Rhenium(IV) chloride is the inorganic compound with the formula ReCl4. This black solid is of interest as a binary phase but otherwise is of little practical value. A second polymorph of ReCl4 is also known.[1]
_chloride.png) Unit cell of Rhenium(IV) chloride.
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| Names | |
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| Other names
rhenium tetrachloride
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.033.612 |
PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| Cl4Re | |
| Molar mass | 328.01 g·mol−1 |
| Appearance | black solid |
| Density | 4.5 g·cm−3 (β) |
| Structure[1] | |
| Primitive monoclinic | |
| P2/c, No. 13 | |
a = 636.2 pm, b = 627.3 pm, c = 1216.5 pm α = 90°, β = 93.15°, γ = 90°[1]
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Formula units (Z)
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4 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preparation
editReCl4 can be prepared by comproportionation of rhenium(V) chloride and rhenium(III) chloride. It can also be produced by reduction of rhenium(V) chloride with antimony trichloride.[2]
Tetrachloroethylene at 120 °C is also effective as a reductant:
Structure
editX-ray crystallography reveals a polymeric structure. The Re–Re bonding distance is 2.728 Å. Re centers are octahedral, being surrounded by six chloride ligands. Pairs of octahedra share faces. The Re2Cl9 subunits are linked by bridging chloride ligands. The structural motif - corner-shared bioctahedra - is unusual in the binary metal halides.[1]
References
edit- ^ a b c d Cotton FA, DeBoer BG, Mester Z (1973). "Chemistry of Rhenium(IV) Chloride. II. Structure of One of the Polymorphs (β) and Evidence for a New Polymorph (γ)". Journal of the American Chemical Society. 95 (4): 1159–1163. doi:10.1021/ja00785a027.
- ^ Erwin Riedel; Christoph Janiak (2011). Anorganische Chemie. Walter de Gruyter. ISBN 978-311022567-9.