Phyllocladane

Phyllocladane
Names
	IUPAC name (1R,4S,9S,10R,13S,14S)-5,5,9,14-Tetramethyltetracyclo[11.2.1.01,10.04,9]hexadecane
	Other names (8α,9β)-Kaurane
Identifiers
CAS Number	133097-76-4 [???];
3D model (JSmol)	Interactive image;
ChemSpider	66423789;
PubChem CID	12304768;
	InChI InChI=1S/C20H34/c1-14-12-20-11-8-16-18(2,3)9-5-10-19(16,4)17(20)7-6-15(14)13-20/h14-17H,5-13H2,1-4H3/t14-,15-,16-,17-,19-,20+/m0/s1 Key: IVZWRQBQDVHDNG-BUJXUYPKSA-N;
	SMILES C[C@H]1C[C@@]23CC[C@@H]4[C@@]([C@@H]2CC[C@H]1C3)(CCCC4(C)C)C;
Properties
Chemical formula	C20H34
Molar mass	274.492 g·mol−1
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Phyllocladane is a tricyclic diterpane which is generally found in gymnosperm resins.^[1] It has a formula of C₂₀H₃₄ and a molecular weight of 274.4840.^[2] As a biomarker, it can be used to learn about the gymnosperm input into a hydrocarbon deposit, and about the age of the deposit in general. It indicates a terrogenous origin of the source rock. Diterpanes, such as Phyllocladane are found in source rocks as early as the middle and late Devonian periods, which indicates any rock containing them must be no more than approximately 360 Ma. Phyllocladane is commonly found in lignite, and like other resinites derived from gymnosperms, is naturally enriched in ¹³C. This enrichment is a result of the enzymatic pathways used to synthesize the compound.^[1]

The compound can be identified by GC-MS. A peak of m/z 123 is indicative of tricyclic diterpenoids in general, and phyllocladane in particular is further characterized by strong peaks at m/z 231 and m/z 189. Presence of phyllocladane and its relative abundance to other tricyclic diterpanes can be used to differentiate between various oil fields.^[1]

References

^ ^a ^b ^c Walters, C. C. (2005). The Biomarker Guide. Cambridge, UK. pp. 543–551.{{cite book}}: CS1 maint: location missing publisher (link)
^ "Phyllocladane". webbook.nist.gov. Retrieved 2016-12-06.

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[:0-1] Walters, C. C. (2005). The Biomarker Guide. Cambridge, UK. pp. 543–551.{{cite book}}: CS1 maint: location missing publisher (link)

[2] "Phyllocladane". webbook.nist.gov. Retrieved 2016-12-06.

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