This article proves that solutions to the Sturm–Liouville equation corresponding to distinct eigenvalues are orthogonal. For background see Sturm–Liouville theory.
Let and
be solutions of the Sturm-Liouville equation [1] corresponding to eigenvalues and respectively. Multiply the equation for by
(the complex conjugate of ) to get:
(Only
, ,
, and
may be complex; all other quantities are real.) Complex conjugate
this equation, exchange
and
, and subtract the new equation from the original:
Integrate this between the limits
and
The right side of this equation vanishes because of the boundary conditions, which are either:
periodic boundary conditions, i.e., that , , and their first derivatives (as well as ) have the same values at as at , or
that independently at and at either:
the condition cited in equation [2] or [3] holds or:
So: .
If we set
, so that the integral surely is non-zero, then it follows that
; that is, the eigenvalues are real, making the differential operator in the Sturm-Liouville equation self-adjoint (hermitian); so:
It follows that, if
and
have distinct eigenvalues, then they are orthogonal. QED.