Groups containing oxygen

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Compounds that contain C-O bonds each possess differing reactivity based upon the location and hybridization of the C-O bond, owing to the electron-withdrawing effect of sp² hybridized oxygen and the donating effects of sp³ hybridized oxygen.

Chemical class Group Formula Structural Formula Prefix Suffix Example
Ether Ether ROR'   alkoxy- alkyl alkyl ether  
Diethyl ether
(Ethoxyethane)
Alcohol Hydroxyl ROH   hydroxy- -ol  
Methanol
Peroxide Peroxy ROOR   peroxy- alkyl peroxide  
Di-tert-butyl peroxide
Hydroperoxide Hydroperoxy ROOH   hydroperoxy- alkyl hydroperoxide  
Methyl ethyl ketone peroxide
Ketone Carbonyl RCOR'   keto-, oxo- -one  
Methyl ethyl ketone
(Butanone)
Aldehyde Aldehyde RCHO   aldo- -al  
Acetaldehyde
(Ethanal)
Acyl halide Haloformyl RCOX   haloformyl- -oyl halide  
Acetyl chloride
(Ethanoyl chloride)
Ester Ester RCOOR'   alkyl alkanoate  
Ethyl butyrate
(Ethyl butanoate)
Carboxylic acid Carboxyl RCOOH   carboxy- -ic acid  
Acetic acid
(Ethanoic acid)
Carboxylate Carboxylate RCOO  

 

carboxy- -oate  
Sodium acetate
(Sodium ethanoate)
Carbonate Carbonate ester ROCOOR   alkyl carbonate