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Plasmonic nanolithography

Plasmonic nanolithography (also known as plasmonic lithography or plasmonic photolithography)[1] is a nanolithographic process that utilizes surface plasmon excitations such as surface plasmon polaritons (SPPs) to fabricate nanoscale structures. SPPs, which are surface waves that propagate in between planar dielectric-metal layers in the optical regime, can bypass the diffraction limit on the optical resolution that acts as a bottleneck for conventional photolithography.

Theory

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Schematic representation of a surface plasmon polariton
Main article: Surface plasmon polariton

Surface plasmon polaritons are surface electromagnetic waves that propagate in between two surfaces with sign-changing permittivities. They originate from coupling of photons to plasma oscillations, quantized as plasmons. SPPs result in evanescent fields that decay perpendicularly to the interface where the propagation occurs. The dispersion relation for SPPs permits the excitation of wavelengths shorter than the free-space wavelength of the inbound light, additionally ensuring subwavelength field confinement. Nevertheless, the excitation of SPPs necessitate momentum mismatch; prism and grating coupling methods are common.[2] For plasmonic nanolithography processes, this is achieved through surface roughness and perforations.[1]

Methods

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A general scheme for photomask lithography

Plasmonic contact lithography, a modification on the evanescent near-field lithography, uses a metal photomask, on which the SPPs are excited. Similar to common photolithographic processes, photoresist is exposed to SPPs that propagate from the mask. Photomasks with holes enable grating coupling of SPPs; the fields only propagate for nanometers.[1][3] Srituravanich et al. has demonstrated the lithographic process experimentally with a 2D silver hole array mask; 90 nm hole arrays were produced at 365 nm wavelength, which is beyond diffraction limit.[4] Zayats and Smolyaninov utilized a multi-layered metal film mask to enhance the subwavelength aperture; such structures can be realized by thin film deposition methods. Bowtie apertures and nanogaps were also suggested as alternative apertures.[1] A version of the method, named as surface plasmon interference nanolithography by Liu et al., uses SPP interference patterns.[5] Despite offering high resolution and throughput, plasmonic contact lithography is regarded as an expensive and complex method; contamination due to contact is also a limiting factor.[1]

Optical trapping via plasmon-assisted etching. In this scheme, etching is achieved through LSP resonances in gold nanoantennas.[6]

Planar lens imaging nanolithography uses plasmonic lenses or negative-index superlenses, which were first proposed by John Pendry. Many superlens designs, such as Pendry's thin silver film or Fang et al.'s superlens, benefit from plasmonic excitations to focus Fourier components of incoming light beyond the diffraction limit.[1] Chaturvedi et al. has demonstrated the imaging of a 30 nm chromium grating through silver superlens photolithography at 380 nm,[7] while Shi et al. simulated a 20 nm lithography resolution at 193 nm wavelength with an aluminum superlens.[8] Srituravanich et al. has developed a mechanically adjustable, hovering plasmonic lens for maskless near-field nanolithography,[9] whereas another maskless approach by Pan et al. uses a "multi-stage plasmonic lens" for progressive coupling.[10]

Plasmonic direct writing is a maskless form of photolithography that is based on scanning probe lithography; the method uses localized surface plasmon (LSP) enhancements from embedded plasmonic scanning probes to expose the photoresist.[1][11] Wang et al. experimentally demonstrated 100 nm field confinement with this method.[12] Kim et al. has developed a ~50 nm resolution scanning probe with a patterning speed of ~10 mm/s.[13] Gold nanoparticles and other plasmonic nanostructures such as nanogaps have been used as masks for lithography;[6][14] etching in this case can be achieved through either through photomasking principles[14] or enhanced local heating in the vicinity of the nanostructure due to the LSP resonances.[6][15][16] Lin et al. also used localized thermal excitations in gold nanoparticles to fabricate two-dimensional structures such as patterned graphene and molybdenum disulfide monolayers in a process termed as "optothermoplasmonic nanolithography."[17] Photochemical effects of LSP resonances were also used as a catalyst in lithographic processes:[18] Saito et al. demonstrated selective etching of silver nanocubes on titanium dioxide substrates by the means of plasmon-induced charge separation.[19]

See also

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References

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  1. ^ a b c d e f g Xie, Zhihua; Yu, Weixing; Wang, Taisheng; et al. (31 May 2011). "Plasmonic nanolithography: a review". Plasmonics. 6 (3): 565–580. doi:10.1007/s11468-011-9237-0.
  2. ^ Maradudin, Alexei A.; Sambles, J. Roy; Barnes, William L., eds. (2014). Modern Plasmonics. Amsterdam: Elsevier. p. 1–23. ISBN 9780444595263.
  3. ^ Shao, D. B.; Chen, S. C. (2005). "Surface-plasmon-assisted nanoscale photolithography by polarized light". Applied Physics Letters. 86 (25): 253107. doi:10.1063/1.1951052.
  4. ^ Srituravanich, Werayut; Fang, Nicholas; Sun, Cheng; et al. (2004). "Plasmonic nanolithography". Nano Letters. 4 (6): 1085–1088. Bibcode:2004NanoL...4.1085S. doi:10.1021/nl049573q.
  5. ^ Liu, Zhao-Wei; Wei, Qi-Huo; Zhang, Xiang (2005). "Surface plasmon interference nanolithography". Nano Letters. 5 (5): 957–961. Bibcode:2005NanoL...5..957L. doi:10.1021/nl0506094. PMID 15884902.
  6. ^ a b c Chen, Hao; Bhuiya, Abdul M.; Ding, Qing; Johnson, Harley T.; Toussaint Jr., Kimani C. (2016). "Towards do-it-yourself planar optical components using plasmon-assisted etching". Nature Communications. 7 (7): 10468. doi:10.1038/ncomms10468. PMC 4737853. PMID 26814026.
  7. ^ Chaturvedi1, Pratik; Wu, Wei; Logeeswaran, VJ; et al. (25 January 2010). "A smooth optical superlens". Applied Physics Letters. 96 (4): 043102. Bibcode:2010ApPhL..96d3102C. doi:10.1063/1.3293448.{{cite journal}}: CS1 maint: numeric names: authors list (link)
  8. ^ Shi, Zhong; Kochergin, Vladimir; Wang, Fei (2009). "193nm superlens imaging structure for 20nm lithography node". Optics Express. 17 (3): 11309–11314. Bibcode:2009OExpr..1711309S. doi:10.1364/OE.17.011309. PMID 19582044.
  9. ^ Srituravanich, Werayut; Pan, Liang; Wang, Yuan; Sun, Cheng (12 October 2008). "Flying plasmonic lens in the near field for high-speed nanolithography". Nature Nanotechnology. 3 (12): 733–737. Bibcode:2008NatNa...3..733S. doi:10.1038/nnano.2008.303. PMID 19057593.
  10. ^ Pan, Liang; Park, Yongshik; Xiong, Yi; Ulin-Avila, Erick (29 November 2011). "Maskless plasmonic lithography at 22 nm resolution". Scientific Reports. 1 (175): 175. doi:10.1038/srep00175. PMC 3240963. PMID 22355690.
  11. ^ Heltzel, Alex; Theppakuttai, Senthil; Chen, S.C.; Howell, John R. (6 December 2007). "Surface plasmon-based nanopatterning assisted by gold nanospheres". Nanotechnology. 19 (2): 025305. doi:10.1088/0957-4484/19/02/025305. PMID 21817542.
  12. ^ Wang, Yuan; Srituravanich, Werayut; Sun, Cheng; Zhang, Xiang (2008). "Plasmonic nearfield scanning probe with high transmission". Nano Letters. 8 (9): 3041–3045. Bibcode:2008NanoL...8.3041W. CiteSeerX 10.1.1.862.5284. doi:10.1021/nl8023824. PMID 18720976.
  13. ^ Kim, Yongwoo; Kim, Seok; Jung, Howon; et al. (2009). "Plasmonic nano lithography with a high scan speed contact probe". Optics Express. 17 (22): 19476–19485. Bibcode:2009OExpr..1719476K. doi:10.1364/OE.17.019476. PMID 19997168.
  14. ^ a b Ueno, Kosei; Takabatake, Satoaki; Nishijima, Yoshiaki; et al. (2010). "Nanogap-Assisted Surface Plasmon Nanolithography". The Journal of Physical Chemistry Letters. 1 (3): 657–662. doi:10.1021/jz9002923.
  15. ^ Fedoruk, Michael; Meixner, Marco; Carretero-Palacios, Sol; Lohmüller, Theobald (2013). "Nanolithography by Plasmonic Heating and Optical Manipulation of Gold Nanoparticles". ACS Nano. 7 (9): 7648–7653. doi:10.1021/nn402124p. PMID 23941522.
  16. ^ Wang, Shuangshuang; Ding, Tao (2019). "Plasmon-assisted nanojet lithography". Nanoscale. 11 (19): 9593–9597. doi:10.1039/C8NR08834A. PMID 31063168.
  17. ^ Lin, Linhan; Li, Jingang Li; Li, Wei; Yogeesh, Maruthi N.; et al. (2018). "Optothermoplasmonic Nanolithography for On-Demand Patterning of 2D Materials". Advanced Functional Materials. 28 (41): 1870299. doi:10.1002/adfm.201803990.
  18. ^ Tan, Che; Qin, Chu; Sadtler, Bryce; Sadtler, Bryce (2017). "Light-directed growth of metal and semiconductor nanostructures". Journal of Materials Chemistry C. 5 (23): 5628–5642. doi:10.1039/C7TC00379J.
  19. ^ Saito, Koichiro; Tanabe, Ichiro; Tatsuma, Tetsu (2016). "Site-Selective Plasmonic Etching of Silver Nanocubes". The Journal of Physical Chemistry Letters. 7 (21): 4363–4368. doi:10.1021/acs.jpclett.6b02393. PMID 27767323.
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