Potassium hexafluorozirconate

Potassium hexafluorozirconate
Names
	Other names dipotassium hexafluorozirconate, potassium zirconium hexafluoride, potassium fluorozirconate
Identifiers
CAS Number	16923-95-8 ;
3D model (JSmol)	Interactive image;
ChemSpider	11221760;
ECHA InfoCard	100.037.244
EC Number	240-985-6;
PubChem CID	56828182;
CompTox Dashboard (EPA)	DTXSID00893979;
	InChI InChI=1S/6FH.2K.Zr/h61H;;;/q;;;;;;2+1;+4/p-6 Key: BJZIJOLEWHWTJO-UHFFFAOYSA-H;
	SMILES F[Zr-2](F)(F)(F)(F)F.[K+].[K+];
Properties
Chemical formula	F6K2Zr
Molar mass	283.411 g·mol−1
Appearance	white crystalline powder
Density	3.48 g/cm3
Solubility in water	soluble
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H301, H315, H319, H335
Precautionary statements	P301, P302, P305, P310, P330, P351, P352
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Potassium hexafluorozirconate is an inorganic compound of potassium, fluorine, and zirconium with the chemical formula K₂ZrF₆.^[1]^[2]

Preparation

Potassium hexafluorozirconate can be prepared from precipitation from solutions:

2KF + ZrF₄ → K₂ZrF₆↓

2KCl + (NH₄)₂ZrF₆ → K₂ZrF₆↓ + 2NH₄Cl

Also, in industry, it is obtained by sintering zirconium ore concentrates with K₂SiF₆ at 600–700 °C.^[3]

Physical properties

Potassium hexafluorozirconate forms an odorless white crystalline powder.

It crystallizes in the monoclinic space group C 2/c (space group No. 15).^[4]

Uses

Potassium hexafluorozirconate is used as an intermediate product in the electrolytic production of metallic zirconium.

It is also used as a flame retardant for wool,^[5] grain refining agent in magnesium and aluminum alloys, welding flux, and optical glass component.^[6]

References

^ "Potassium Hexafluorozirconate". American Elements. Retrieved 26 February 2024.
^ "Potassium hexafluorozirconate". Sigma Aldrich. Retrieved 26 February 2024.
^ Lewis, Alison; Olsen, Christine (2007). BIWIC 2007: 14th International Workshop on Industrial Crystallization : September 9th-11th, 2007, University of Cape Town, Cape Town, South Africa. IOS Press. p. 186. ISBN 978-1-58603-790-1. Retrieved 26 February 2024.
^ Hoppe, R.; Mehlhorn, B. (September 1976). "Die Kristallstruktur von K 2 ZrF 6". Zeitschrift für anorganische und allgemeine Chemie. 425 (3): 200–208. doi:10.1002/zaac.19764250303. Retrieved 26 February 2024.
^ Lewis, David M.; Rippon, John A. (20 May 2013). The Coloration of Wool and Other Keratin Fibres. John Wiley & Sons. p. 115. ISBN 978-1-118-62509-5. Retrieved 26 February 2024.
^ "Potassium hexafluorozirconate | CAS 16923-95-8 | Connect Chemicals". connectchemicals.com. Retrieved 26 February 2024.

[1] "Potassium Hexafluorozirconate". American Elements. Retrieved 26 February 2024.

[2] "Potassium hexafluorozirconate". Sigma Aldrich. Retrieved 26 February 2024.

[3] Lewis, Alison; Olsen, Christine (2007). BIWIC 2007: 14th International Workshop on Industrial Crystallization : September 9th-11th, 2007, University of Cape Town, Cape Town, South Africa. IOS Press. p. 186. ISBN 978-1-58603-790-1. Retrieved 26 February 2024.

[4] Hoppe, R.; Mehlhorn, B. (September 1976). "Die Kristallstruktur von K 2 ZrF 6". Zeitschrift für anorganische und allgemeine Chemie. 425 (3): 200–208. doi:10.1002/zaac.19764250303. Retrieved 26 February 2024.

[5] Lewis, David M.; Rippon, John A. (20 May 2013). The Coloration of Wool and Other Keratin Fibres. John Wiley & Sons. p. 115. ISBN 978-1-118-62509-5. Retrieved 26 February 2024.

[6] "Potassium hexafluorozirconate | CAS 16923-95-8 | Connect Chemicals". connectchemicals.com. Retrieved 26 February 2024.

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