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Tetramethylammonium perchlorate

Tetramethylammonium perchlorate is a perchlorate salt with a condensed formula [N(CH3)4]+ClO4−.

Tetramethylammonium perchlorate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.018.005 Edit this at Wikidata
EC Number
  • 219-805-5
  • InChI=1S/C4H12N.ClHO4/c1-5(2,3)4;2-1(3,4)5/h1-4H3;(H,2,3,4,5)/q+1;/p-1
    Key: ZCWKIFAQRXNZCH-UHFFFAOYSA-M
  • C[N+](C)(C)C.[O-]Cl(=O)(=O)=O
Properties
(CH3)4NClO4
Appearance White Crystal Powder[1]
Melting point 300 °C
Hazards
GHS labelling:
GHS03: OxidizingGHS06: ToxicGHS07: Exclamation markGHS08: Health hazardGHS09: Environmental hazard
Danger
H272, H300, H311, H315, H319, H335, H370, H373, H411
P210, P220, P221, P260, P261, P264, P270, P271, P273, P280, P301+P310, P302+P352, P304+P340, P305+P351+P338, P307+P311, P312, P314, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P370+P378, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 3: Capable of detonation or explosive decomposition but requires a strong initiating source, must be heated under confinement before initiation, reacts explosively with water, or will detonate if severely shocked. E.g. hydrogen peroxideSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
2
1
3
OX
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Preparation

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Tetramethylammonium perchlorate can be produced by mixing cold, dilute perchloric acid with cold tetramethylammonium hydroxide, the reaction will lead to a white precipitation.[2]

Uses

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The perchlorate is used as an intermediate in organic synthesis, in chromatography and as a supporting electrolyte in electrochemistry.[3] Along with trimethylammonium perchlorate, it was investigated as a component in composite propellants during the Cold War, but without much success.

References

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  1. ^ TETRAMETHYLAMMONIUM PERCHLORATE CAS#: 2537-36-2 (chemicalbook.com) . Chemical Book. [2018-3-14]
  2. ^ Juknelevicius, Dominykas; Dufter, Alicia; Rusan, Magdalena; Klapötke, Thomas M.; Ramanavicius, Arunas (2017-02-17). "Study of Pyrotechnic Blue Strobe Compositions Based on Ammonium Perchlorate and Tetramethylammonium Nitrate: Study of Pyrotechnic Blue Strobe Compositions Based on Ammonium Perchlorate and Tetramethylammonium Nitrate". European Journal of Inorganic Chemistry. 2017 (7): 1113–1119. doi:10.1002/ejic.201601486.
  3. ^ "2537-36-2 - Tetramethylammonium perchlorate - 30834 - Alfa Aesar".

Further reading

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  • Hofmann, K. A.; Roth, R.; Hobold, K.; Metzler, A. Relationship between the Constitution and Behavior towards Water of Ammonium Oxonium Perchlorates. Berichte der Deutschen Chemischen Gesellschaft, 1911. 43: 2624-2630. ISSN 0365-9496
 

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