Selenide borates, officially known as borate selenides, are chemical mixed anion compounds that contain any kind of borate and selenide ions. They are distinct from selenoborates in which selenium atoms replace oxygen in borates. There are also analogous borate sulfides, with sulfur ions instead of selenium.

List

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name chem mw crystal system space group unit cell volume density comments references
Zn8Se2[BO2]12 I43m a=7.6749 b=7.6749 c=7.6749 band gap 4.42 eV SHG 0.14xKDP [1][2]
YSeBO2 210.68 orthorhombic Cmc21 a=5.6617 b=16.5858 c=1.441 Z=4 389.15 3.596 band gap 3.45 eV [3]
Sm6Ta2MgSeB8O26 1869.75 trigonal P3 a=8.089 c=8.6765 Z=1 491.70 6.314 [4]
Eu6Ta2MgSeB8O26 1879.41 trigonal P3 a=8.0717 c=8.6491 Z=1 488.01 6.395 [4]
Gd6Ta2MgSeB8O26 1911.15 trigonal P3 a=8.0536 c=8.6296 Z=1 484.73 6.547 [4]

References

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  1. ^ Zhou, Wenfeng; Li, Xiao-Hui; Yao, Wen-Dong; Xue, Huaiguo; Guo, Sheng-Ping (2020), CSD 1999764: Experimental Crystal Structure Determination, FIZ Karlsruhe - Leibniz Institute for Information Infrastructure, doi:10.5517/ccdc.csd.cc253xjr, retrieved 2021-03-13
  2. ^ Zhou, Wenfeng; Li, Xiao-Hui; Yao, Wen-Dong; Xue, Huaiguo; Guo, Sheng-Ping (October 2020). "Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis". Journal of Solid State Chemistry. 290: 121572. Bibcode:2020JSSCh.29021572Z. doi:10.1016/j.jssc.2020.121572. S2CID 224876635.
  3. ^ Lu, Zhen-Tao; Fan, Wen-Jing; Wang, Zhi-Qian; Gu, Ning; Yue, Zeng-Hao; Xue, Huai-Guo; Guo, Sheng-Ping (2020-06-15). "Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO 2 : Featuring a [YSeBO 2 ] n Planar Belt". Inorganic Chemistry. 59 (12): 7905–7909. doi:10.1021/acs.inorgchem.0c00753. ISSN 0020-1669. PMID 32469211. S2CID 218984948.
  4. ^ a b c Shi, Zhi-Hui; Chi, Yang; Yang, Mei; Liu, Wenlong; Guo, Sheng-Ping (2020-03-16). "A Series of Chalcogenide Borates RE 6 Ta 2 MgQB 8 O 26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B 4 O 10 Cluster". Inorganic Chemistry. 59 (6): 3532–3536. doi:10.1021/acs.inorgchem.0c00086. ISSN 0020-1669. PMID 32090554. S2CID 211263182.