Talk:Bioorthogonal chemistry
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SPAAC raction rates
editWhere are those taken from? They are missing temperature and solvent (which can change the rate of cycloadditions quite a bit). 84.113.127.57 (talk) 21:29, 7 March 2016 (UTC)
Staudinger Ligation Mechanism error
editThe image you have for the Staudinger ligation (i.e. this: http://en.wikipedia.org/wiki/File:Staudingerligmech.png) has a small error. The issue is that it is shown as regenerating the phosphine in the end of the reaction. This is not the case, a phosphine oxide is generated by this process (amazing things could be done if water could reduce phosphorous V into phosphorous III). Just take the final species and make sure there is a P=O at the end, then I believe you are all good.149.155.222.31 (talk) 17:12, 18 October 2013 (UTC)
-Wait Scratch that being all, also the transition state in the brackets [] has a phenyl ring integrated into the phosphorous-nitrogen heterocycle. That "Ph" in the ring should be another "N". I'd say that is it, but if I do, then I might find another error five seconds later like last time.149.155.222.31 (talk) 17:17, 18 October 2013 (UTC)