Talk:Caesium phosphide
Latest comment: 6 months ago by Leiem in topic Existence of Cs2P5
Existence of Cs2P5
editI did not find any papers about crystallographic characterizations about Cs2P5. However, from Chem. Rev. by HG Von Schnering, W Hönle (1988) (doi:10.1021/cr00083a012), it mentions "the yellow M3P7 (in the literature formerly erroneously called M2P5) have been prepared in NH3(l)", which indicates that Cs2P5 is actually Cs3P7. --Leiem (talk) 17:32, 3 March 2024 (UTC)
- Yes this whole article is problematic as there appears to be multiple compounds, eg Cs4P6.[1] This article:[2] has Cs4P6, Cs3P7, Cs3P8.33, Cs3P11, CsP7, CsP11, CsP15. There exists variants that are solvated: Cs3P (dubious), s2P4 and Cs4P11. 9 different crystal structures are listed in that article.
- ^ Kraus, Florian; Günne, Jörn Schmedt auf der; DiSalle, Brian F.; Korber, Nikolaus (21 December 2006). "No aromaticity of P64− observed via solid state 31P-NMR spectroscopy". Chemical Communications (2): 218–219.
- ^ Sangster, James M. (February 2010). "Cs-P (Cesium-Phosphorus) System". Journal of Phase Equilibria and Diffusion. 31 (1): 77–80. doi:10.1007/s11669-009-9615-x. ISSN 1547-7037.