This is the talk page for discussing improvements to the Haloform reaction article. This is not a forum for general discussion of the article's subject. |
Article policies
|
Find sources: Google (books · news · scholar · free images · WP refs) · FENS · JSTOR · TWL |
This level-5 vital article is rated C-class on Wikipedia's content assessment scale. It is of interest to the following WikiProjects: | |||||||||||
|
- Reynold C. Fuson and Benton A. Bull (1934). "The Haloform Reaction". Chemical Reviews. 15 (3): 275–309. doi:10.1021/cr60052a001.
- SERULLAS Ann. chim. 20, 165 (1822);
- LIEBEN: Ann. Spl. Bd. 7, 218 (1870).
- LIEBEN: Ann. Spl. Bd. 7, 377 (1870).--Stone (talk) 11:08, 1 March 2009 (UTC)
Mechanism suspect
editI seriously doubt that the mechanism of I2 oxidation of secondary alcohols involves a ternary encounter, as depicted. Besides, no reference is provided. Much more likely in my mind is the α-deprotonation of an R-OI intermediate.