- Group 1
| Pos | Team | Pld | W | D | L | GF | GA | GD | Pts | Promotion[a] | 
|
|
|
| |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 | Georgia (P)
|
6 | 5 | 1 | 0 | 12 | 2 | +10 | 16 | Promotion to League C | — | 2–1 | 1–0 | 3–0 | |
| 2 | Kazakhstan (P)
|
6 | 1 | 3 | 2 | 8 | 7 | +1 | 6 | 0–2 | — | 1–1 | 4–0 | ||
| 3 | Latvia
|
6 | 0 | 4 | 2 | 2 | 6 | −4 | 4[b] | 0–3 | 1–1 | — | 0–0 | ||
| 4 | Andorra
|
6 | 0 | 4 | 2 | 2 | 9 | −7 | 4[b] | 1–1 | 1–1 | 0–0 | — |
- ^ Due to revamp of the format for the 2020–21 UEFA Nations League, the second-placed teams in each group and the best third-placed team among all groups were also promoted.
- ^ a b Tied on head-to-head results. Overall goal difference was used as the tiebreaker.
- Group 2
| Pos | Team | Pld | W | D | L | GF | GA | GD | Pts | Promotion[a] | 
|
|
|
| |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 | Belarus (P)
|
6 | 4 | 2 | 0 | 10 | 0 | +10 | 14 | Promotion to League C | — | 1–0 | 0–0 | 5–0 | |
| 2 | Luxembourg (P)
|
6 | 3 | 1 | 2 | 11 | 4 | +7 | 10 | 0–2 | — | 4–0 | 3–0 | ||
| 3 | Moldova (P)
|
6 | 2 | 3 | 1 | 4 | 5 | −1 | 9 | 0–0 | 1–1 | — | 2–0 | ||
| 4 | San Marino
|
6 | 0 | 0 | 6 | 0 | 16 | −16 | 0 | 0–2 | 0–3 | 0–1 | — |
- ^ Due to revamp of the format for the 2020–21 UEFA Nations League, the second-placed teams in each group and the best third-placed team among all groups were also promoted.
- Group 3
| Pos | Team | Pld | W | D | L | GF | GA | GD | Pts | Promotion[a] | 
|
|
|
| |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 | Kosovo (P)
|
6 | 4 | 2 | 0 | 15 | 2 | +13 | 14 | Promotion to League C | — | 4–0 | 2–0 | 3–1 | |
| 2 | Azerbaijan (P)
|
6 | 2 | 3 | 1 | 7 | 6 | +1 | 9 | 0–0 | — | 2–0 | 1–1 | ||
| 3 | Faroe Islands
|
6 | 1 | 2 | 3 | 5 | 10 | −5 | 5 | 1–1 | 0–3 | — | 3–1 | ||
| 4 | Malta
|
6 | 0 | 3 | 3 | 5 | 14 | −9 | 3 | 0–5 | 1–1 | 1–1 | — |
- ^ Due to revamp of the format for the 2020–21 UEFA Nations League, the second-placed teams in each group and the best third-placed team among all groups were also promoted.
- Group 4
| Pos | Team | Pld | W | D | L | GF | GA | GD | Pts | Promotion[a] | 
|
|
|
| |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 | Macedonia (P)
|
6 | 5 | 0 | 1 | 14 | 5 | +9 | 15 | Promotion to League C | — | 2–0 | 4–0 | 4–1 | |
| 2 | Armenia (P)
|
6 | 3 | 1 | 2 | 14 | 8 | +6 | 10 | 4–0 | — | 0–1 | 2–1 | ||
| 3 | Gibraltar
|
6 | 2 | 0 | 4 | 5 | 15 | −10 | 6 | 0–2 | 2–6 | — | 2–1 | ||
| 4 | Liechtenstein
|
6 | 1 | 1 | 4 | 7 | 12 | −5 | 4 | 0–2 | 2–2 | 2–0 | — |
- ^ Due to revamp of the format for the 2020–21 UEFA Nations League, the second-placed teams in each group and the best third-placed team among all groups were also promoted.
- 3rd place
| Pos | Grp | Team | Pld | W | D | L | GF | GA | GD | Pts | Promotion |
|---|---|---|---|---|---|---|---|---|---|---|---|
| 1 | D2 | Moldova (P)
|
6 | 2 | 3 | 1 | 4 | 5 | −1 | 9 | Promotion to League C |
| 2 | D4 | Gibraltar
|
6 | 2 | 0 | 4 | 5 | 15 | −10 | 6 | |
| 3 | D3 | Faroe Islands
|
6 | 1 | 2 | 3 | 5 | 10 | −5 | 5 | |
| 4 | D1 | Latvia
|
6 | 0 | 4 | 2 | 2 | 6 | −4 | 4 |
Source: UEFA
Rules for classification: 1) Points; 2) Goal difference; 3) Goals scored; 4) Away goals scored; 5) Wins; 6) Away wins; 7) Disciplinary points; 8) UEFA national team coefficient.
(P) Promoted
Rules for classification: 1) Points; 2) Goal difference; 3) Goals scored; 4) Away goals scored; 5) Wins; 6) Away wins; 7) Disciplinary points; 8) UEFA national team coefficient.
(P) Promoted