Tin(IV) iodate

Tin(IV) iodate
Names
	IUPAC name triiodyloxystannyl iodate
Identifiers
CAS Number	57232-85-6 ;
3D model (JSmol)	Interactive image;
PubChem CID	129651196;
	InChI InChI=1S/4HIO3.Sn/c42-1(3)4;/h4(H,2,3,4);/q;;;;+4/p-4 Key: WGVVTQUSFDMILB-UHFFFAOYSA-J;
	SMILES O=I(=O)O[Sn](OI(=O)=O)(OI(=O)=O)OI(=O)=O;
Properties
Chemical formula	Sn(IO3)4
Molar mass	818.29
Appearance	colourless columnal crystals
Density	5.107 g·cm-3（23 °C
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Tin(IV) iodate is an inorganic compound with the chemical formula Sn(IO₃)₄. It was first obtained in 2020 through the hydrothermal reaction of tin(II) oxide and iodic acid in water at 220 °C.^[1] It is a colorless columnar crystal, crystallized in the triclinic P1 space group.^[1] It has an indirect band gap (experimental 4.0 eV; calculated 2.75 eV).^[2]

References

^ ^a ^b ^c Luo, Min; Liang, Fei; Hao, Xia; Lin, Donghong; Li, Bingxuan; Lin, Zheshuai; Ye, Ning (2020-03-24). "Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO 3 ) 2 F 2". Chemistry of Materials. 32 (6): 2615–2620. doi:10.1021/acs.chemmater.0c00196. ISSN 0897-4756.
^ Liang, Akun; Rodriguez-Hernandez, Placida; Muñoz, Alfonso; Rahman, Saqib; Segura, Alfredo; Errandonea, Daniel (2021). "Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons". Inorganic Chemistry Frontiers. 8 (22): 4780–4790. doi:10.1039/D1QI00870F. ISSN 2052-1553.

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[Luo-1] Luo, Min; Liang, Fei; Hao, Xia; Lin, Donghong; Li, Bingxuan; Lin, Zheshuai; Ye, Ning (2020-03-24). "Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO 3 ) 2 F 2". Chemistry of Materials. 32 (6): 2615–2620. doi:10.1021/acs.chemmater.0c00196. ISSN 0897-4756.

[2] Liang, Akun; Rodriguez-Hernandez, Placida; Muñoz, Alfonso; Rahman, Saqib; Segura, Alfredo; Errandonea, Daniel (2021). "Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons". Inorganic Chemistry Frontiers. 8 (22): 4780–4790. doi:10.1039/D1QI00870F. ISSN 2052-1553.

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