Ytterbium monotelluride is an inorganic compound, one of the tellurides of ytterbium, with the chemical formula YbTe.
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| ECHA InfoCard | 100.031.983 |
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| Properties | |
| TeYb | |
| Molar mass | 300.65 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preparation
editYtterbium monotelluride can be produced by the high-temperature reduction reaction of ytterbium(III) telluride (Yb2Te3),[1] or by the reaction of ytterbium(III) chloride, tellurium and hydrogen:[2]
- YbCl3 + H2 → YbCl2 + 2 HCl
- YbCl2 + H2 + Te → YbTe + 2 HCl
The thermal decomposition of [(py)2Yb(μ-η2-η2-PhNNPh)(TePh)]2·2py will also produce ytterbium monotelluride, but at the same time, ytterbium(III) nitride will be produced.[3]
References
edit- ^ Senff, Heinz; Klemm, Wilhelm. Measurements on bivalent and quadrivalent compounds of the rare earths. IX. The selenides and tellurides of bivalent ytterbium. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1939. 242: 92-96.
- ^ Obolonchik, V. A.; Yanaki, A. A. Synthesis of some rare-earth metal tellurides. Khal'kogenidy, 1970. 2: 141-148. CODEN D8MMYC.
- ^ Kornienko, Anna; Freedman, Deborah; Emge, Thomas J.; Brennan, John G. (2001-01-01). "Heteroleptic Lanthanide Compounds with Chalcogenolate Ligands: Reduction of PhNNPh/PhEEPh (E = Se or Te) Mixtures with Ln (Ln = Ho, Er, Tm, Yb). Thermolysis Can Give LnN or LnE". Inorganic Chemistry. 40 (1): 140–145. doi:10.1021/ic000499y. ISSN 0020-1669. PMID 11195372. Archived from the original on 2023-05-10. Retrieved 2023-06-13.
Further reading
edit- Ziya S. Aliev, Gulnara I. Ibadova, Jean-Claude Tedenac, Mahammad B. Babanly (Jul 2014). "Study of the YbTe–SnTe–Sb2Te3 quasi-ternary system". Journal of Alloys and Compounds. 602: 248–254. doi:10.1016/j.jallcom.2014.03.036. Archived from the original on 2018-06-09. Retrieved 2023-06-13.
{{cite journal}}: CS1 maint: multiple names: authors list (link) - Siron, Martin; Andriuc, Oxana; Persson, Kristin A. (2022-08-11). "Data-Driven Investigation of Tellurium-Containing Semiconductors for CO 2 Reduction: Trends in Adsorption and Scaling Relations". The Journal of Physical Chemistry C. 126 (31): 13224–13236. doi:10.1021/acs.jpcc.2c04810. ISSN 1932-7447. PMC 9377373. PMID 35983310.