Neodymium(III) vanadate

Neodymium(III) vanadate is an inorganic compound, a salt of neodymium and vanadic acid with the chemical formula of NdVO4. It forms pale-blue,[2] hydrated crystals.

Neodymium(III) vanadate
Names
Other names
Neodymium(III) vanadate(V)
Neodymium orthovanadate
Identifiers
3D model (JSmol)
EC Number
  • 237-290-5
  • InChI=1S/Nd.4O.V/q+3;;3*-1;
    Key: SEEUVPGHIZOZOF-UHFFFAOYSA-N
  • [O-][V](=O)([O-])[O-].[Nd+3]
Properties
NdVO4
Molar mass 259,1806 g/mol
Appearance light positive crystals[2]
Density 4,979 g/cm³[2]
insoluble
Structure
a = 0,736 nm, b = 0,736 nm, c = 0,6471 nm[3]
Related compounds
Other anions
Neodymium niobate
Neodymium tantalate
Other cations
Praseodymium(III) vanadate
Prometium(III) vanadate
Samarium(III) vanadate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Preparation

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Neodymium(III) vanadate is produced by the reaction of hot acidic neodymium(III) chloride and sodium vanadate:[4]

 

Physical properties

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Neodymium(III) vanadate forms crystals of the tetragonal crystal system, space group I 41/amd, lattice constants a = 0.736 nm, b = 0.736 nm, c = 0.6471 nm, α = 90°, β = 90°, γ = 90°, Z = 4.[4]

It doesn't dissolve in water.[citation needed]

It can form hydrates.[citation needed]

Applications

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Neodymium(III) vanadate can be used for:

References

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  1. ^ "Substance Information - ECHA". Echa.europa.eu.
  2. ^ a b c Standard X-ray Diffraction Powder Patterns (United States. National Bureau of Standards; U. S. Department of Commerce, National Bureau of Standards, 1953), page 30. Accessed January 20, 2021.
  3. ^ Handbook… (Pierre Villars, Karin Cenzual, Roman Gladyshevskii; Walter de Gruyter GmbH & Co KG, 24 thg 7, 2017 - 1970 trang). Truy cập 20 tháng 1 năm 2021.
  4. ^ a b Swanson, Howard E.; Morris, Marlene C. & Evans, Eloise H. (28 June 1966). Standard X-ray Diffraction Powder Patterns: Section 4. Data for 103 Substances. Washington D.C.: UNT Digital Library. p. 30.{{cite book}}: CS1 maint: multiple names: authors list (link)
  5. ^ Vlasov, V. I.; Garnov, S. V.; Zavartsev, Yu D.; Zagumennyi, A. I.; Kutovoi, S. A.; Sirotkin, A. A.; Shcherbakov, I. A. (2007-10-31). "New possibilities of neodymium-doped vanadate crystals as active media for diode-pumped lasers". Quantum Electronics. 37 (10): 938–940. doi:10.1070/QE2007V037N10ABEH013663. ISSN 1063-7818. OSTI 21466728. S2CID 250882847.
  6. ^ Payne, Stephen A.; Kway, Wayne L.; DeLoach, Laura D.; Krupke, William F.; Chai, Bruce H. T. (1994-01-01). "Ytterbium- and neodymium-doped vanadate laser hose crystals having the apatite crystal structure". {{cite journal}}: Cite journal requires |journal= (help)

External reading

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