Palladium(II) perchlorate is an inorganic chemical compound with the formula Pd(ClO4)2. It is a light-brown solid produced by the reaction of dichlorine hexoxide and palladium(II) chloride followed by heating at 60 °C in a vacuum:[1]
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| Names | |
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| Systematic IUPAC name
Palladium(II) diperchlorate | |
Other names
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| Identifiers | |
3D model (JSmol)
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PubChem CID
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| Properties | |
| Pd(ClO4)2 | |
| Molar mass | 305.32 g/mol |
| Appearance | Light-brown solid |
| Soluble | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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- 3 PdCl2 + 4 Cl2O6 → 3 Pd(ClO4)2 + 4 Cl2
Aqueous solutions of palladium(II) perchlorate can be produced by the addition of perchloric acid to a solution of palladium(II) nitrate.[2]
Structure
editSolid anhydrous palladium(II) perchlorate consists of a pair of bidentate perchlorate ligands attached to the central palladium atom.[1]
References
edit- ^ a b Frédérique Cunin; Frédéric Favier; Jean Louis Pascal (2000). "Anhydrous perchlorato complexes of palladium(II): Pd(ClO4)2, (ClO2)2Pd(ClO4)4, and (NO2)2Pd(ClO4)4. Syntheses and structural analyses". Canadian Journal of Chemistry. 78 (12): 1544–1522. doi:10.1139/v00-149.
- ^ A. K. Sundaram; E. B. Sandell (1955). "Chloro Complexes of Palladium(II) in Solution". Journal of the American Chemical Society. 77 (4): 855–857. doi:10.1021/ja01609a008.