Terbium monoselenide is an inorganic compound, with the chemical formula of TbSe. It is one of the selenides of terbium.[2] It is a yellow-red solid.
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3D model (JSmol)
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| ECHA InfoCard | 100.031.709 |
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CompTox Dashboard (EPA)
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| Properties | |
| SeTb | |
| Molar mass | 237.896 g·mol−1 |
| Appearance | yellow-red solid |
| Hazards | |
| GHS labelling:[1] | |
  
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| Danger | |
| H301, H331, H373, H410 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preparation
editTerbium monoselenide can be prepared by reacting terbium and selenium:[3]
- Tb + Se → TbSe
Properties
editTerbium monoselenide has the sodium chloride crystal structure, with space group Fm3m.[2][4][5][6] It can undergo a peritectic reaction in thallium monoselenide to generate TlTbSe2:[7]
- TlSe + TbSe → TlTbSe2
References
edit- ^ "C&L Inventory". echa.europa.eu.
- ^ a b Pribyl'skaya, N. Yu.; Orlova, I. G.; Shkabura, O. N.; Eliseev, A. A. Synthesis and study of the physicochemical properties of terbium selenides. Zhurnal Neorganicheskoi Khimii, 1985. 30 (3): 603-606.
- ^ Olcese, Giorgio L. Structure and magnetic properties of MX compounds from terbium and metalloids of the Groups V and VI. Atti Accad. Nazi. Lincei Rend. Classe Sci. Fis. Mat. e Nat., 1961. 30: 195-200.
- ^ Диаграммы состояния двойных металлических систем. Vol. 3 Книга 2. М.: Машиностроение. 2000. ISBN 5-217-02932-3.
{{cite book}}: Unknown parameter|agency=ignored (help) - ^ B. Predel (1998). "Se-Tb (Selenium-Terbium)". Pu-Re – Zn-Zr. Landolt-Börnstein - Group IV Physical Chemistry. Vol. 5J (Landolt-Börnstein - Group IV Physical Chemistry ed.). p. 1. doi:10.1007/10551312_2716. ISBN 3-540-61742-6.
- ^ H. Okamoto (2001). "Se-Tb (Selenium-Terbium)". Journal of Phase Equilibria. 22 (2) (Journal of Phase Equilibria ed.): 185. doi:10.1361/105497101770339229.
- ^ Guseinov, G. D.; Kerimova, E. M.; Agamaliev, D. G.; Nadzhafov, A. I. The phase diagram of the system thallium monoselenide-terbium monoselenide. zvestiya Akademii Nauk SSSR, Neorganicheskie Materialy, 1987. 23 (10): 1632-1634.