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Vivek Polshettiwar

Vivek Vijayrao Polshettiwar (born 18 March 1979) is an Indian chemist who is a professor of chemistry at the Tata Institute of Fundamental Research. His research focuses on advanced nanomaterials and nanocatalysis, particularly for harvesting solar energy and converting carbon dioxide into valuable chemicals and fuels. His work is aimed at producing value-added products from CO2 to effectively combat climate change. He was awarded the International Union of Pure and Applied Chemistry prize for Green Chemistry in 2022. In 2023, he received the Falling Walls Award in Physical Sciences. The following year, in 2024, he was elected as a Fellow of the Indian Academy of Sciences (FASc). In 2024, he received Vigyan Yuva Shanti Swarup Bhatnagar (SSB)  award from the President of India.[1]

Vivek Vijayrao Polshettiwar
Polshettiwar receiving the Shanti Swarup Bhatnagar (SSB) Award from the President of India
Born (1979-03-18) March 18, 1979 (age 45)
Mangli (Dist-Yavatmal, Maharashtra)
Alma materSant Gadge Baba Amravati University Maharashtra
Scientific career
InstitutionsTata Institute of Fundamental Research
United States Environmental Protection Agency
King Abdullah University of Science and Technology
Websitehttps://www.nanocat.co.in/

Early life and education

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Polshettiwar was born in Mangli, a village in the Yavatmal district within the Vidarbha region of Maharashtra. He began his education in Zilla Parishad government schools, which had limited infrastructure and often lacked sufficient teachers, with many of his classes taking place under trees or in temporary shelters.

For high school, he moved to the nearby village of Mukutban, where he attended Adarsh Highschool. He then pursued his 12th science and BSc degree at Lokmanya Tilak Mahavidyalaya in Wani. In 2001, Polshettiwar earned his Master's degree in Chemistry from Amravati University, Amravati.

He earned his doctorate at DRDE and Jiwaji University in Gwalior.[1] After earning his doctorate, he moved to the ENSCM: Ecole Nationale Suprieure de chimie de Montpellier in France, where he spent one year as a postdoctoral researcher.[2] He was awarded an Oak Ridge Institute for Science and Education Research Fellowship and joined the United States Environmental Protection Agency in 2007.[3]

Research and career

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In 2009, Polshettiwar launched his independent career at King Abdullah University of Science and Technology.[4] He returned to India in 2013, where he started working on nanomaterials at the Tata Institute of Fundamental Research. His research considers nanocatalysis: the design of sustainable, reactive, stable and selective catalysts.[5] He believes that the activity and kinetics of nanocatalysts can be influenced by tuning the morphology and defects of the catalyst.[5]

Polshettiwar has primarily focused on dendritic fibrous nanosilica,[6] which has a fibrous structure that enhances the surface area on which reactions can occur.[7] His innovations in producing efficient dendritic fibrous nanosilica catalysts were made possible by altering the nanoscale properties of the material, specifically, the spacing between the nanostructures themselves. These dendritic fibrous nanosilica catalysts can capture carbon dioxide and convert it to fuel and useful chemicals.[8][9] He has created amorphous aluminosilicates that can convert plastics to hydrocarbons at low temperature, contributing to a circular economy.[10]

Polshettiwar's research encompasses several key areas in nanocatalysis. One notable achievement is the development of "Black Gold[11][12]," a system designed to study plasmonic hot electron generation and transfer. This model mimics natural photosynthesis, using sunlight, water, and CO2 to offer potential sustainable energy solutions. Another significant focus of his work is the exploration of defects[13][14] in nanomaterials as active catalytic sites, presenting a new approach to catalyst design that avoids the need for metals or complex organic ligands. Additionally, his group has developed "Acidic Amorphous Aluminosilicate," which combines the strong acidity of zeolites with the textural properties of aluminosilicates. This material has shown promise in converting plastics to chemicals and CO2 to fuel.

Awards and honours

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Selected publications

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  • Dendritic Fibrous Nano-Silica (DFNS): Discovery, Synthesis, Formation Mechanism, Catalysis, and CO2 Capture-Conversion. Vivek Polshettiwar* ACS Accounts of Chemical Research, 2022, 55, 1395–1410.
  • Pt-Doped Ru Nanoparticles Loaded on ‘Black Gold’ Plasmonic Nanoreactors as Air Stable Reduction Catalysts. Gunjan Sharma, Rishi Verma, Shinya Masuda, Khaled Mohamed Badawy, Nirpendra Singh, Tatsuya Tsukuda,* Vivek Polshettiwar* Nature Communication 2024, 15, 713.
  • Nickel Laden Dendritic Plasmonic Colloidosomes of Black Gold: Forced Plasmon Mediated CO2 Hydrogenation using Solar Energy. Rishi Verma, Rajesh Belgamwar, P. Chatterjee, R. B. Vadell, Jacinto Sá and Vivek Polshettiwar* ACS Nano, 2023 17, 4526–4538.
  • Surface Plasmon-Enhanced Photo-Driven CO2 Hydrogenation by Hydroxy Terminated Nickel Nitride Nanosheets. Saideep Singh, R. Verma, N. Kaul, J. Sa, Vivek Polshettiwar,* Nature Communication 2023, 14, 2551
  • Defects Tune the Strong Metal-Support Interactions in Copper Supported on Defected Titanium Dioxide Catalyst for CO2 Reduction. Rajesh Belgamwar, Rishi Verma, Tisita Das, Sudip Chakraborty, Pradip Sarawade, Vivek Polshettiwar* J. Am. Chem. Soc. 2023, 145, 8634-8646.
  • Defects in Nanosilica Catalytically Convert CO2 to Methane without Any Metal and Ligand. Amit K. Mishra, R. Belgamwar, R. Jana, A. Datta, and Vivek Polshettiwar*, Proc. Natl. Acad. Sci. U.S.A 2020, 117, 6383-6390.
  • Facile Synthesis Protocol to Tune Size, Textural Properties & Fiber Density of Dendritic Fibrous Nanosilica (DFNS): Applications in Catalysis and CO2 Capture. Ayan Maity, R. Belgamwar, Vivek Polshettiwar,* Nature Protocol, 2019, 14, 2177-2204
  • Nanosponges of Acidic Amorphous Aluminosilicate for Catalysis, Plastic Degradation and CO2 to Fuel Conversion. Ayan Maity, S. Chaudhari, J. J. Titman, Vivek Polshettiwar*, Nature Commun. 2020, 11, 3828.

References

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  1. ^ "Nanocatalysis Laboratories". Nanocatalysis Laboratories. Retrieved 2024-06-10.
  2. ^ Vivek Vijayrao Polshettiwar. OCLC 4780110112.
  3. ^ "Department of Chemical Sciences, Tata Institute of Fundamental Research, Vivek Polshettiwar".
  4. ^ A. Rawool, Sushma; K. Yadav, Kishan; Polshettiwar, Vivek (2021). "Defective TiO 2 for photocatalytic CO 2 conversion to fuels and chemicals". Chemical Science. 12 (12): 4267–4299. doi:10.1039/D0SC06451C. PMC 8179507. PMID 34163693.
  5. ^ a b "Vivek Polshettiwar". www.tifr.res.in. Retrieved 2022-08-14.
  6. ^ Polshettiwar, Vivek (2022-05-17). "Dendritic Fibrous Nanosilica: Discovery, Synthesis, Formation Mechanism, Catalysis, and CO 2 Capture–Conversion". Accounts of Chemical Research. 55 (10): 1395–1410. doi:10.1021/acs.accounts.2c00031. ISSN 0001-4842.
  7. ^ Maity, Ayan; Belgamwar, Rajesh; Polshettiwar, Vivek (July 2019). "Facile synthesis to tune size, textural properties and fiber density of dendritic fibrous nanosilica for applications in catalysis and CO2 capture". Nature Protocols. 14 (7): 2177–2204. doi:10.1038/s41596-019-0177-z. ISSN 1750-2799. PMID 31189974. S2CID 186207685.
  8. ^ Dhiman, Mahak; Maity, Ayan; Das, Anirban; Belgamwar, Rajesh; Chalke, Bhagyashree; Lee, Yeonhee; Sim, Kyunjong; Nam, Jwa-Min; Polshettiwar, Vivek (2019-07-10). "Plasmonic colloidosomes of black gold for solar energy harvesting and hotspots directed catalysis for CO2 to fuel conversion". Chemical Science. 10 (27): 6594–6603. doi:10.1039/C9SC02369K. ISSN 2041-6539. PMC 6625417. PMID 31367310.
  9. ^ "Eureka! Now what?". The Week. Retrieved 2022-08-14.
  10. ^ Maity, Ayan; Chaudhari, Sachin; Titman, Jeremy J.; Polshettiwar, Vivek (2020-07-31). "Catalytic nanosponges of acidic aluminosilicates for plastic degradation and CO2 to fuel conversion". Nature Communications. 11 (1): 3828. Bibcode:2020NatCo..11.3828M. doi:10.1038/s41467-020-17711-6. ISSN 2041-1723. PMC 7395177. PMID 32737304.
  11. ^ Sharma, Gunjan; Verma, Rishi; Masuda, Shinya; Badawy, Khaled Mohamed; Singh, Nirpendra; Tsukuda, Tatsuya; Polshettiwar, Vivek (2024-01-24). "Pt-doped Ru nanoparticles loaded on 'black gold' plasmonic nanoreactors as air stable reduction catalysts". Nature Communications. 15 (1): 713. doi:10.1038/s41467-024-44954-4. ISSN 2041-1723. PMC 10808126.
  12. ^ Verma, Rishi; Belgamwar, Rajesh; Chatterjee, Pratip; Bericat-Vadell, Robert; Sa, Jacinto; Polshettiwar, Vivek (2023-03-14). "Nickel-Laden Dendritic Plasmonic Colloidosomes of Black Gold: Forced Plasmon Mediated Photocatalytic CO 2 Hydrogenation". ACS Nano. 17 (5): 4526–4538. doi:10.1021/acsnano.2c10470. ISSN 1936-0851.
  13. ^ Belgamwar, Rajesh; Verma, Rishi; Das, Tisita; Chakraborty, Sudip; Sarawade, Pradip; Polshettiwar, Vivek (2023-04-19). "Defects Tune the Strong Metal–Support Interactions in Copper Supported on Defected Titanium Dioxide Catalysts for CO 2 Reduction". Journal of the American Chemical Society. 145 (15): 8634–8646. doi:10.1021/jacs.3c01336. ISSN 0002-7863.
  14. ^ Mishra, Amit K.; Belgamwar, Rajesh; Jana, Rajkumar; Datta, Ayan; Polshettiwar, Vivek (2020-03-24). "Defects in nanosilica catalytically convert CO 2 to methane without any metal and ligand". Proceedings of the National Academy of Sciences. 117 (12): 6383–6390. doi:10.1073/pnas.1917237117. ISSN 0027-8424. PMC 7104409. PMID 32156731.
  15. ^ "Emerging Investigators 2016: Novel design strategies for new functional materials Home". pubs.rsc.org. Retrieved 2022-08-14.
  16. ^ "List of newly elected Young associates and Fellows of Maharashtra Academy of Sciences (MASc)-2019" (PDF).
  17. ^ "Materials Research Society of India". www.mrsi.org.in. Retrieved 2022-08-14.
  18. ^ "Young Career Award in Nano Science & Technology for the year 2020 to Prof. Polshettiwar". Nanocatalysis Laboratories. Retrieved 2022-08-14.
  19. ^ "The National Academy of Sciences, India" (PDF).
  20. ^ "Prof. Vivek Polshettiwar is Elected as a Fellow National Academy of Sciences, India (NASI)". Nanocatalysis Laboratories. Retrieved 2022-08-14.
  21. ^ "Vivek Polshettiwar is awarded the 2022 IUPAC-CHEMRAWN VII Prize for Green Chemistry". IUPAC | International Union of Pure and Applied Chemistry. 2022-08-11. Retrieved 2022-08-14.
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