu; Yu, Haizhu; Zhu, Manzhou (2020). "Structure and Properties of Au₅Cu₆(DPPF)₂(SAdm)₆)(BPH₄)". The Journal of Physical Chemistry C. 124 (39): 21867–21873. doi:10.1021/acs.jpcc.0c06978.
((C₅Me₅)*AlCu)₆H₄	Ganesamoorthy, Chelladurai; Weßing, Jana; Kroll, Clarissa; Seidel, Rüdiger W.; Gemel, Christian; Fischer, Roland A. (2014). "The Intermetalloid Cluster [(CpAlCu)₆H₄], Embedding a Cu₆ Core Inside an Octahedral Al₆ Shell: Molecular Models of Hume–Rothery Nanophases". Angewandte Chemie International Edition*. 53 (30): 7943–7947. doi:10.1002/anie.201402149. PMID 24962074.
((C₅Me₅)*AlCu)₆H₃(N=CHPh)	Ganesamoorthy, Chelladurai; Weßing, Jana; Kroll, Clarissa; Seidel, Rüdiger W.; Gemel, Christian; Fischer, Roland A. (2014). "The Intermetalloid Cluster [(CpAlCu)₆H₄], Embedding a Cu₆ Core Inside an Octahedral Al₆ Shell: Molecular Models of Hume–Rothery Nanophases". Angewandte Chemie International Edition*. 53 (30): 7943–7947. doi:10.1002/anie.201402149. PMID 24962074.
[Ag₁₂Au₁(Pz(CF₃)₂)₆(CCPh)₈)]^-	Zheng, Ji; Wang, Jia-Nan; Wang, Ting; Wu, Kun; Wei, Rong-Jia; Lu, Weigang; Li, Dan (2021). "Phosphorescent Metal Rotaxane-like Bimetallic Ag/Au Clusters". The Journal of Physical Chemistry C. 125 (17): 9400–9410. doi:10.1021/acs.jpcc.1c00621.
[Ag₁₂Au₁(Pz(CF₃)₂)₆(CCPhF)₈)]^-	Zheng, Ji; Wang, Jia-Nan; Wang, Ting; Wu, Kun; Wei, Rong-Jia; Lu, Weigang; Li, Dan (2021). "Phosphorescent Metal Rotaxane-like Bimetallic Ag/Au Clusters". The Journal of Physical Chemistry C. 125 (17): 9400–9410. doi:10.1021/acs.jpcc.1c00621.
[Ag₁₂Au₁(Pz(CF₃)₂)₆(CCPhOMe)₈)]^-	Zheng, Ji; Wang, Jia-Nan; Wang, Ting; Wu, Kun; Wei, Rong-Jia; Lu, Weigang; Li, Dan (2021). "Phosphorescent Metal Rotaxane-like Bimetallic Ag/Au Clusters". The Journal of Physical Chemistry C. 125 (17): 9400–9410. doi:10.1021/acs.jpcc.1c00621.
[Au₁₃Cu₂(PPh₃)₆(SPy)₆)]⁺	Yang, Huayan; Wang, Yu; Lei, Jing; Shi, Lei; Wu, Xiaohu; Mäkinen, Ville; Lin, Shuichao; Tang, Zichao; He, Jian; Häkkinen, Hannu; Zheng, Lansun; Zheng, Nanfeng (2013). "Ligand-Stabilized Au₁₃Cu_x ( x = 2, 4, 8) Bimetallic Nanoclusters: Ligand Engineering to Control the Exposure of Metal Sites". Journal of the American Chemical Society. 135 (26): 9568–9571. doi:10.1021/ja402249s. PMID 23789787.
[Au₇Ag₆Cu₂(SCH₂Ph)₆]⁺	Shen, Hui; Xu, Zhen; Wang, Lingzheng; Han, Ying-Zi; Liu, Xianhu; Malola, Sami; Teo, Boon K.; Häkkinen, Hannu; Zheng, Nanfeng (2021). "Tertiary Chiral Nanostructures from C−H⋅⋅⋅F Directed Assembly of Chiroptical Superatoms". Angewandte Chemie International Edition. 60 (41): 22411–22416. doi:10.1002/anie.202108141. PMID 34347339.
[Au₂Pd₁₄(μ₃-CO)₇(μ₂-CO)₂(PMe₃)₁₁]²⁺	Copley, Royston C. B.; Hill, Christopher M.; Mingos, D. Michael P. (1995). "Synthesis and structural characterization of [Au2Pd14(?3-CO)7(?2-CO)2(PMe3)11](PF6)2?An icosahedrally-based high nuclearity mixed metal cluster". Journal of Cluster Science. 6: 71–91. doi:10.1007/BF01175837.
[Au₁₃Cu₄(PPh₂Py)₄(SC₆H₄-^tBu)₈)]⁺	Yang, Huayan; Wang, Yu; Lei, Jing; Shi, Lei; Wu, Xiaohu; Mäkinen, Ville; Lin, Shuichao; Tang, Zichao; He, Jian; Häkkinen, Hannu; Zheng, Lansun; Zheng, Nanfeng (2013). "Ligand-Stabilized Au₁₃Cu_x ( x = 2, 4, 8) Bimetallic Nanoclusters: Ligand Engineering to Control the Exposure of Metal Sites". Journal of the American Chemical Society. 135 (26): 9568–9571. doi:10.1021/ja402249s. PMID 23789787.
[Au₁₃Cu₄(PPh₂Py)₃(SePh)₉]	Song, Yongbo; Lv, Ying; Zhou, Meng; Luo, Tian-Yi; Zhao, Shuo; Rosi, Nathaniel L.; Yu, Haizhu; Zhu, Manzhou; Jin, Rongchao (2018). "Single-ligand exchange on an Au–Cu bimetal nanocluster and mechanism". Nanoscale. 10 (25): 12093–12099. doi:10.1039/C8NR01611A. PMID 29911717.
[Au₇Cu₁₂(dppy)₆(TBBT)₆Br₄]³⁺	Song, Yongbo; Weng, Shiyin; Li, Hao; Yu, Haizhu; Zhu, Manzhou (2019). "The Structure of a Au₇Cu₁₂ Bimetal Nanocluster and Its Strong Emission". Inorganic Chemistry. 58 (11): 7136–7140. doi:10.1021/acs.inorgchem.9b00547. PMID 31094521.
[Pd₁₆Ni₄(CO)₂₂(PPh₃)₄]^2-	Kawano, Masaki; Bacon, Jeffrey W.; Campana, Charles F.; Winger, Brian E.; Dudek, James D.; Sirchio, Scott A.; Scruggs, Sabrina L.; Geiser, Urs; Dahl, Lawrence F. (2001). "High-Nuclearity Close-Packed Palladium-Nickel Carbonyl Phosphine Clusters: Heteropalladium [Pd₁₆Ni₄(CO)₂₂(PPH₃)₄]^2-and [Pd₃₃Ni₉(CO)₄₁(PPH₃)₆]^4-Containing Pseudo- T _d CCP Pd₁₆Ni₄and Pseudo- D ₃ _h HCP Pd₃₃Ni₉Cores". Inorganic Chemistry. 40 (11): 2554–2569. doi:10.1021/ic000979p. PMID 11350234.
[Au₁₃Cu₈(PPh₂Py)₁₂]⁺	Yang, Huayan; Wang, Yu; Lei, Jing; Shi, Lei; Wu, Xiaohu; Mäkinen, Ville; Lin, Shuichao; Tang, Zichao; He, Jian; Häkkinen, Hannu; Zheng, Lansun; Zheng, Nanfeng (2013). "Ligand-Stabilized Au₁₃Cu_x ( x = 2, 4, 8) Bimetallic Nanoclusters: Ligand Engineering to Control the Exposure of Metal Sites". Journal of the American Chemical Society. 135 (26): 9568–9571. doi:10.1021/ja402249s. PMID 23789787.
Au₂₀Ag(S-tBu)₁₅	Yang, Sha; Chai, Jinsong; Song, Yongbo; Fan, Jiqiang; Chen, Tao; Wang, Shuxin; Yu, Haizhu; Li, Xiaowu; Zhu, Manzhou (2017). "In Situ Two-Phase Ligand Exchange: A New Method for the Synthesis of Alloy Nanoclusters with Precise Atomic Structures". Journal of the American Chemical Society. 139 (16): 5668–5671. doi:10.1021/jacs.7b00668. PMID 28383901.
Au₁₆Ag₅(S-tBu)₁₅	Yang, Sha; Chai, Jinsong; Song, Yongbo; Fan, Jiqiang; Chen, Tao; Wang, Shuxin; Yu, Haizhu; Li, Xiaowu; Zhu, Manzhou (2017). "In Situ Two-Phase Ligand Exchange: A New Method for the Synthesis of Alloy Nanoclusters with Precise Atomic Structures". Journal of the American Chemical Society. 139 (16): 5668–5671. doi:10.1021/jacs.7b00668. PMID 28383901.
Au₁₆Cu₅(S-tBu)₁₅	Yang, Sha; Chai, Jinsong; Song, Yongbo; Fan, Jiqiang; Chen, Tao; Wang, Shuxin; Yu, Haizhu; Li, Xiaowu; Zhu, Manzhou (2017). "In Situ Two-Phase Ligand Exchange: A New Method for the Synthesis of Alloy Nanoclusters with Precise Atomic Structures". Journal of the American Chemical Society. 139 (16): 5668–5671. doi:10.1021/jacs.7b00668. PMID 28383901.
Au₂₂Cd(SAdm)₁₆	Li, Yingwei; Cowan, Michael J.; Zhou, Meng; Luo, Tian-Yi; Song, Yongbo; Wang, He; Rosi, Nathaniel L.; Mpourmpakis, Giannis; Jin, Rongchao (2020). "Atom-by-Atom Evolution of the Same Ligand-Protected Au₂₁, Au₂₂, Au₂₂Cd₁, and Au₂₄ Nanocluster Series". Journal of the American Chemical Society. 142 (48): 20426–20433. doi:10.1021/jacs.0c09110. PMID 33170677.
[PdAg₂₄(SPhCl₂)₁₈]^2–	Yan, Juanzhu; Su, Haifeng; Yang, Huayan; Malola, Sami; Lin, Shuichao; Häkkinen, Hannu; Zheng, Nanfeng (2015). "Total Structure and Electronic Structure Analysis of Doped Thiolated Silver [MAg₂₄(SR)₁₈]^2– (M = Pd, Pt) Clusters". Journal of the American Chemical Society. 137 (37): 11880–11883. doi:10.1021/jacs.5b07186. PMID 26351859.
[PtAg₂₄(SPhCl₂)₁₈]^2–	Yan, Juanzhu; Su, Haifeng; Yang, Huayan; Malola, Sami; Lin, Shuichao; Häkkinen, Hannu; Zheng, Nanfeng (2015). "Total Structure and Electronic Structure Analysis of Doped Thiolated Silver [MAg₂₄(SR)₁₈]^2– (M = Pd, Pt) Clusters". Journal of the American Chemical Society. 137 (37): 11880–11883. doi:10.1021/jacs.5b07186. PMID 26351859.
Au₂₄Cd(PET)₁₈	Wang, Shuxin; Song, Yongbo; Jin, Shan; Liu, Xia; Zhang, Jun; Pei, Yong; Meng, Xiangming; Chen, Man; Li, Peng; Zhu, Manzhou (2015). "Metal Exchange Method Using Au₂₅Nanoclusters as Templates for Alloy Nanoclusters with Atomic Precision". Journal of the American Chemical Society. 137 (12): 4018–4021. doi:10.1021/ja511635g. PMID 25799517.
[Au₁₃Ag₁₂(PPh₃)₁₀Cl₈]⁺	Liu, Lingli; Song, Yongbo; Chong, Hanbao; Yang, Sha; Xiang, Ji; Jin, Shan; Kang, Xi; Zhang, Jun; Yu, Haizhu; Zhu, Manzhou (2016). "Size-confined growth of atom-precise nanoclusters in metal–organic frameworks and their catalytic applications". Nanoscale. 8 (3): 1407–1412. Bibcode:2016Nanos...8.1407L. doi:10.1039/C5NR06930K. PMID 26669234.
[Ag₂₄Au(SC₆H₁₁)₁₈]^-	Jin, Renxi; Zhao, Shuo; Liu, Chong; Zhou, Meng; Panapitiya, Gihan; Xing, Yan; Rosi, Nathaniel L.; Lewis, James P.; Jin, Rongchao (2017). "Controlling Ag-doping in [Ag_xAu_25−x(SC₆H₁₁)₁₈]⁻nanoclusters: Cryogenic optical, electronic and electrocatalytic properties". Nanoscale. 9 (48): 19183–19190. doi:10.1039/C7NR05871C. PMID 29186224.
[Ag₂₀Au₅(SC₆H₁₁)₁₈]^-	Jin, Renxi; Zhao, Shuo; Liu, Chong; Zhou, Meng; Panapitiya, Gihan; Xing, Yan; Rosi, Nathaniel L.; Lewis, James P.; Jin, Rongchao (2017). "Controlling Ag-doping in [Ag_xAu_25−x(SC₆H₁₁)₁₈]⁻nanoclusters: Cryogenic optical, electronic and electrocatalytic properties". Nanoscale. 9 (48): 19183–19190. doi:10.1039/C7NR05871C. PMID 29186224.
[Ag₁₉Au₆(SC₆H₁₁)₁₈]^-	Jin, Renxi; Zhao, Shuo; Liu, Chong; Zhou, Meng; Panapitiya, Gihan; Xing, Yan; Rosi, Nathaniel L.; Lewis, James P.; Jin, Rongchao (2017). "Controlling Ag-doping in [Ag_xAu_25−x(SC₆H₁₁)₁₈]⁻nanoclusters: Cryogenic optical, electronic and electrocatalytic properties". Nanoscale. 9 (48): 19183–19190. doi:10.1039/C7NR05871C. PMID 29186224.
[Cu₂Au₂₃(PPh₃)₁₀(SC₂H₄Ph)₅Cl₂]²⁺	Yang, Sha; Chai, Jinsong; Chen, Tao; Rao, Bo; Pan, Yiting; Yu, Haizhu; Zhu, Manzhou (2017). "Crystal Structures of Two New Gold–Copper Bimetallic Nanoclusters: Cu_xAu_{25– x}(PPH₃)₁₀(PHC₂H₄S)₅Cl₂²⁺ and Cu₃Au₃₄(PPH₃)₁₃(^tBuPhCH₂S)₆S₂³⁺". Inorganic Chemistry. 56 (4): 1771–1774. doi:10.1021/acs.inorgchem.6b02016. PMID 28140578.
Pd₂Au₂₃(PPh₃)₁₀Br₇	Kang, Xi; Xiang, Ji; Lv, Ying; Du, Wenjun; Yu, Haizhu; Wang, Shuxin; Zhu, Manzhou (2017). "Synthesis and Structure of Self-Assembled Pd₂Au₂₃(PPH₃)₁₀Br₇ Nanocluster: Exploiting Factors That Promote Assembly of Icosahedral Nano-Building-Blocks". Chemistry of Materials. 29 (16): 6856–6862. doi:10.1021/acs.chemmater.7b02015.
[Au_25–xCu_x(PET)₁₈]⁻	Hossain, Sakiat; Suzuki, Daiki; Iwasa, Takeshi; Kaneko, Ryo; Suzuki, Taiyo; Miyajima, Sayuri; Iwamatsu, Yuki; Pollitt, Stephan; Kawawaki, Tokuhisa; Barrabés, Noelia; Rupprechter, Günther; Negishi, Yuichi (2020). "Determining and Controlling Cu-Substitution Sites in Thiolate-Protected Gold-Based 25-Atom Alloy Nanoclusters". The Journal of Physical Chemistry C. 124 (40): 22304–22313. doi:10.1021/acs.jpcc.0c06858.
Au_24–xPtCu_x(PET)₁₈	Hossain, Sakiat; Suzuki, Daiki; Iwasa, Takeshi; Kaneko, Ryo; Suzuki, Taiyo; Miyajima, Sayuri; Iwamatsu, Yuki; Pollitt, Stephan; Kawawaki, Tokuhisa; Barrabés, Noelia; Rupprechter, Günther; Negishi, Yuichi (2020). "Determining and Controlling Cu-Substitution Sites in Thiolate-Protected Gold-Based 25-Atom Alloy Nanoclusters". The Journal of Physical Chemistry C. 124 (40): 22304–22313. doi:10.1021/acs.jpcc.0c06858.
Ag₂₃Pd₂(PPh₃)₁₀Cl₇	Hossain, Sakiat; Miyajima, Sayuri; Iwasa, Takeshi; Kaneko, Ryo; Sekine, Taishu; Ikeda, Ayaka; Kawawaki, Tokuhisa; Taketsugu, Tetsuya; Negishi, Yuichi (2021). "[Ag23Pd2(PPh3)10Cl7]: A new family of synthesizable bi-icosahedral superatomic molecules". The Journal of Chemical Physics. 155 (2): 024302. doi:10.1063/5.0057005. PMID 34266257.
[Au₁₃Ag₁₆(C₁₀H₆NO)₂₄]^3-	Qin, Zhaoxian; Sharma, Sachil; Wan, Chong-Qing; Malola, Sami; Xu, Wen-wu; Häkkinen, Hannu; Li, Gao (2021). "A Homoleptic Alkynyl-Ligated [Au₁₃Ag₁₆L₂₄]³⁻ Cluster as a Catalytically Active Eight-Electron Superatom". Angewandte Chemie International Edition. 60 (2): 970–975. doi:10.1002/anie.202011780. PMID 32996286.
[Ag₂₂Cu₇(C≡CR)₁₆(PPh₃)₅Cl₆]^-	Deng, Guocheng; Lee, Kangjae; Deng, Hongwen; Malola, Sami; Bootharaju, Megalamane S.; Häkkinen, Hannu; Zheng, Nanfeng; Hyeon, Taeghwan (2023). "Alkynyl-Protected Chiral Bimetallic Ag₂₂Cu₇ Superatom with Multiple Chirality Origins". Angewandte Chemie International Edition. 62 (12): e202217483. doi:10.1002/anie.202217483. PMID 36581588.
Au₂₄Cu₆(SPh^tBu)₂₂	Chai, Jinsong; Yang, Sha; Lv, Ying; Chong, Hanbao; Yu, Haizhu; Zhu, Manzhou (2019). "Exposing the Delocalized Cu−S π Bonds on the Au₂₄Cu₆(SPH t Bu)₂₂ Nanocluster and Its Application in Ring-Opening Reactions". Angewandte Chemie International Edition. 58 (44): 15671–15674. doi:10.1002/anie.201907609. PMID 31437333.
Au_30–xAg_x(S-^tBu)₁₈	Wijesinghe, Kalpani Hirunika; Sakthivel, Naga Arjun; Jones, Tanya; Dass, Amala (2020). "Crystal Structure of Au_{30– x}Ag_x(S- t Bu)₁₈ and Effect of the Ligand on Ag Alloying in Gold Nanomolecules". The Journal of Physical Chemistry Letters. 11 (15): 6312–6319. doi:10.1021/acs.jpclett.0c01330. PMID 32700914.
Au_30-xAg_x(S-^tBu)18	Li, Yingwei; Taylor, Michael G.; Luo, Tian-Yi; Song, Yongbo; Rosi, Nathaniel L.; Mpourmpakis, Giannis; Jin, Rongchao (2020). "Heteroatom Tracing Reveals the 30-Atom Au–Ag Bimetallic Nanocluster as a Dimeric Structure". The Journal of Physical Chemistry Letters. 11 (17): 7307–7312. doi:10.1021/acs.jpclett.0c01977. PMID 32787300.
Pd₂₉Ni₃(CO)₂₂(PMe₃)₁₃	Tran, Nguyet T.; Kawano, Masaki; Dahl, Lawrence F. (2001). "High-nuclearity palladium carbonyl trimethylphosphine clusters containing unprecedented face-condensed icosahedral-based transition-metal core geometries: Proposed growth patterns from a centered Pd13 icosahedron†". Journal of the Chemical Society, Dalton Transactions (19): 2731–2748. doi:10.1039/B103547A.
[Pt₂Cu₃₄(PET)₂₂Cl₄]^2-	Lee, Sanghwa; Bootharaju, Megalamane S.; Deng, Guocheng; Malola, Sami; Häkkinen, Hannu; Zheng, Nanfeng; Hyeon, Taeghwan (2021). "[Pt₂Cu₃₄(PET)₂₂Cl₄]^2–: An Atomically Precise, 10-Electron PtCu Bimetal Nanocluster with a Direct Pt–Pt Bond". Journal of the American Chemical Society. 143 (31): 12100–12107. doi:10.1021/jacs.1c04002. PMID 34314590.
[Cu₃Au₃₄(PPh₃)₁₃(SCH₂Ph^tBu)₆S₂]³⁺	Yang, Sha; Chai, Jinsong; Chen, Tao; Rao, Bo; Pan, Yiting; Yu, Haizhu; Zhu, Manzhou (2017). "Crystal Structures of Two New Gold–Copper Bimetallic Nanoclusters: Cu_xAu_{25– x}(PPH₃)₁₀(PHC₂H₄S)₅Cl₂²⁺ and Cu₃Au₃₄(PPH₃)₁₃(^tBuPhCH₂S)₆S₂³⁺". Inorganic Chemistry. 56 (4): 1771–1774. doi:10.1021/acs.inorgchem.6b02016. PMID 28140578.
Au₃₄Ag₄(SCH₂CH₂Ph)₂₄	Kumara, Chanaka; Gagnon, Kevin J.; Dass, Amala (2015). "X-ray Crystal Structure of Au_{38– x}Ag_x(SCH₂CH₂Ph)₂₄ Alloy Nanomolecules". The Journal of Physical Chemistry Letters. 6 (7): 1223–1228. doi:10.1021/acs.jpclett.5b00270. PMID 26262976.
Au₃₇Cu(2,4-(CH₃)₂C₆H₃S)₂₄	Chai, Jinsong; Lv, Ying; Yang, Sha; Song, Yongbo; Zan, Xiaofeng; Li, Qinzhen; Yu, Haizhu; Wu, Mingzai; Zhu, Manzhou (2017). "X-ray Crystal Structure and Optical Properties of Au_{38– x}Cu_x(2,4-(CH₃)₂C₆H₃S)₂₄ ( x = 0–6) Alloy Nanocluster". The Journal of Physical Chemistry C. 121 (39): 21665–21669. doi:10.1021/acs.jpcc.7b05074.
[Pd₃₃Ni₉(CO)₄₁(PPh₃)₆]^4-	Kawano, Masaki; Bacon, Jeffrey W.; Campana, Charles F.; Winger, Brian E.; Dudek, James D.; Sirchio, Scott A.; Scruggs, Sabrina L.; Geiser, Urs; Dahl, Lawrence F. (2001). "High-Nuclearity Close-Packed Palladium-Nickel Carbonyl Phosphine Clusters: Heteropalladium [Pd₁₆Ni₄(CO)₂₂(PPH₃)₄]^2-and [Pd₃₃Ni₉(CO)₄₁(PPH₃)₆]^4-Containing Pseudo- T _d CCP Pd₁₆Ni₄and Pseudo- D ₃ _h HCP Pd₃₃Ni₉Cores". Inorganic Chemistry. 40 (11): 2554–2569. doi:10.1021/ic000979p. PMID 11350234.
[Ag₂₈Cu₁₂(S(PhCl₂))₂₄]^4–	Yan, Juanzhu; Su, Haifeng; Yang, Huayan; Hu, Chengyi; Malola, Sami; Lin, Shuichao; Teo, Boon K.; Häkkinen, Hannu; Zheng, Nanfeng (2016). "Asymmetric Synthesis of Chiral Bimetallic [Ag₂₈Cu₁₂(SR)₂₄]^4– Nanoclusters via Ion Pairing". Journal of the American Chemical Society. 138 (39): 12751–12754. doi:10.1021/jacs.6b08100. PMID 27626935.
[Au₁₂Ag₃₂(SPhF)₃₀]^4-	Yang, Huayan; Wang, Yu; Huang, Huaqi; Gell, Lars; Lehtovaara, Lauri; Malola, Sami; Häkkinen, Hannu; Zheng, Nanfeng (2013). "All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures". Nature Communications. 4: 2422. doi:10.1038/ncomms3422. PMID 24005600.
[Au₁₂Ag₃₂(SPhF₂)₃₀]^4-	Yang, Huayan; Wang, Yu; Huang, Huaqi; Gell, Lars; Lehtovaara, Lauri; Malola, Sami; Häkkinen, Hannu; Zheng, Nanfeng (2013). "All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures". Nature Communications. 4: 2422. doi:10.1038/ncomms3422. PMID 24005600.
[Au₁₂Ag₃₂(SPhF₃)₃₀]^4-	Yang, Huayan; Wang, Yu; Huang, Huaqi; Gell, Lars; Lehtovaara, Lauri; Malola, Sami; Häkkinen, Hannu; Zheng, Nanfeng (2013). "All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures". Nature Communications. 4: 2422. doi:10.1038/ncomms3422. PMID 24005600.
[Au₁₂Ag₃₂(SPhF₂)₃₀]^4-	Zhang, Xin; Yang, Hua-Yan; Zhao, Xiao-Jing; Wang, Yu; Zheng, Nan-Feng (2014). "The effects of surface ligands and counter cations on the stability of anionic thiolated M12Ag32 (M=Au, Ag) nanoclusters". Chinese Chemical Letters. 25 (6): 839–843. doi:10.1016/j.cclet.2014.05.027.
[Au₁₂Ag₃₂(SPhCF₃)₃₀]^4-	Zhang, Xin; Yang, Hua-Yan; Zhao, Xiao-Jing; Wang, Yu; Zheng, Nan-Feng (2014). "The effects of surface ligands and counter cations on the stability of anionic thiolated M12Ag32 (M=Au, Ag) nanoclusters". Chinese Chemical Letters. 25 (6): 839–843. doi:10.1016/j.cclet.2014.05.027.
[Au₁₀Ag₃₄(SC₆H₃F₂)₃₀]^4–	Su, Haifeng; Wang, Yu; Ren, Liting; Yuan, Peng; Teo, Boon K.; Lin, Shuichao; Zheng, Lansun; Zheng, Nanfeng (2019). "Fractal Patterns in Nucleation and Growth of Icosahedral Core of [Au_nAg_{44– n}(SC₆H₃F₂)₃₀]^4– ( n = 0–12) via ab Initio Synthesis: Continuously Tunable Composition Control". Inorganic Chemistry. 58 (1): 259–264. doi:10.1021/acs.inorgchem.8b02249. PMID 30582690.
[Au₁₂Ag₃₂(SC₆H₃F₂)₃₀]^4–	Su, Haifeng; Wang, Yu; Ren, Liting; Yuan, Peng; Teo, Boon K.; Lin, Shuichao; Zheng, Lansun; Zheng, Nanfeng (2019). "Fractal Patterns in Nucleation and Growth of Icosahedral Core of [Au_nAg_{44– n}(SC₆H₃F₂)₃₀]^4– ( n = 0–12) via ab Initio Synthesis: Continuously Tunable Composition Control". Inorganic Chemistry. 58 (1): 259–264. doi:10.1021/acs.inorgchem.8b02249. PMID 30582690.
Cd₁₂Ag₃₂(SePh)₃₆	Bootharaju, Megalamane S.; Chang, Hogeun; Deng, Guocheng; Malola, Sami; Baek, Woonhyuk; Häkkinen, Hannu; Zheng, Nanfeng; Hyeon, Taeghwan (2019). "Cd₁₂Ag₃₂(SePh)₃₆: Non-Noble Metal Doped Silver Nanoclusters". Journal of the American Chemical Society. 141 (21): 8422–8425. doi:10.1021/jacs.9b03257. PMID 31083937.
[Au_12+nCu₃₂(SPhCF₃)_30+n]^4–	Yang, Huayan; Wang, Yu; Yan, Juanzhu; Chen, Xi; Zhang, Xin; Häkkinen, Hannu; Zheng, Nanfeng (2014). "Structural Evolution of Atomically Precise Thiolated Bimetallic [Au_{12+ n}Cu₃₂(SR)_{30+ n}]^4– ( n = 0, 2, 4, 6) Nanoclusters". Journal of the American Chemical Society. 136 (20): 7197–7200. doi:10.1021/ja501811j. PMID 24796211.
Au_5.34Ag_44.66(Dppm)₆(SPh-^tBu)₃₀	Du, Wenjun; Jin, Shan; Xiong, Lin; Chen, Man; Zhang, Jun; Zou, Xuejuan; Pei, Yong; Wang, Shuxin; Zhu, Manzhou (2017). "Ag₅₀(DPPM)₆(SR)₃₀ and Its Homologue Au_xAg_{50– x}(DPPM)₆(SR)₃₀ Alloy Nanocluster: Seeded Growth, Structure Determination, and Differences in Properties". Journal of the American Chemical Society. 139 (4): 1618–1624. doi:10.1021/jacs.6b11681. PMID 28111946.
[Cu₄₃Al₁₂](C₅Me₅)₁₂	Weßing, Jana; Ganesamoorthy, Chelladurai; Kahlal, Samia; Marchal, Rémi; Gemel, Christian; Cador, Olivier; Da Silva, Augusto C. H.; Da Silva, Juarez L. F.; Saillard, Jean-Yves; Fischer, Roland A. (2018). "The Mackay-Type Cluster [Cu₄₃Al₁₂](Cp)₁₂: Open-Shell 67-Electron Superatom with Emerging Metal-Like Electronic Structure" (PDF). Angewandte Chemie International Edition*. 57 (44): 14630–14634. doi:10.1002/anie.201806039. PMID 29981271.
[Au₈₀Ag₃₀(C≡CPh)₄₂Cl₉]⁺	Zeng, Jiu-Lian; Guan, Zong-Jie; Du, Yang; Nan, Zi-Ang; Lin, Yu-Mei; Wang, Quan-Ming (2016). "Chloride-Promoted Formation of a Bimetallic Nanocluster Au₈₀Ag₃₀ and the Total Structure Determination". Journal of the American Chemical Society. 138 (25): 7848–7851. doi:10.1021/jacs.6b04471. PMID 27285954.
Au₅₇Ag₅₃(C≡CPh)₄₀Br₁₂	Guan, Zong-Jie; Zeng, Jiu-Lian; Yuan, Shang-Fu; Hu, Feng; Lin, Yu-Mei; Wang, Quan-Ming (2018). "Au₅₇Ag₅₃(C≡CPH)₄₀Br₁₂: A Large Nanocluster with C ₁ Symmetry". Angewandte Chemie International Edition. 57 (20): 5703–5707. doi:10.1002/anie.201801261. PMID 29575416.
[Au₇₄Ag₆₀(C≡CPh)₄₀Br₁₂]²⁻	Yuan, Xiting; Malola, Sami; Deng, Guocheng; Chen, Fengjiao; Häkkinen, Hannu; Teo, Boon K.; Zheng, Lansun; Zheng, Nanfeng (2021). "Atomically Precise Alkynyl- and Halide-Protected AuAg Nanoclusters Au₇₈Ag₆₆(C≡CPH)₄₈Cl₈ and Au₇₄Ag₆₀(C≡CPH)₄₀Br₁₂: The Ligation Effects of Halides". Inorganic Chemistry. 60 (6): 3529–3533. doi:10.1021/acs.inorgchem.0c03462. PMID 33615777.
[Au₇₈Ag₆₆(C≡CPh)₄₈Cl₈]^q−	Yuan, Xiting; Malola, Sami; Deng, Guocheng; Chen, Fengjiao; Häkkinen, Hannu; Teo, Boon K.; Zheng, Lansun; Zheng, Nanfeng (2021). "Atomically Precise Alkynyl- and Halide-Protected AuAg Nanoclusters Au₇₈Ag₆₆(C≡CPH)₄₈Cl₈ and Au₇₄Ag₆₀(C≡CPH)₄₀Br₁₂: The Ligation Effects of Halides". Inorganic Chemistry. 60 (6): 3529–3533. doi:10.1021/acs.inorgchem.0c03462. PMID 33615777.
Pd_164-xPt_x(CO)₇₂(PPh₃)₂₀	Mednikov, Evgueni G.; Jewell, Matthew C.; Dahl, Lawrence F. (2007). "Nanosized (μ₁₂-Pt)Pd_164- _x Pt _x (CO)₇₂(PPH₃)₂₀( x ≈ 7) Containing Pt-Centered Four-Shell 165-Atom Pd−Pt Core with Unprecedented Intershell Bridging Carbonyl Ligands: Comparative Analysis of Icosahedral Shell-Growth Patterns with Geometrically Related Pd₁₄₅(CO) _x (PEt₃)₃₀( x ≈ 60) Containing Capped Three-Shell Pd₁₄₅Core". Journal of the American Chemical Society. 129 (37): 11619–11630. doi:10.1021/ja073945q. PMID 17722929.

Partially experimentally determined

Table of partially experimentally determined structures of MPCs.
Formula	References
Ag₂₉(LA)₁₂∩CB₁	Nag, Abhijit; Chakraborty, Papri; Thacharon, Athira; Paramasivam, Ganesan; Mondal, Biswajit; Bodiuzzaman, Mohammad; Pradeep, Thalappil (2020). "Atomically Precise Noble Metal Cluster-Assembled Superstructures in Water: Luminescence Enhancement and Sensing". The Journal of Physical Chemistry C. 124 (40): 22298–22303. doi:10.1021/acs.jpcc.0c06770.
Ag₂₉(LA)₁₂@β-CD₁	Nag, Abhijit; Chakraborty, Papri; Thacharon, Athira; Paramasivam, Ganesan; Mondal, Biswajit; Bodiuzzaman, Mohammad; Pradeep, Thalappil (2020). "Atomically Precise Noble Metal Cluster-Assembled Superstructures in Water: Luminescence Enhancement and Sensing". The Journal of Physical Chemistry C. 124 (40): 22298–22303. doi:10.1021/acs.jpcc.0c06770.
Au₆₈(SH)₃₂	Azubel, Maia; Koivisto, Jaakko; Malola, Sami; Bushnell, David; Hura, Greg L.; Koh, Ai Leen; Tsunoyama, Hironori; Tsukuda, Tatsuya; Pettersson, Mika; Häkkinen, Hannu; Kornberg, Roger D. (2014). "Electron microscopy of gold nanoparticles at atomic resolution". Science. 345 (6199): 909–912. Bibcode:2014Sci...345..909A. doi:10.1126/science.1251959. PMC 4315941. PMID 25146285.
Au₁₄₄(3-MBA)_x	Azubel, Maia; Koh, Ai Leen; Koyasu, Kiichirou; Tsukuda, Tatsuya; Kornberg, Roger D. (2017). "Structure Determination of a Water-Soluble 144-Gold Atom Particle at Atomic Resolution by Aberration-Corrected Electron Microscopy". ACS Nano. 11 (12): 11866–11871. doi:10.1021/acsnano.7b06051. PMID 29136369.

References

^ ^a ^b Tatsuya Tsukuda and Hannu Häkkinen. Protected Metal Clusters: From Fundamentals to Applications. Elsevier Ltd. 2015, Amsterdam, Netherlands, ISBN 978-0-08-100086-1
^ Maity, Prasenjit; Tsunoyama, Hironori; Yamauchi, Miho; Xie, Songhai; Tsukuda, Tatsuya (2011). "Organogold Clusters Protected by Phenylacetylene". Journal of the American Chemical Society. 133 (50): 20123–20125. doi:10.1021/ja209236n. PMID 22082045.
^ Hurst, Eleanor C.; Wilson, Karen; Fairlamb, Ian J. S.; Chechik, Victor (2009). "N-Heterocyclic carbene coated metal nanoparticles". New Journal of Chemistry. 33 (9): 1837. doi:10.1039/B905559B.
^ https://www.ccdc.cam.ac.uk/
^ "Crystallography Open Database".
^ https://www.rcsb.org/
^ ^a ^b Mingos, D. Michael P.; Hill, Christopher M. (1 November 1995). "Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]". Croatica Chemica Acta. 68 (4): 745–767. ISSN 0011-1643.

External links

Pihlajamäki, Antti; Malola, Sami; Häkkinen, Hannu (24 May 2024). "Creating a Catalog of the Crystal Structures of Monolayer-Protected Clusters". ChemRxiv. doi:10.26434/chemrxiv-2024-kxjpb. this work

[tsukuda15-1] Tatsuya Tsukuda and Hannu Häkkinen. Protected Metal Clusters: From Fundamentals to Applications. Elsevier Ltd. 2015, Amsterdam, Netherlands, ISBN 978-0-08-100086-1

[maity11-2] Maity, Prasenjit; Tsunoyama, Hironori; Yamauchi, Miho; Xie, Songhai; Tsukuda, Tatsuya (2011). "Organogold Clusters Protected by Phenylacetylene". Journal of the American Chemical Society. 133 (50): 20123–20125. doi:10.1021/ja209236n. PMID 22082045.

[hurst09-3] Hurst, Eleanor C.; Wilson, Karen; Fairlamb, Ian J. S.; Chechik, Victor (2009). "N-Heterocyclic carbene coated metal nanoparticles". New Journal of Chemistry. 33 (9): 1837. doi:10.1039/B905559B.

[4] ttps://www.ccdc.cam.ac.uk/

[5] "Crystallography Open Database".

[6] ttps://www.rcsb.org/

[hill-7] Mingos, D. Michael P.; Hill, Christopher M. (1 November 1995). "Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]". Croatica Chemica Acta. 68 (4): 745–767. ISSN 0011-1643.

[1]

[2]

[3]

[4]

[5]

[6]

[7]